Skip to main content
Log in

Effect of air annealing on the optical electrical and structural properties of In2S3 films

  • Published:
Science in China Series E: Technological Sciences Aims and scope Submit manuscript

Abstract

The effect of the annealing temperature T a on the optical, electrical and structural properties of the In2S3 films obtained by the spray pyrolysis method at 350°C substrate temperature was studied. All the In2S3 films annealed in the range from 100 to 400°C are polycrystalline with (220) preferential orientation. The resistivity decreases as T a increases until it reaches a value of 25 Ohm-cm for T a=400°C. The grain size also increases when T a increases as observed in data calculated from X-ray measurements. XRD data indicates that samples show microstructural perfection improvement as a function of annealing temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Seyam M A M. Optical and electrical properties of indium monosulfide (InS) thin films. Vacuum, 2001, 63: 441–447

    Article  Google Scholar 

  2. Hara K, Sayama K, Arakawa H. Semiconductor-sensitized solar cells based on nanocrystalline In2S3/In2O3 thin film electrodes. Sol Energy Mater Sol Cells, 2001, 62: 441–447

    Article  Google Scholar 

  3. Shay J L, Tell B. Energy band structure of I–III–VI2 semiconductors. Surf Sci, 1973, 37: 748–762

    Article  Google Scholar 

  4. George J, Joseph K S, Prodeep B, et al. Reactively evaporated films of indium sulphide. Phys Status Solidi, Appl Res, 1988, 106: 123

    Article  Google Scholar 

  5. Barreau N, Bernède J C, Marsillac S, et al. New Cd-free buffer layer deposited by PVD: In2S3 containing Na compounds. Thin Solid Films, 2003, 431: 326–329

    Article  Google Scholar 

  6. Bube R H, McCarroll W H. Photoconductivity in indium sulfide powders and crystals. J Phys Chem Solids. 1959, 10(4): 333–335

    Article  Google Scholar 

  7. Yukawa T, Kuwabara K, Koumoto K. Electrodeposition of CuInS2 from aqueous solution (II) electrodeposition of CuInS2 film. Thin Solid Films, 1996, 286: 151–153

    Article  Google Scholar 

  8. Belgacem S, Amlouk M, Bennaceur R. The effect of Cu/In ratio on the structure of thin films of CuInS2 made by airless spraying (in French.). Rev Phys Appl, 1990, 25(12): 1213–1223

    Google Scholar 

  9. Kazuki I M, Nakamura T A, Arai E. Photochemical deposition of Se and CdSe films from aqueous solutions. Thin Solid Films, 2001, 384: 157–159

    Article  Google Scholar 

  10. John T T, Bini S, Kashiwaba Y, et al. Characterization of spray pyrolysed indium sulfide thin films. Semicond Sci Technol, 2003, 18: 491

    Article  Google Scholar 

  11. Kumaresan R, Ichimura M, Sato N, et al. Application of novel photochemical deposition technique for the deposition of indium sulfide. Mater Sci Eng B Solid-State Mater Adv Technol, 2002, 96: 37–42

    Google Scholar 

  12. Kamoun N, Bennaceur R, Amlouk M, et al. L. Optical properties of InS layers deposited using an airless spray technique. Phys Status Solidi (a), 1998, 169(1): 97–104

    Article  Google Scholar 

  13. Bouguila N, Bouzouita H, Lacaze E, et al. Effet de la température de fabrication sur les propriétés structurales et morphologiques des couches épaisses de In2S3 “spray”. J Phys III France, 1997, 7(8): 1647–1660

    Article  Google Scholar 

  14. Naghavi N, Henriquez R, Laptev V, et al. Growth studies and characterisation of In2S3 thin films deposited by atomic layer deposition (ALD). Appl Surf Sci, 2004, 222: 65–73

    Article  Google Scholar 

  15. Asikainen T, Ritala M, Leskelä M. Growth of In2S3 thin films by atomic layer epitaxy. Appl Surf Sci, 1994, 82/83: 122–125

    Article  Google Scholar 

  16. George J, Joseph K S, Pradeep B, et al. Reactively evaporated films of indium sulphide. Phys Status Solidi (a), 1988, 106(1): 123–131

    Article  Google Scholar 

  17. El Shazly A A, Abd Elhady D, Metwally H S, et al. Electrical properties of β-In2S3 thin films. J Phys: Condensed Matter, 1998, 10(26): 5943

    Article  Google Scholar 

  18. Guillén C, García T, Herrero J, et al. Tailoring growth conditions for modulated flux deposition of In2S3 thin films. Thin Solid Films, 2004, 451/452: 112–115

    Article  Google Scholar 

  19. Diehl R, Nitsche R. Vapour growth of three In2S3 modifications by iodine transport. J Cryst Growth, 1975, 28: 306–310

    Article  Google Scholar 

  20. Bessergenev V G, Ivanova E N, Kovalevskaya Yu A, etal. Electrical properties of conductive In2S3 and In2O3S films prepared from the In(S2COC3H7-iso)3 volatile precursor. Inorganic Mater, 1996, 32(6): 592

    Google Scholar 

  21. Hai-Ning C, Xi S Q, The fabrication of dipped CdS and sputtered ITO thin films for photovoltaic solar cells. Thin Film Solids, 1996, 288: 325–329

    Article  Google Scholar 

  22. Morgan D V, Aliyu Y H, Bunce R. W, Salehi A. Annealing effects on opto-electronic properties of sputtered and thermally evaporated indium-tin-oxide films. Thin Solid Films, 2004, 84: 126–130

    Google Scholar 

  23. Bhatti M T, Rana A M, Khan A F. Characterization of rf-sputtered indium tin oxide thin films. Mater Chem Phys, 2004, 84: 126–130

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Metin Bedir.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bedir, M., Öztas, M. Effect of air annealing on the optical electrical and structural properties of In2S3 films. Sci. China Ser. E-Technol. Sci. 51, 487–493 (2008). https://doi.org/10.1007/s11431-008-0074-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11431-008-0074-0

Keywords

Navigation