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Iridium complex of porphycene: a new member of metalloporphycene

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  • Special Issue: Celebrating the 100th Anniversary of Chemical Science in Nanjing University
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Abstract

Iridium(III) porphycene complex was synthesized and structurally characterized for the first time. The introduction of the posttransition iridium(III) ion not only significantly enhances the absorption intensity at the end of visible region, but also displays efficient singlet oxygen quantum yield (76%), which is applicable for photodynamic therapy in living cells.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21771102, 21911540069, 21601052, 21603062, 21877027), the Program for Science Technology Innovation Teams in Universities of Henan Province (19IRTSTHN023), the Key Program for High School of Henan Province (16A150012). The theoretical calculations were carried out at the Center for High-Performance Computing in Nanjing University and the High Performance Computing (HPC) Centre of Henan Normal University.

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210046, China

    Yi Chang, Fan Wu, Yue Zhao, Kin Shing Chan & Zhen Shen

  2. Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China

    Yi Chang, Fei Zhao, Nana Ma & Xiaoming Ma

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  1. Yi Chang
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  2. Fei Zhao
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  3. Fan Wu
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  4. Nana Ma
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  5. Xiaoming Ma
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  6. Yue Zhao
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  7. Kin Shing Chan
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  8. Zhen Shen
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Correspondence to Xiaoming Ma or Zhen Shen.

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The authors declare that they have no conflict of interest.

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Chang, Y., Zhao, F., Wu, F. et al. Iridium complex of porphycene: a new member of metalloporphycene. Sci. China Chem. 63, 682–686 (2020). https://doi.org/10.1007/s11426-019-9693-1

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  • DOI: https://doi.org/10.1007/s11426-019-9693-1

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