Abstract
Carbon dioxide (CO2) is an important and appealing C1 building block in chemical synthesis due to its nontoxicity, abundance, availability and sustainability. Tremendous progress has been achieved in the chemical transformation of CO2 into high value-added organic chemicals. However, the asymmetric synthesis with CO2 to form enantioenriched molecules, especially the catalytic process, has lagged far behind. The enantioselective incorporation of CO2 into organic compounds is highly desirable, as the corresponding chiral products, such as carboxylic acids and amino acids, are common structural units in a vast array of natural products and biologically active compounds. Herein, we discuss recent progress toward the enantioselective incorporation of CO2 into organic molecules, which mainly rely on three strategies: 1) kinetic resolution or desymmetrization of epoxides with CO2 to form chiral cyclic carbonates and polycarbonates; 2) nucleophilic attack of O- or N-nucleophiles to CO2 in tandem with asymmetric C−O bond formation to prepare chiral cyclic carbonates and carbamates; 3) direct enantioselective nucleophilic attack of organometallic reagents to CO2 with asymmetric C−C bond formation. Finally, challenges and future outlook in this area are also presented.
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References
Song C. Catal Today, 2006, 115: 2–32
von der Assen N, Voll P, Peters M, Bardow A. Chem Soc Rev, 2014, 43: 7982–7994
Li L, Zhao N, Wei W, Sun Y. Fuel, 2013, 108: 112–130
Burkart MD, Hazari N, Tway CL, Zeitler EL. ACS Catal, 2019, 9: 7937–7956
Aresta M, ed. Carbon Dioxide as Chemical Feedstock. Wiley-VCH: Weinheim, 2010
Huang K, Sun CL, Shi ZJ. Chem Soc Rev, 2011, 40: 2435–2452
Martin R, Kleij AW. ChemSusChem, 2011, 4: 1259–1263
Tsuji Y, Fujihara T. Chem Commun, 2012, 48: 9956–9964
Zhang L, Hou Z. Chem Sci, 2013, 4: 3395–3403
He M, Sun Y, Han B. Angew Chem Int Ed, 2013, 52: 9620–9633
Liu Q, Wu L, Jackstell R, Beller M. Nat Commun, 2015, 6: 5933–5945
Yu D, Teong SP, Zhang Y. Coord Chem Rev, 2015, 293–294: 279–291
Zhu Q, Wang L, Xia C, Liu C. Chin J Org Chem, 2016, 36: 2813–2821
Tortajada A, Juliá-Hernández F, Börjesson M, Moragas T, Martin R. Angew Chem Int Ed, 2018, 57: 15948–15982
Chen YG, Xu XT, Zhang K, Li YQ, Zhang LP, Fang P, Mei TS. Synthesis, 2018, 50: 35–48
Yan SS, Fu Q, Liao LL, Sun GQ, Ye JH, Gong L, Bo-Xue YZ, Yu DG. Coord Chem Rev, 2018, 374: 439–463
Sakakura T, Choi JC, Yasuda H. Chem Rev, 2007, 107: 2365–2387
Sekine K, Yamada T. Chem Soc Rev, 2016, 45: 4524–4532
Yang Y, Lee JW. Chem Sci, 2019, 10: 3905–3926
Fujihara T, Tsuji Y. Front Chem, 2019, 7: 430–437
Song J, Liu Q, Liu H, Jiang X. Eur J Org Chem, 2018, 2018: 696–713
Luan YX, Ye M. Tetrahedron Lett, 2018, 59: 853–861
Bhanage BM, Arai M, eds. Transformation and Utilization of Carbon Dioxide. Berlin, Heidelberg: Springer-Verlag, 2014
Lu XB, ed. Carbon Dioxide and Organometallics. Heidelberg: Springer, 2016
Zhang L, Li Z, Takimoto M, Hou Z. Chem Rec, 2020, 20: 494–512
Hong J, Li M, Zhang J, Sun B, Mo F. ChemSusChem, 2019, 12: 6–39
Tappe NA, Reich RM, D’Elia V, Kühn FE. Dalton Trans, 2018, 47: 13281–13313
Wu XF, Zheng F. Top Curr Chem (Z), 2017, 375: 4–6
Janes T, Yang Y, Song D. Chem Commun, 2017, 53: 11390–11398
Zhang L, Hou Z. Curr Opin Green Sustain Chem, 2017, 3: 17–21
Hu J, Liu H, Han B. Sci China Chem, 2018, 61: 1486–1493
Cokoja M, Wilhelm ME, Anthofer MH, Herrmann WA, Kühn FE. ChemSusChem, 2015, 8: 2436–2454
Cao Y, He X, Wang N, Li HR, He LN. Chin J Chem, 2018, 36: 644–659
Zhao Y, Liu Z. Chin J Chem, 2018, 36: 455–460
Tan F, Yin G. Chin J Chem, 2018, 36: 545–554
Hou J, Li JS, Wu J. Asian J Org Chem, 2018, 7: 1439–1447
Yeung CS. Angew Chem Int Ed, 2019, 58: 5492–5502
Gui YY, Zhou WJ, Ye JH, Yu DG. ChemSusChem, 2017, 10: 1337–1340
Zhang Z, Gong L, Zhou XY, Yan SS, Li J, Yu DG. Acta Chim Sin, 2019, 77: 783–793
Senboku H, Katayama A. Curr Opin Green Sustain Chem, 2017, 3: 50–54
Zhang Z, Ye JH, Wu DS, Zhou YQ, Yu DG. Chem Asian J, 2018, 13: 2292–2306
Wang S, Xi C. Chem Soc Rev, 2019, 48: 382–404
Zhang Z, Ju T, Ye JH, Yu DG. Synlett, 2017, 28: 741–750
Zhang W, Zhang N, Guo C, Lü X. Chin J Org Chem, 2017, 37: 1309–1321
Pulla S, Felton CM, Ramidi P, Gartia Y, Ali N, Nasini UB, Ghosh A. J CO2Utilization, 2013, 2: 49–57
Lu XB, Darensbourg DJ. Chem Soc Rev, 2012, 41: 1462–1484
North M, Pasquale R, Young C. Green Chem, 2010, 12: 1514–1539
Song L, Jiang Y, Zhang Z, Gui Y, Zhou X, Yu DG. Chem Commun, 2020, 12: https://doi.org/10.1039/d0cc00547a
Wu L, Liu Q, Jackstell R, Beller M. Angew Chem Int Ed, 2014, 53: 6310–6320
Tlili A, Blondiaux E, Frogneux X, Cantat T. Green Chem, 2015, 17: 157–168
Li X, He X, Liu X, He LN. Sci China Chem, 2017, 60: 841–852
Li Y, Cui X, Dong K, Junge K, Beller M. ACS Catal, 2017, 7: 1077–1086
Beydoun K, Klankermayer J. Top Organomet Chem, 2018, 63: 39–76
He X, Cao Y, Lang XD, Wang N, He LN. ChemSusChem, 2018, 11: 3382–3387
Wang L, Sun W, Liu C. Chin J Chem, 2018, 36: 353–362
Cabrero-Antonino JR, Adam R, Beller M. Angew Chem Int Ed, 2019, 58: 12820–12838
Liu XF, Li XY, Qiao C, He LN. Synlett, 2018, 29: 548–555
Hulla M, Dyson PJ. Angew Chem Int Ed, 2020, 59: 1002–1017
Zhang Y, Zhang T, Das S. Green Chem, 2020, 22: 1800–1820
Kielland N, Whiteoak CJ, Kleij AW. Adv Synth Catal, 2013, 355: 2115–2138
Vaitla J, Guttormsen Y, Mannisto JK, Nova A, Repo T, Bayer A, Hopmann KH. ACS Catal, 2017, 7: 7231–7244
Childers MI, Longo JM, Van Zee NJ, LaPointe AM, Coates GW. Chem Rev, 2014, 114: 8129–8152
Jacobsen EN, Pfaltz A, Yamamoto H, eds. Comprehensive Asymmetric Catalysis. New York: Springer, 2000
Carreira EM, Yamamoto H. eds. Comprehensive Chirality. Oxford: Elsevier, 2012
Patai S, ed. The Chemistry of Acid Derivatives. New York: Wiley, 1992
Gooßen L, Rodriguez N, Gooßen K. Angew Chem Int Ed, 2008, 47: 3100–3120
Maag H, ed. Prodrugs of Carboxylic Acids. New York: Springer, 2007
Beller M, ed. Catalytic Carbonylation Reactions. Berlin: Springer, 2006
Borner A, Franke R, eds. Hydroformylation: Fundamentals, Processes, and Applications in Organic Synthesis. Weinheim: Wiley-VCH, 2016
BKckvall JE, ed. Modern Oxidation Methods. Weinheim: Wiley-VCH, 2004
Haines AH, ed. Methods for the Oxidation of Organic Compounds. New York: Academic Press, 1985
For reviews on the application of organic cyclic carbonates, see: Shaikh AAG, Sivaram S. Chem Rev, 1996, 96: 951–976
Schaffner B, Schaffner F, Verevkin SP, Borner A. Chem Rev, 2010, 110: 4554–4581
Lu XB, Liang B, Zhang YJ, Tian YZ, Wang YM, Bai CX, Wang H, Zhang R. J Am Chem Soc, 2004, 126: 3732–3733
Ren WM, Wu GP, Lin F, Jiang JY, Liu C, Luo Y, Lu XB. Chem Sci, 2012, 3: 2094–2102
Paddock RL, Nguyen SBT. Chem Commun, 2004, 1: 1622–1623
Tanaka H, Kitaichi Y, Sato M, Ikeno T, Yamada T. Chem Lett, 2004, 33: 676–677
Berkessel A, Brandenburg M. Org Lett, 2006, 8: 4401–4404
Chen SW, Kawthekar RB, Kim GJ. Tetrahedron Lett, 2007, 48: 297–300
Kawthekar RB, Bi W.T, Kim GJ. Bull Korean Chem Soc, 2008, 29: 313–318
Chang T, Jing H, Jin L, Qiu W. J Mol Catal A-Chem, 2007, 264: 241–247
Jin L, Huang Y, Jing H, Chang T, Yan P. Tetrahedron-Asymmetry, 2008, 19: 1947–1953
Chang T, Jin L, Jing H. ChemCatChem, 2009, 1: 379–383
Zhang S, Song Y, Jing H, Yan P, Cai Q. Chin J Catal, 2009, 30: 1255–1260
Yan P, Jing H. Adv Synth Catal, 2009, 351: 1325–1332
Roy T, Kureshy RI, Khan NH, Abdi SHR, Bajaj HC. Catal Sci Technol, 2013, 3: 2661–2667
Ren Y, Cheng X, Yang S, Qi C, Jiang H, Mao Q. Dalton Trans, 2013, 42: 9930–9937
North M, Quek SCZ, Pridmore NE, Whitwood AC, Wu X. ACS Catal, 2015, 5: 3398–3402
Qin J, Larionov VA, Harms K, Meggers E. ChemSusChem, 2019, 12: 320–325
Ema T, Yokoyama M, Watanabe S, Sasaki S, Ota H, Takaishi K. Org Lett, 2017, 19: 4070–4073
Lu XB, Ren WM, Wu GP. Acc Chem Res, 2012, 45: 1721–1735
Childers MI, Longo JM, Van Zee NJ, LaPointe AM, Coates GW. Chem Rev, 2014, 114: 8129–8152
Lu XB. Top Organomet Chem, 2015, 53: 171–198
Monfared A, Mohammadi R, Hosseinian A, Sarhandi S, Kheirollahi Nezhad PD. RSC Adv, 2019, 9: 3884–3899
Grignard B, Gennen S, Jérôme C, Kleij AW, Detrembleur C. Chem Soc Rev, 2019, 48: 4466–4514
Allen SD, Moore DR, Lobkovsky EB, Coates GW. J Am Chem Soc, 2002, 124: 14284–14285
Qin Z, Thomas CM, Lee S, Coates GW. Angew Chem Int Ed, 2003, 42: 5484–5487
Lu XB, Wang Y. Angew Chem Int Ed, 2004, 43: 3574–3577
Ren WM, Liu Y, Wu GP, Liu J, Lu XB. J Polym Sci A Polym Chem, 2011, 49: 4894–4901
Ren WM, Zhang WZ, Lu XB. Sci China Chem, 2010, 53: 1646–1652
Nakano K, Hashimoto S, Nakamura M, Kamada T, Nozaki K. Angew Chem Int Ed, 2011, 50: 4868–4871
Wu GP, Xu PX, Lu XB, Zu YP, Wei SH, Ren WM, Darensbourg DJ. Macromolecules, 2013, 46: 2128–2133
Inoue S, Koinuma H, Tsuruta T. J Polym Sci B Polym Lett, 1969, 7: 287–292
Inoue S, Koinuma H, Tsuruta T. Makromol Chem, 1969, 130: 210–220
Wilks ES, ed. Industrial Polymers Handbook. Weinheim: Wiley-VCH, 2001. 291–304
Luinstra G. Polym Revs, 2008, 48: 192–219
Gomez FJ, Waymouth RM. Science, 2002, 295: 635–636
Nakano K, Kosaka N, Hiyama T, Nozaki K. Dalton Trans, 2003, 1: 4039–4050
Worch JC, Prydderch H, Jimaja S, Bexis P, Becker ML, Dove AP. Nat Rev Chem, 2019, 3: 514–535
Nozaki K, Nakano K, Hiyama T. J Am Chem Soc, 1999, 121: 11008–11009
Nakano K, Nozaki K, Hiyama T. J Am Chem Soc, 2003, 125: 5501–5510
Cheng M, Darling NA, Lobkovsky EB, Coates GW. Chem Commun, 2000, 1: 2007–2008
Ellis WC, Jung Y, Mulzer M, Di Girolamo R, Lobkovsky EB, Coates GW. Chem Sci, 2014, 5: 4004–4011
Xiao Y, Wang Z, Ding K. Chem Eur J, 2005, 11: 3668–3678
Xiao Y, Wang Z, Ding K. Macromolecules, 2006, 39: 128–137
Hua YZ, Yang XC, Liu MM, Song X, Wang MC, Chang JB. Macromolecules, 2015, 48: 1651–1657
Abbina S, Du G. Organometallics, 2012, 31: 7394–7403
Wu GP, Ren WM, Luo Y, Li B, Zhang WZ, Lu XB. JAm Chem Soc, 2012, 134: 5682–5688
Liu Y, Ren WM, Liu J, Lu XB. Angew Chem Int Ed, 2013, 52: 11594–11598
Liu Y, Ren WM, He KK, Zhang WZ, Li WB, Wang M, Lu XB. J Org Chem, 2016, 81: 8959–8966
Jacobsen EN, Tokunaga M, Larrow JF. Stereoselective ring opening reactions. World Patent, WO/2000/09463, 2000-03-14
Li B, Zhang R, Lu XB. Macromolecules, 2007, 40: 2303–2307
Nakano K, Nakamura M, Nozaki K. Macromolecules, 2009, 42: 6972–6980
Nishioka K, Goto H, Sugimoto H. Macromolecules, 2012, 45: 8172–8192
Yoshida M, Fujita M, Ishii T, Ihara M. J Am Chem Soc, 2003, 125: 4874–4881
Yoshida S, Fukui K, Kikuchi S, Yamada T. J Am Chem Soc, 2010, 132: 4072–4073
Vara BA, Struble TJ, Wang W, Dobish MC, Johnston JN. J Am Chem Soc, 2015, 137: 7302–7305
Yousefi R, Struble TJ, Payne JL, Vishe M, Schley ND, Johnston JN. J Am Chem Soc, 2019, 141: 618–625
Barbachyn MR, Ford CW. Angew Chem Int Ed, 2003, 42: 2010–2023
Mukhtar TA, Wright GD. Chem Rev, 2005, 105: 529–542
Gao XT, Gan CC, Liu SY, Zhou F, Wu HH, Zhou J. ACS Catal, 2017, 7: 8588–8593
Zhang M, Zhao X, Zheng S. Chem Commun, 2014, 50: 4455–4458
Zheng SC, Zhang M, Zhao XM. Chem Eur J, 2014, 20: 7216–7221
Xie S, Gao X, Zhou F, Wu H, Zhou J. Chin Chem Lett, 2020, 31: 324–328
Kerrick ST, Beak P. J Am Chem Soc, 1991, 113: 9708–9710
Park YS, Beak P. J Org Chem, 1997, 62: 1574–1575
Schlosser M, Limat D. J Am Chem Soc, 1995, 117: 12342–12343
Chong JM, Park SB. J Org Chem, 1992, 57: 2220–2222
Jeanjean F, Fournet G, Bars DL, Goré J. Eur J Org Chem, 2000, 2000: 1297–1305
Mita T, Sugawara M, Hasegawa H, Sato Y. J Org Chem, 2012, 77: 2159–2168
Mita T, Sugawara M, Saito K, Sato Y. Org Lett, 2014, 16: 3028–3031
Perron Q, Alexakis A. Adv Synth Catal, 2010, 352: 2611–2620
For selected reviews: see refs. 4l, 4r, 4z; For selected examples: Williams CM, Johnson JB, Rovis T. J Am Chem Soc, 2008, 130: 14936–14937
Takaya J, Iwasawa N. J Am Chem Soc, 2008, 130: 15254–15255
Zhang L, Cheng J, Carry B, Hou Z. J Am Chem Soc, 2012, 134: 14314–14317
Wang X, Nakajima M, Martin R. J Am Chem Soc, 2015, 137: 8924–8927
Butcher TW, McClain EJ, Hamilton TG, Perrone TM, Kroner KM, Donohoe GC, Akhmedov NG, Petersen JL, Popp BV. Org Lett, 2016, 18: 6428–6431
Tortajada A, Ninokata R, Martin R. J Am Chem Soc, 2018, 140: 2050–2053
Takimoto M, Mori M. J Am Chem Soc, 2002, 124: 10008–10009
Takimoto M, Nakamura Y, Kimura K, Mori M. J Am Chem Soc, 2004, 126: 5956–5957
Ishii M, Mori F, Tanaka K. Chem Eur J, 2014, 20: 2169–2174
Kawashima S, Aikawa K, Mikami K. Eur J Org Chem, 2016, 2016: 3166–3170
Dian L, Müller DS, Marek I. Angew Chem Int Ed, 2017, 56: 6783–6787
Pirnot MT, Wang YM, Buchwald SL. Angew Chem Int Ed, 2016, 55: 48–57
Gui YY, Hu N, Chen XW, Liao L, Ju T, Ye JH, Zhang Z, Li J, Yu DG. J Am Chem Soc, 2017, 139: 17011–17014
Qiu J, Gao S, Li C, Zhang L, Wang Z, Wang X, Ding K. Chem Eur J, 2019, 25: 13874–13878
Chen XW, Zhu L, Gui YY, Jing K, Jiang YX, Bo ZY, Lan Y, Li J, Yu DG. J Am Chem Soc, 2019, 141: 18825–18835
Cheng L, Xie J. Chin J Org Chem, 2020, 40: 247–248
For selected reviews, see: Jutand A. Chem Rev, 2008, 108: 2300–2347
Yan M, Kawamata Y, Baran PS. Chem Rev, 2017, 117: 13230–13319
Sauermann N, Meyer TH, Qiu Y, Ackermann L. ACS Catal, 2018, 8: 7086–7103
Tang S, Liu Y, Lei A. Chem, 2018, 4: 27–45
Sauer GS, Lin S. ACS Catal, 2018, 8: 5175–5187
Yang QL, Fang P, Mei TS. Chin J Chem, 2018, 36: 338–352
Xiong P, Xu HC. Acc Chem Res, 2019, 52: 3339–3350
Chang X, Zhang Q, Guo C. Angew Chem Int Ed, 2020, https://doi.org/10.1002/anie.202000016
Matthessen R, Fransaer J, Binnemans K, De Vos DE. Beilstein J Org Chem, 2014, 10: 2484–2500
Feroci M, Orsini M, Palombi L, Sotgiu G, Colapietro M, Inesi A. J Org Chem, 2004, 69: 487–494
Feroci M, Inesi A, Orsini M, Palombi L. Org Lett, 2002, 4: 2617–2620
Orsini M, Feroci M, Sotgiu G, Inesi A. Org Biomol Chem, 2005, 3: 1202–1208
Zhang K, Wang H, Zhao SF, Niu DF, Lu JX. J Electroanal Chem, 2009, 630: 35–41
Zhao SF, Zhu MX, Zhang K, Wang H, Lu JX. Tetrahedron Lett, 2011, 52: 2702–2705
Chen BL, Tu ZY, Zhu HW, Sun WW, Wang H, Lu JX. Electrochim Acta, 2014, 116: 475–483
Chen BL, Zhu HW, Xiao Y, Sun QL, Wang H, Lu JX. Electrochem Commun, 2014, 42: 55–59
Jiao KJ, Li ZM, Xu XT, Zhang LP, Li YQ, Zhang K, Mei TS. Org Chem Front, 2018, 5: 2244–2248
Acknowledgements
This work was supported by the National Natural Science Foundation of China (21801176, 91956111), the Sichuan Science and Technology Program (2019YJ0379, 20CXTD0112) and the Fundamental Research Funds for the Central Universities.
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Ran, CK., Chen, XW., Gui, YY. et al. Recent advances in asymmetric synthesis with CO2. Sci. China Chem. 63, 1336–1351 (2020). https://doi.org/10.1007/s11426-020-9788-2
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DOI: https://doi.org/10.1007/s11426-020-9788-2