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Synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48 (ANMZ-48) directed by metal complexes in amphiphilic molecules

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Abstract

The synthesis of mesoporous zeolite-anchored atomically dispersed metal catalysts (ADCs) is a considerable challenge in chemistry and materials science. Here we report the synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48 (ANMZ-48) by in situ hydrothermal reaction employing a designed tri-functional metal complex template, by which the triquaternary ammonium groups in the hydrophilic region direct the formation of ZSM-48 zeolite; the aromatic groups in the hydrophobic tail generate the mesopores through π-π stacking; and the complexes formed by nickel ions coordinated with terpyridyl groups generate atomically dispersed Ni2+ confined in zeolite frameworks due to the strong sintering resistance generated by the strong coordination interaction. The ANMZ-48 is consisting of stacking of sheet-like ZSM-48 domains connected by multiply crystal twinning sharing the common (011) plane, generating abundant of imbedded mesopores with the uniform thickness of ∼2.4 nm and with the width of 10–50 nm. The excellent catalytic activity and stability of ANMZ-48 were also reflected in the dry reforming of methane (DRM) reaction.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21922304, 22276086) and the Fundamental Research Funds for the Central Universities.

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Author notes

  1. These authors contributed equally to this work.

Authors and Affiliations

  1. School of Chemical Science and Engineering, Tongji University, Shanghai, 200092, China

    Yu Chen, Quanzheng Deng, Shunai Che & Lu Han

  2. School of Chemistry and Chemical Engineering, Nanchang University, Nanchang, 330031, China

    Yiru Mao, Zhihua Cao & Honggen Peng

  3. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China

    Yuxi Fang & Shunai Che

  4. School of Resources and Environment, Nanchang University, Nanchang, 330031, China

    Honggen Peng

  5. State Key Laboratory of Metal Matrix Composites, Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, Shanghai Jiao Tong University, Shanghai, 200240, China

    Shunai Che

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  1. Yu Chen
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Correspondence to Yuxi Fang, Honggen Peng, Shunai Che or Lu Han.

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Supporting information The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.

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11426_2023_1823_MOESM1_ESM.pdf

Synthesis of Atomically Dispersed Cationic Nickel-Confined Mesoporous ZSM-48 (ANMZ-48) Directed by Metal Complexes in Amphiphilic Molecules

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Chen, Y., Deng, Q., Mao, Y. et al. Synthesis of atomically dispersed cationic nickel-confined mesoporous ZSM-48 (ANMZ-48) directed by metal complexes in amphiphilic molecules. Sci. China Chem. 67, 343–350 (2024). https://doi.org/10.1007/s11426-023-1823-9

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  • DOI: https://doi.org/10.1007/s11426-023-1823-9

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