Abstract
Selective semihydrogenation of acetylene in raw olefin streams to ethylene is a key industrial reaction to produce polymer-grade feeds for the manufacture of corresponding polymers. The currently used process in industry is the thermocatalytic acetylene semihydrogenation with pressurized hydrogen and Pd-based catalysts at relatively high temperatures. The high cost of Pd urgently desires the design of non-noble metal-based catalysts. However, non-noble metal-based catalysts commonly require much higher reaction temperatures than Pd-based catalysts because of their poor intrinsic activity. Therefore, aiming at increasing economic efficiency and sustainability, various strategies are explored for developing non-noble metal-based catalysts for thermocatalytic and green acetylene semihydrogenation processes. In this review, we systematically summarize the recent advances in catalytic technology from thermocatalysis to sustainable alternatives, as well as corresponding regulation strategies for designing high-performance non-noble metal-based catalysts. The crucial factors affecting catalytic performance are discussed, and the fundamental structure-performance correlation of catalysts is outlined. Meanwhile, we emphasize current challenging issues and future perspectives for acetylene semihydrogenation. This review will not only promote the rapid exploration of non-noble metal-based catalysts for acetylene semihydrogenation, but also advance the development of sustainable processes like electrocatalysis and photocatalysis.
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Crespo-Quesada M, Cárdenas-Lizana F, Dessimoz AL, Kiwi-Minsker L. ACS Catal, 2012, 2: 1773–1786
Torres Galvis HM, de Jong KP. ACS Catal, 2013, 3: 2130–2149
Garba MD, Jackson SD. Appl Petrochem Res, 2016, 7: 1–8
Nørskov JK, Bligaard T, Logadottir A, Bahn S, Hansen LB, Bollinger M, Bengaard H, Hammer B, Sljivancanin Z, Mavrikakis M, Xu Y, Dahl S, Jacobsen CJH. J Catal, 2002, 209: 275–278
Zhang L, Zhou M, Wang A, Zhang T. Chem Rev, 2020, 120: 683–733
Cui X, Chen K, Xing H, Yang Q, Krishna R, Bao Z, Wu H, Zhou W, Dong X, Han Y, Li B, Ren Q, Zaworotko MJ, Chen B. Science, 2016, 353: 141–144
Suo X, Cui X, Yang L, Xu N, Huang Y, He Y, Dai S, Xing H. Adv Mater, 2020, 32: 1907601
McCue AJ, Anderson JA. Front Chem Sci Eng, 2015, 9: 142–153
Rubinson JF, Behymer TD, Mark Jr. B. J Am Chem Soc, 1982, 104: 1224–1229
Mark Jr. HB, Rubinson JF, Krotine J, Vaughn W, Goldschmidt M. Electrochim Acta, 2000, 45: 4309–4313
Huang B, Wang T, Yang Z, Qian W, Long J, Zeng G, Lei C. ACS Sustain Chem Eng, 2017, 5: 1668–1674
Song XL, Du HY, Liang ZH, Zhu ZP, Duan DH, Liu SB. Int J Electrochem Sci, 2013, 8: 6566–6573
Bai R, Li J, Lin J, Liu Z, Yan C, Zhang L, Zhang J. CCS Chem, 2023, 5: 200–208
Chang SY, Bu J, Li JJ, Lin J, Liu ZP, Ma WX, Zhang J. Chin Chem Lett, 2022, 34: 107765
An S, Liu Z, Bu J, Lin J, Yao Y, Yan C, Tian W, Zhang J. Angew Chem Int Ed, 2022, 61: e202116370
Guo Y, Huang Y, Zeng B, Han B, Akri M, Shi M, Zhao Y, Li Q, Su Y, Li L, Jiang Q, Cui YT, Li L, Li R, Qiao B, Zhang T. Nat Commun, 2022, 13: 2648
Zhou S, Shang L, Zhao Y, Shi R, Waterhouse GIN, Huang YC, Zheng L, Zhang T. Adv Mater, 2019, 31: 1900509
Kyriakou G, Boucher MB, Jewell AD, Lewis EA, Lawton TJ, Baber AE, Tierney HL, Flytzani-Stephanopoulos M, Sykes ECH. Science, 2012, 335: 1209–1212
Jiang L, Liu K, Hung SF, Zhou L, Qin R, Zhang Q, Liu P, Gu L, Chen HM, Fu G, Zheng N. Nat Nanotechnol, 2020, 15: 848–853
García-Mota M, Gómez-Díaz J, Novell-Leruth G, Vargas-Fuentes C, Bellarosa L, Bridier B, Pérez-Ramírez J, López N. Theor Chem Acc, 2011, 128: 663–673
Wei S, Li A, Liu JC, Li Z, Chen W, Gong Y, Zhang Q, Cheong WC, Wang Y, Zheng L, Xiao H, Chen C, Wang D, Peng Q, Gu L, Han X, Li J, Li Y. Nat Nanotech, 2018, 13: 856–861
Shao L, Zhang B, Zhang W, Teschner D, Girgsdies F, Schlögl R, Su DS. Chem Eur J, 2012, 18: 14962–14966
Li M, Shen J. ThermoChim Acta, 2001, 379: 45–50
Hock S, Reichel CV, Zieschang AM, Albert B, Rose M. ACS Sustain Chem Eng, 2021, 9: 16570–16576
Bridier B, López N, Pérez-Ramírez J. J Catal, 2010, 269: 80–92
Studt F, Abild-Pedersen F, Bligaard T, Sørensen RZ, Christensen CH, Nørskov JK. Science, 2008, 320: 1320–1322
Gu J, Jian M, Huang L, Sun Z, Li A, Pan Y, Yang J, Wen W, Zhou W, Lin Y, Wang HJ, Liu X, Wang L, Shi X, Huang X, Cao L, Chen S, Zheng X, Pan H, Zhu J, Wei S, Li WX, Lu J. Nat Nanotechnol, 2021, 16: 1141–1149
Bridier B, Pérez-Ramírez J. J Am Chem Soc, 2010, 132: 4321–4327
Kojima T, Kameoka S, Fujii S, Ueda S, Tsai AP. Sci Adv, 2018, 4: eaat6063
Spanjers CS, Held JT, Jones MJ, Stanley DD, Sim RS, Janik MJ, Rioux RM. J Catal, 2014, 316: 164–173
Liu Y, Liu X, Feng Q, He D, Zhang L, Lian C, Shen R, Zhao G, Ji Y, Wang D, Zhou G, Li Y. Adv Mater, 2016, 28: 4747–4754
Cao Y, Zhang H, Ji S, Sui Z, Jiang Z, Wang D, Zaera F, Zhou X, Duan X, Li Y. Angew Chem Int Ed, 2020, 59: 11647–11652
Ge X, Dou M, Cao Y, Liu X, Yuwen Q, Zhang J, Qian G, Gong X, Zhou X, Chen L, Yuan W, Duan X. Nat Commun, 2022, 13: 5534
Armbrüster M, Kovnir K, Friedrich M, Teschner D, Wowsnick G, Hahne M, Gille P, Szentmiklósi L, Feuerbacher M, Heggen M, Girgsdies F, Rosenthal D, Schlögl R, Grin Y. Nat Mater, 2012, 11: 690–693
Ma J, Xing F, Nakaya Y, Shimizu KI, Furukawa S. Angew Chem Int Ed, 2022, 61: e202200889
Dai X, Chen Z, Yao T, Zheng L, Lin Y, Liu W, Ju H, Zhu J, Hong X, Wei S, Wu Y, Li Y. Chem Commun, 2017, 53: 11568–11571
Zhuo HY, Yu X, Yu Q, Xiao H, Zhang X, Li J. Sci China Mater, 2020, 63: 1741–1749
Chai Y, Wu G, Liu X, Ren Y, Dai W, Wang C, Xie Z, Guan N, Li L. J Am Chem Soc, 2019, 141: 9920–9927
Fu B, McCue AJ, Liu Y, Weng S, Song Y, He Y, Feng J, Li D. ACS Catal, 2021, 12: 607–615
Huang F, Deng Y, Chen Y, Cai X, Peng M, Jia Z, Xie J, Xiao D, Wen X, Wang N, Jiang Z, Liu H, Ma D. Nat Commun, 2019, 10: 4431
Shi X, Lin Y, Huang L, Sun Z, Yang Y, Zhou X, Vovk E, Liu X, Huang X, Sun M, Wei S, Lu J. ACS Catal, 2020, 10: 3495–3504
Fu F, Liu Y, Li Y, Fu B, Zheng L, Feng J, Li D. ACS Catal, 2021, 11: 11117–11128
Wang Y, Liu B, Lan X, Wang T. ACS Catal, 2021, 11: 10257–10266
Niu Y, Huang X, Wang Y, Xu M, Chen J, Xu S, Willinger MG, Zhang W, Wei M, Zhang B. Nat Commun, 2020, 11: 3324
Ge X, Ren Z, Cao Y, Liu X, Zhang J, Qian G, Gong X, Chen L, Zhou X, Yuan W, Duan X. J Mater Chem A, 2022, 10: 19722–19731
Lu C, Zeng A, Wang Y, Wang A. ACS Omega, 2021, 6: 3363–3371
Wang Y, Kang L. Catalysts, 2020, 10: 115
Hou C, Kang L, Zhu M. Molecules, 2022, 27: 5437
Zhou H, Li B, Fu H, Zhao X, Zhang M, Wang X, Liu Y, Yang Z, Lou X. ACS Sustain Chem Eng, 2022, 10: 4849–4861
Durante C. Nat Catal, 2021, 4: 537–538
Otsuka K, Yagi T. J Catal, 1994, 145: 289–294
Huang B, Durante C, Isse AA, Gennaro A. Electrochem Commun, 2013, 34: 90–93
Wang S, Uwakwe K, Yu L, Ye J, Zhu Y, Hu J, Chen R, Zhang Z, Zhou Z, Li J, Xie Z, Deng D. Nat Commun, 2021, 12: 7072
Bu J, Liu Z, Ma W, Zhang L, Wang T, Zhang H, Zhang Q, Feng X, Zhang J. Nat Catal, 2021, 4: 557–564
Shi R, Wang Z, Zhao Y, Waterhouse GIN, Li Z, Zhang B, Sun Z, Xia C, Wang H, Zhang T. Nat Catal, 2021, 4: 565–574
Chen Z, Cai C, Wang T. J Phys Chem C, 2022, 126: 3037–3042
Zhang L, Chen Z, Liu Z, Bu J, Ma W, Yan C, Bai R, Lin J, Zhang Q, Liu J, Wang T, Zhang J. Nat Commun, 2021, 12: 6574
Li J, Guo Y, Chang S, Lin J, Wang Y, Liu Z, Wu Y, Zhang J. Small, 2023, 19: 2205845
Ma W, Chen Z, Bu J, Liu Z, Li J, Yan C, Cheng L, Zhang L, Zhang H, Zhang J, Wang T, Zhang J. J Mater Chem A, 2022, 10: 6122–6128
Liu Z, Chen Z, Bu J, Ma W, Zhang L, Zhong H, Cheng L, Li S, Wang T, Zhang J. Chem Eng J, 2022, 431: 134129
Arcudi F, Đorđević L, Schweitzer N, Stupp SI, Weiss EA. Nat Chem, 2022, 14: 1007–1012
Acknowledgements
This work was supported by the National Natural Science Foundation of China (22005245, 52101271), the Fundamental Research Funds for the Central Universities (G2022KY0606, G2020KY05306, G2022KY05111), Guangdong Basic and Applied Basic Research Foundation (2020A1515111017), the Natural Science Foundation of Shaanxi Province (2021JQ–094), and the fellowship of China Postdoctoral Science Foundation (2021M692619).
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Zhang, L., Lin, J., Liu, Z. et al. Non-noble metal-based catalysts for acetylene semihydrogenation: from thermocatalysis to sustainable catalysis. Sci. China Chem. 66, 1963–1974 (2023). https://doi.org/10.1007/s11426-022-1597-y
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DOI: https://doi.org/10.1007/s11426-022-1597-y