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Traditional mortar represented by sticky rice lime mortar—One of the great inventions in ancient China

Science in China Series E: Technological Sciences volume 52, pages 1641–1647 (2009)Cite this article

Abstract

The development of traditional lime-based bond in ancient times was reviewed in this paper. It was proved by a lot of historical data that the application of organic materials in inorganic mortar was a sharp-cut characteristic during the developing process of construction gelled materials in ancient China. The important role sticky rice mortar ever played and the historical significance were revealed. Due to the excellent performance, such as high adhesive strength, good toughness, water-proof and so on, traditional mortar represented by sticky rice mortar should be one of the greatest technological contributions of the day in the world. Modern technology was employed in the study of the sticky rice lime mortar and the researching results of our laboratory and some researchers, including the composition and the mechanism of solidification, were also presented. It was found that the sticky rice acted as a matrix of bio-mineralization which affected the microstructure of the calcium carbonate crystal and there was cooperation between sticky rice and calcite produced during the solidifying of the sticky rice mortar, which maybe lead to the excellent performance of the mortar. Because of excellent performance and importance in science, sticky rice mortar can be regarded as one of the greatest inventions in construction history of China. Relative research of sticky mortar will be of importance for the exploring of ancient momentous invention and the repairing of ancient construction.

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References

  1. Liu J Z. Civil Engineering Materials (in Chinese). Beijing: Science Press, 2005. 37

    Google Scholar 

  2. Lu L C. Discussion about the properties of “lime powder” in the new stone age. In: the Institute for the History of Natural Science Eds. Collection of Science and Technology History (in Chinese). Shanghai: Shanghai Scientific and Technical Publishers, 1985. 14: 107

    Google Scholar 

  3. Qiu S H. When did the lime production begin? The 14C isotopic geochemical method can answer the question (in Chinese). Archeol Cul Rel, 1980, 5: 126–130

    Google Scholar 

  4. Yao Y. The History of Xi’an in Han Dynasty (Science and Technology) (in Chinese). Xi’an: Shanxi People’s Publishing House, 1993. 477–478

    Google Scholar 

  5. Zuo Q M (Spring and Autumn Period). Zuo Zhuan (in Chinese). Changsha: Yuelu Press, 2001. 289

    Google Scholar 

  6. Xing J W. Shanxi Ancient Science and Technology (in Chinese). Beijing: China Science & Technology Press, 1995. 161–163

    Google Scholar 

  7. Wang K. The Ancient History of Road Transportation in Shanxi (in Chinese). Beijing: China Communication Press, 1989. 10

    Google Scholar 

  8. Tie F D. Conservation and restoration of wall paintings of early Western Han Dynasty (1)—Investigation of conservation history and actuality (in Chinese). Sci Conserv Archaeol, 2004, 16(1): 47–51

    Google Scholar 

  9. Huang Y F. Fresco Art of a Han tomb in Henan province (in Chinese). Acad Forum Nandu, 1998, 18(2): 17–20

    Google Scholar 

  10. Ma X Y. A different opinion about Fresco of the Dahuting Han tomb (in Chinese). J Hist Sci, 1999, 5: 32–65

    Google Scholar 

  11. Shanxi Archeology Research Institute. Brief Excavation Report of the Northern Dynasty Tomb Found in the Northern Suburbs, Xi’an (in Chinese). Archaeol Cul Rel, 2005, 1: 7–16

    Google Scholar 

  12. CPAM of Zoucheng City. Excavation of Liu Bao’s Tomb of the Western Jin at Zoucheng in Shandong (in Chinese). Cul Rel, 2005, 1: 4–26

    Google Scholar 

  13. Shanxi Provincial Institute of Archeology. Remains of Zhou Dynasty and Han Dynasty were found in Lingshi country, Shanxi (in Chinese). Cul Rel, 2004, 8: 29–37

    Google Scholar 

  14. Pu S. North Yan tomb in Yuantaizi village, Chaoyang county, Liaoning province (in Chinese). Cul Rel, 1994, 11: 43–47

    Google Scholar 

  15. Yao Q Z, Lv Da. On historical evolution of the ancient Tongwan City & its architecture (in Chinese). J Yan’an Univ (Social Science Edition), 2004, 26(2): 126–128

    Google Scholar 

  16. Shen Kuo (Song Dynasty). The Dream Rivulet Diary (in Chinese). Changchun: Times Wenyi Press, 2001. 110

    Google Scholar 

  17. Tang C R. References of Chinese General History (in Chinese). Beijing: Zhong Hua Press, 1983.

    Google Scholar 

  18. Archeology crew of Henan province. A Stick Tomb with Colorized Portrait in Deng Country, Henan Provice (in Chinese). Beijing: Cultural Relic Press, 1958.

  19. Song Ying-xing (Ming Dynasty). Tian Gong Kai Wu (in Chinese). Shanghai: Commercial press, 1958. 197.

    Google Scholar 

  20. Wu Q Z. The experience and implication for the flooding control in the ancient towns in China (continued) (in Chinese). City Plan Rev, 2002, 26(5): 76–84

    Google Scholar 

  21. Jiang X F (Song Dynasty). Linji Zazhi, About City, Volume 30 (in Chinese). Shanghai: Shanghai Ancient Books Publishing Company, 1988

    Google Scholar 

  22. Li X H, De Q S. The artistic appreciation of stone tower with sutra inscriptions (in Chinese). Architect Gard, 2005, 3: 32–34

    Google Scholar 

  23. Lin J S, Lin Z J, Chen J F. The ancient great earthquake and earthquake-resistance of the ancient buildings (towers, temples and bridges) in Quanzhou city (in Chinese). World Earthquake Eng, 2005, 21(2): 159–166

    Google Scholar 

  24. Ji S J. Some discussions about Nanjing city wall (in Chinese). Palace Mus J, 1984, 2: 70–81

    Google Scholar 

  25. Riccardia M P, Duminucob P, Tomasic C, et al. Thermal, microscopic and X-raydiffraction studieson some ancient mortars. Thermochim Acta, 1998, 321: 207–214

    Article  Google Scholar 

  26. Paulo M d S, Veiga M d R, de Brito j. Gypsum coatings in ancient buildings. Constr Build Mater, 2007, 21: 126–131

    Article  Google Scholar 

  27. Hasan B, Sedat A, Başak I, et al. Characteristics of brick used as aggregate in historic brick-lime mortars and plasters. Cem Concr Res, 2006, 36: 1115–1122

    Article  Google Scholar 

  28. Moropoulou A, Bakolas A, Anagnostopoulou S. Composite materials in ancient structures. Cem Concr Compos, 2005, 27: 295–300

    Article  Google Scholar 

  29. Bakolas A, Biscontin G, Contardi V, et al. Thermoanalytical research on traditional mortars in Venice. Thermochim Acta, 1995, 269: 817–828

    Article  Google Scholar 

  30. Güleç A, Tulun T. Physico-chemical and petrographical studies of old motars and plasters of Anatolia. Cem Concr Res, 1997, 27(2): 227–234

    Article  Google Scholar 

  31. Needham J. Science and Civilization in China. Shanghai: Shanghai People’s Publishing House, 2001. 2

    Google Scholar 

  32. Jiangsu Committee for the Protection of Antiquities and Monuments. Fresco tomb of Song Dynasty in Huai’an, Jiangsu (in Chinese). Ref Mater Cul Rel, 1960, 8(9): 43

    Google Scholar 

  33. Institute of Cultural Relics of Hebei. The report on archaeological excavations of the Shi relative’s grave site in Hebei province. In: The Collection of Archeology Discovery in Hebei Province (in Chinese). Beijing: Orient Press, 1998. 344–369

    Google Scholar 

  34. Liu X D. The earth pit tomb with stone out coffin in Jin Dynasty and relative problems. In: The Collection of Archeology Discovery for the 20th Anniversary of Archaeology Department, Jilin University (in Chinese). Beijing: World Affairs Press, 1993, 397–401

    Google Scholar 

  35. Yang G L. Viewing the Remains-antirot technique in the ancient grave custom (in Chinese). J Changsha Soc Work Coll, 2004, 4: 11–15

    Google Scholar 

  36. Ma J. A surprising discovery: A ranee tomb was found in East China Jiao Tong University (in Chinese). Rel S, 2003, 3: 116–117

    Google Scholar 

  37. De’an Museum. A briefing about the material collection of Daixiogshi tomb in De’an (in Chinese). Rel S, 1994, 4: 5–9

    Google Scholar 

  38. Zheng Q. On architectural features and humanistic values of the ancient pagodas in Taizhou (in Chinese). Huazhong Architect, 2003, 21: 83–86

    Google Scholar 

  39. The Archeological Team at the Yuquan Iron Pagoda. Clearing up of the basement of the Yuquan Iron Pagoda at Dangyang, Hubei, the archeological team at the Yuquan iron pagoda (in Chinese). Cul Rel, 1996, 10: 43–57

    Google Scholar 

  40. Chen J L. The Researching About the Relation of Materials Prescription of Ancient Mortar and Strength (in Chinese). Tainan: National Cheng Kung University, 2004

    Google Scholar 

  41. CPAM of Shanghai City. Excavation of the Yuan and Ming underground closets of the Fahua Pagoda at Jiading, Shanghai (in Chinese). Cul Rel, 1999, 2: 4–15

    Google Scholar 

  42. Qiu Z J. The Chongqing “leaning tower pisa” with a tilt angle of 45 degree suvived 300 hundreds of years (in Chinese). Buil’Mon, 2006, 7: 55–55

    Google Scholar 

  43. Peng S F. Rethinking of the change and development of ancient Nanchang city (in Chinese). Rel S, 1995, 4: 86–98

    Google Scholar 

  44. Zhang Y H. The History of Building Technology in Ancient China (in Chinese). Beijing: Science Press, 1985. 173

    Google Scholar 

  45. Wu Q Z. Study on citywall and moat military defence system of Nanjing City in Ming Dynasty (in Chinese). Architect, 2005, 2: 96–101

    Google Scholar 

  46. Zhao T M. Features the gate of Guidefu ancient city in Shangqiu (in Chinese). Shanxi Architect, 2007, 33(6): 63–65

    Google Scholar 

  47. Wang X S, Fixing up and application technology of ancient city wall (in Chinese). Trad Chin Architect Gard, 2004, 1: 20–22

    Google Scholar 

  48. Wang Z C. Ancient city below water—Sizhou city (in Chinese). Encyclopedic Knowl, 2005, 11: 54–56

    Google Scholar 

  49. Yu H Y, Chen D. Protection and development of tourism resources for ancient seawall of Qiantang River (in Chinese). Zhejiang Hydrotechn, 2004, 4: 9–10

    Google Scholar 

  50. Wang Y M. The Developing History of Cement in China (in Chinese). Beijing: China Architecture & Building Press, 2005. 4–5

    Google Scholar 

  51. Cai S C. Introduction of ancient bridges in Jiangsu province (in Chinese). Trad Chin Architect Gard, 2001, 3: 48–54

    Google Scholar 

  52. Wuhan City Museum. Ancient bridge in Wuhan (in Chinese). Wuhan Cul Historical Mater, 2001, 9: 45–48

    Google Scholar 

  53. Lu X. The history of dragon bridge (in Chinese). Rel Museol, 2007, 2: 56–57

    Google Scholar 

  54. Wang W J. Checking, assessing, repairing and reinforcing design of Huguo Bridge, Kunming City (in Chinese). Yunnan Commun Sci Tech, 2001, 2: 44–48

    Google Scholar 

  55. Shen X Y, Liu P L, Liu A. Type, value and heritage management model of Diao Tower in Kai Ping (in Chinese). J Hunan U Arts Sci (Social Science Edition), 2006, 1(4): 95–99

    Google Scholar 

  56. Cai J S. Environment friendly Castle-Like Dwellings (in Chinese). Architect J, 1995, 5: 42–44

    Google Scholar 

  57. Zeng Y Y, Zhang B J, Liang X L. A case study and mechanism investigation of typical mortars used on ancient architecture in China. Thermochim Acta, 2008, 473(1–2): 1–6

    Article  Google Scholar 

  58. Yang F W, Zhang B J, Zeng Y Y, et al. The exploring research of the scientificalness and application of traditional sticky rice mortar. Palace Mus J, 2008, 5: 105–114

    Google Scholar 

  59. Sawai J, Shiga H, Kojima H, et al. Kinetic analysis of the bactericidal action of heated scallop-shell powder. Int J Food Microbiol, 2001, 71: 211–218

    Article  Google Scholar 

  60. Catalano V R, Knabel S J. Incidence of Salmonella in Pennsylvania egg processing plants and destruction by high pH. J Food Prot, 1994, 57: 587–591

    Google Scholar 

  61. Liu Q, Zhang B J. Bioinspired preparation of a protective Biomineralized material on the surfaces of historic stones. Acta Chim Sinica, 2006, 64(15): 1601–1605

    Google Scholar 

  62. Liu Q, Zhang B J. Syntheses of a novel nanomaterial for conservation of historic stones inspired by nature. Mater Lett, 2007, 61: 4976–4979

    Article  Google Scholar 

  63. Zeng Y Y, Zhang B J, Liang X L. A study on the Characteristics and consolidating mechanism of Chinese traditional mortars used on historical architecture. Sci Conserv Archaeol, 2008, 20(2): 1–7

    Google Scholar 

  64. Yang L, Ding W J, An Y G, et al. Control synthesis of Aragonite Calcium Carbonate with Glucan as the template. Chem J Chin Univ, 2004, 8: 1403–1406

    Google Scholar 

  65. Zhang X Y, Liao Z J, Yang L, et al. Interaction between β-Cyclodextrin and Crystallization of Calcium Carbonate (in Chinese). Acta Chim Sinica, 2003, 1: 69–73

    Google Scholar 

  66. Ding W J, An Y G, Yang L, et al. Study on IR of interaction of three Modified-Starchs and Crystallization of Calcium Carbonate (in Chinese). Spectrosc Spect Anal, 2005, 25(5): 701–704

    Google Scholar 

  67. Wang L D, Sun W Z, Liang T X, et al. Research status of Biomimetic materials (in Chinese). J Mater Eng, 1996, 2: 3–5

    Google Scholar 

  68. Xie F L. Cross-linkage of hydroxyapatite/gelatin nanocomposite using EGDE (in Chinese). Sci Tech Gel, 2007, 27(1): 24–28

    Google Scholar 

  69. Li X H, Hou W T. The conch structure and Biomimetic research on ceramics (in Chinese). Bull Chin Ceram Soc, 2003, 2: 53–55

    Article  Google Scholar 

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Authors and Affiliations

  1. Laboratory of Cultural Relics Conservation Materials, Department of Chemistry, Zhejiang University, Hangzhou, 310027, China

    FuWei Yang, BingJian Zhang, ChangChu Pan & YuYao Zeng

Authors
  1. FuWei Yang
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  2. BingJian Zhang
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  3. ChangChu Pan
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  4. YuYao Zeng
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Corresponding author

Correspondence to BingJian Zhang.

Additional information

Supported by the National Natural Science Foundation of China (Grant No. 20671080) and the National Technology Support Program of China (Grant No. 2006BAK30B02)

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Yang, F., Zhang, B., Pan, C. et al. Traditional mortar represented by sticky rice lime mortar—One of the great inventions in ancient China. Sci. China Ser. E-Technol. Sci. 52, 1641–1647 (2009). https://doi.org/10.1007/s11431-008-0317-0

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  • DOI: https://doi.org/10.1007/s11431-008-0317-0

Keywords

  • invention
  • sticky rice lime mortar
  • lime
  • bio-mineralization
  • mechanism