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Visible-light-promoted oxidative coupling of styrene with cyclic ethers

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Abstract

A new visible-light-promoted oxidative coupling of vinylarenes with cyclic ethers has been developed using rose bengal as photocatalyst and tert-butyl hydrogenperoxide (TBHP) as oxidant under ambient air at room temperature. A library of α-oxyalkylated ketones with broad functionalities has been synthesized in moderate to good yields. A radical mechanism is suggested for the present protocol

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Acknowledgements

This work was supported by Council of Scientific and Industrial Research (CSIR), and New Delhi (02(0307)/17/EMR-II). D.G thanks University Grants Commission (UGC) (DSK) for his fellowship.

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Authors and Affiliations

  1. Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India

    Golam Kibriya, Debashis Ghosh & Alakananda Hajra

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  1. Golam Kibriya
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  2. Debashis Ghosh
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  3. Alakananda Hajra
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Correspondence to Alakananda Hajra.

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Kibriya, G., Ghosh, D. & Hajra, A. Visible-light-promoted oxidative coupling of styrene with cyclic ethers. Sci. China Chem. 63, 42–46 (2020). https://doi.org/10.1007/s11426-019-9609-9

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