Abstract
Constructing two-dimensional (2D) supramolecular polymers with complicated hierarchical porosity significantly contributes to developing effective strategies to control delicate self-assembly architectures, thus facilitating the fabrication of advanced 2D organic functional materials. Here, we report utilizing cooperative cation-π and electrostatic interactions to construct a series of robust 2D heteropore supramolecular polymers (2D HPSPs) with hierarchical pore structures, in which hexagonal and rectangular pores are alternately and periodically arranged, and the pore sizes can be finely tuned. Remarkably, the as-prepared 2D HPSPs exhibit excellent iodine (I2) capture rate (a maximum K80% value is 2.25 g h−1), and present a novel mechanism involving transport-adsorption spatiotemporal separation for rapid I2 capture. In this mechanism, the transport of free I2 is first conducted in large hexagonal pores, and then I2 can be preferentially adsorbed in small rectangular pores, thereby preventing the transfer channels from blocking and greatly improving the adsorption kinetics.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (22022107, 22071197). We would like to thank the Analytical & Testing Centre of Northwestern Polytechnical University for TEM, AFM, and SEM tests.
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Supporting information The supporting information is available online at https://chem.scichina.com and https://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.
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Cation-π and Electrostatic Interactions Co-Driven Assembly of Two-Dimensional Heteropore Supramolecular Polymers with Rapid Iodine Capture Capability
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Huo, H., Xiao, X., Chang, L. et al. Cation-π and electrostatic interactions co-driven assembly of two-dimensional heteropore supramolecular polymers with rapid iodine capture capability. Sci. China Chem. 66, 2070–2082 (2023). https://doi.org/10.1007/s11426-023-1611-7
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DOI: https://doi.org/10.1007/s11426-023-1611-7