Abstract
Extracting uranium from seawater offers opportunities for sustainable nuclear fuel supply, but the task is quite challenging due to the low uranium concentration (∼3 ppb) in seawater. Here, based on the Knoevenagel condensation reaction of aldehyde and acetonitrile groups, a novel stable sp2 carbon-linked three-dimensional covalent organic framework (3D COF), TFPM-PDAN-AO was prepared as a porous platform for uranium extraction from seawater. The TFPM-PDAN-AO designed with regular 3D pore channel of 7.12 Å provides a specific channel for uranyl diffusion, which exhibits high selectivity and fast kinetics for uranium adsorption. Meanwhile, the superior stability and optoelectronic properties enable it an excellent porous platform for uranium electroextraction. By applying alternating voltages between −5 and 0 V, uranyl ions can rapidly migrate and enrich into the porous structure of TFPM-PDAN-AO, then inducing the electrodeposition of uranium compounds to form the charge neutral species (Na2O(UO3H2O)x) with an unprecedentedly high adsorption capacity of 4,685 mg g−1. This work not only expands the application prospects of functionalized 3D COFs, but also provides a technical support for the electrodeposition adsorption of uranium from seawater.
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Wang Z, Meng Q, Ma R, Wang Z, Yang Y, Sha H, Ma X, Ruan X, Zou X, Yuan Y, Zhu G. Chem, 2020, 6: 1683–1691
Li Y, Guo X, Li X, Zhang M, Jia Z, Deng Y, Tian Y, Li S, Ma L. Angew Chem Int Ed, 2020, 59: 4168–4175
Yu F, Zhu Z, Wang S, Peng Y, Xu Z, Tao Y, Xiong J, Fan Q, Luo F. Chem Eng J, 2020, 412: 127558
Liu T, Zhang X, Wang H, Chen M, Yuan Y, Zhang R, Xie Z, Liu Y, Zhang H, Wang N. Chem Eng J, 2021, 412: 128700
Yang H, Liu X, Hao M, Xie Y, Wang X, Tian H, Waterhouse GIN, Kruger PE, Telfer SG, Ma S. Adv Mater, 2021, 33: 2106621
Cui WR, Li FF, Xu RH, Zhang CR, Chen XR, Yan RH, Liang RP, Qiu JD. Angew Chem Int Ed, 2020, 59: 2–9
Cui WR, Zhang CR, Jiang W, Li FF, Liang RP, Liu J, Qiu JD. Nat Commun, 2020, 11: 436
Zhang CR, Cui WR, Xu RH, Chen XR, Jiang W, Wu YD, Yan RH, Liang RP, Qiu JD. CCS Chem, 2021, 3: 168–179
Gao Z, Wang Y, Lin Y, Zheng Z, Liu Y, Jing Q, Luo F. Sci China Chem, 2022, 65: 1544–1551
Liu W, Dai X, Bai Z, Wang Y, Yang Z, Zhang L, Xu L, Chen L, Li Y, Gui D, Diwu J, Wang J, Zhou R, Chai Z, Wang S. Environ Sci Technol, 2017, 51: 3911–3921
Cui WR, Zhang CR, Liang RP, Qiu JD. J Mater Chem A, 2021, 9: 25611–25620
Zhang CR, Cui WR, Niu CP, Yi SM, Liang RP, Qi JX, Chen XJ, Jiang W, Zhang L, Qiu JD. Chem Eng J, 2022, 428: 131178
Zhang C, Li X, Chen Z, Wen T, Huang S, Hayat T, Alsaedi A, Wang X. Sci China Chem, 2018, 61: 281–293
Yan RH, Cui WR, Zhang CR, Li XJ, Huang J, Jiang W, Liang RP, Qiu JD. Chem Eng J, 2021, 420: 129658
Zhang L, Pu N, Yu B, Ye G, Chen J, Xu S, Ma S. ACS Appl Mater Interfaces, 2020, 12: 3688–3696
Sun Q, Aguila B, Perman J, Ivanov AS, Bryantsev VS, Earl LD, Abney CW, Wojtas L, Ma S. Nat Commun, 2018, 9: 1644
Wang Z, Ma R, Meng Q, Yang Y, Ma X, Ruan X, Yuan Y, Zhu G. J Am Chem Soc, 2021, 143: 14523–14529
Zheng T, Yang Z, Gui D, Liu Z, Wang X, Dai X, Liu S, Zhang L, Gao Y, Chen L, Sheng D, Wang Y, Diwu J, Wang J, Zhou R, Chai Z, Albrecht-Schmitt TE, Wang S. Nat Commun, 2017, 8: 15369
Zhang H, Liu W, Li A, Zhang D, Li X, Zhai F, Chen L, Chen L, Wang Y, Wang S. Angew Chem Int Ed, 2019, 58: 16110–16114
Cui WR, Zhang CR, Xu RH, Chen XR, Jiang W, Li YJ, Liang RP, Zhang L, Qiu JD. Appl Catal B-Environ, 2021, 294: 120250
Zhang Y, Li H, Chang J, Guan X, Tang L, Fang Q, Valtchev V, Yan Y, Qiu S. Small, 2021, 17: 2006112
Ben H, Yan G, Liu H, Ling C, Fan Y, Zhang X. Adv Funct Mater, 2022, 32: 2104519
Shi X, Yi L, Deng H. Sci China Chem, 2022, 65: 1315–1320
Chen X, Wang H. Sci China Chem, 2022, 65: 1453–1454
Li Y, Yan C, Li Q, Cao L. Sci China Chem, 2022, 65: 1279–1285
Li J, Zhao S, Wang B, Feng X. Sci China Chem, 2022, 65: 836–839
Wang C, Wang Y, Ge R, Song X, Xing X, Jiang Q, Lu H, Hao C, Guo X, Gao Y, Jiang D. Chem Eur J, 2018, 24: 585–589
Wang LL, Yang CX, Yan XP. Sci China Chem, 2018, 61: 1470–1474
Zhang CR, Cui WR, Jiang W, Li FF, Wu YD, Liang RP, Qiu JD. Environ Sci-Nano, 2020, 7: 842–850
Niu CP, Zhang CR, Cui WR, Yi SM, Liang RP, Qiu JD. J Hazard Mater, 2022, 425: 127951
Li FF, Cui WR, Jiang W, Zhang CR, Liang RP, Qiu JD. J Hazard Mater, 2020, 392: 122333
Xiong XH, Yu ZW, Gong LL, Tao Y, Gao Z, Wang L, Yin WH, Yang LX, Luo F. Adv Sci, 2019, 6: 1900547
Sun Q, Aguila B, Earl LD, Abney CW, Wojtas L, Thallapally PK, Ma S. Adv Mater, 2018, 30: 1705479
Song Y, Li A, Li P, He L, Xu D, Wu F, Zhai F, Wu Y, Hu K, Wang S, Sheridan MV. Chem Mater, 2022, 34: 2771–2778
Lu Q, Ma Y, Li H, Guan X, Yusran Y, Xue M, Fang Q, Yan Y, Qiu S, Valtchev V. Angew Chem Int Ed, 2018, 57: 6042–6048
Ding H, Li J, Xie G, Lin G, Chen R, Peng Z, Yang C, Wang B, Sun J, Wang C. Nat Commun, 2018, 9: 5234
Bunck DN, Dichtel WR. Angew Chem Int Ed, 2012, 51: 1885–1889
Liao L, Zhang Z, Guan X, Li H, Liu Y, Zhang M, Tang B, Valtchev V, Yan Y, Qiu S, Yao X, Fang Q. Chin J Chem, 2022, 40: 2081–2088
Wang S, Li XX, Da L, Wang Y, Xiang Z, Wang W, Zhang YB, Cao D. J Am Chem Soc, 2021, 143: 15562–15566
Jin E, Asada M, Xu Q, Dalapati S, Addicoat MA, Brady MA, Xu H, Nakamura T, Heine T, Chen Q, Jiang D. Science, 2017, 357: 673–676
Jin E, Li J, Geng K, Jiang Q, Xu H, Xu Q, Jiang D. Nat Commun, 2018, 9: 4143
Ma C, Gao J, Wang D, Yuan Y, Wen J, Yan B, Zhao S, Zhao X, Sun Y, Wang X, Wang N. Adv Sci, 2019, 6: 1900085
Chen R, Shi J, Ma Y, Lin G, Lang X, Wang C. Angew Chem Int Ed, 2019, 58: 6430–6434
Xu S, Richter M, Feng X. Acc Mater Res, 2021, 2: 252–265
Yu Q, Yuan Y, Feng L, Feng T, Sun W, Wang N. Angew Chem Int Ed, 2020, 59: 15997–16001
Yu J, Yuan L, Wang S, Lan J, Zheng L, Xu C, Chen J, Wang L, Huang Z, Tao W, Liu Z, Chai Z, Gibson JK, Shi W. CCS Chem, 2019, 1: 286–295
Wen R, Li Y, Zhang M, Guo X, Li X, Li X, Han J, Hu S, Tan W, Ma L, Li S. J Hazard Mater, 2018, 358: 273–285
Wu T, Liu C, Kong B, Sun J, Gong Y, Liu K, Xie J, Pei A, Cui Y. ACS Cent Sci, 2019, 5: 719–726
Liu C, Hsu PC, Xie J, Zhao J, Wu T, Wang H, Liu W, Zhang J, Chu S, Cui Y. Nat Energy, 2017, 2: 17007
Wang C, Helal AS, Wang Z, Zhou J, Yao X, Shi Z, Ren Y, Lee J, Chang JK, Fugetsu B, Li J. Adv Mater, 2021, 33: 2102633
Wang W, Luo J, Wei W, Liu S, He J, Ma J. Chemosphere, 2021, 271: 129531
Liu X, Xie Y, Hao M, Chen Z, Yang H, Waterhouse GIN, Ma S, Wang X. Adv Sci, 2022, 9: 2201735
Zhang J, Zhou L, Jia Z, Li X, Qi Y, Yang C, Guo X, Chen S, Long H, Ma L. Nanoscale, 2020, 12: 24044–24053
Ye H, Li TH, Huang YQ, Jin JM, Fei JY, Wu MB, Yao J. Chem Eng J, 2023, 451: 138615
Acknowledgements
This work was supported by the National Natural Science Foundation of China (22036003, 21976077) and the Natural Science Foundation of Jiangxi Province (20212ACB203009, 20212ACB203011).
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Supporting information The supporting information is available online at http://chem.scichina.com and http://link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.
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Zhang, CR., Qi, JX., Cui, WR. et al. A novel 3D sp2 carbon-linked covalent organic framework as a platform for efficient electro-extraction of uranium. Sci. China Chem. 66, 562–569 (2023). https://doi.org/10.1007/s11426-022-1466-9
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DOI: https://doi.org/10.1007/s11426-022-1466-9