Abstract
The rational design of robust photoactive material and artful sensing strategy are vital for the construction of an ultrasensitive photoelectrochemical (PEC) sensor. Although great progress has been made in PEC sensing, the resultant detection performances and adoptable sensing strategies are still limited. Herein, through the design of a subtle component reconstitution strategy, an ultrasensitive PEC sensor is developed for the detection of Cu2+ based on advanced CuS/CdS nanohybrids (NHs). This proposed sensor shows superior sensing performances with a low detection limit of 0.1 nM and a wide detection range from 0.2 nM to 60 µM due to the formation of p-n junction between CuS and CdS and the component transformation of CdS to CuxS (x = 1,2). Moreover, such PEC sensor also displays goodish results for monitoring the Cu2+ released from apoptotic HeLa cells in vitro. This idea of component reconstitution provides a new paradigm for the design of advanced PEC sensors.
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Tang J, Li J, Zhang Y, Kong B, Yiliguma B, Wang Y, Quan Y, Cheng H, Al-Enizi AM, Gong X, Zheng G. Anal Chem, 2015, 87: 6703–6708
Cotruvo Jr JA, Aron AT, Ramos-Torres KM, Chang CJ. Chem Soc Rev, 2015, 44: 4400–4414
Zhao XP, Wang SS, Younis MR, Xia XH, Wang C. Anal Chem, 2018, 90: 896–902
Liu X, Zhang N, Bing T, Shangguan D. Anal Chem, 2014, 86: 2289–2296
Jin LH, Han CS. Anal Chem, 2014, 86: 7209–7213
Liu Y, Ding D, Zhen Y, Guo R. Biosens Bioelectron, 2017, 92: 140–146
Ma Y, Li Y, Ma K, Wang Z. Sci China Chem, 2018, 61: 643–655
Li J, Zhao T, Chen T, Liu Y, Ong CN, Xie J. Nanoscale, 2015, 7: 7502–7519
Dong YX, Cao JT, Wang B, Ma SH, Liu YM. ACS Appl Mater Interfaces, 2018, 10: 3723–3731
Li X, Wang X, Zhang L, Gong J. ACS Sens, 2018, 3: 1480–1488
Li R, Tu W, Wang H, Dai Z. Anal Chem, 2018, 90: 9403–9409
Meng L, Li Y, Yang R, Zhang X, Du C, Chen J. Chem Commun, 2019, 55: 2182–2185
Yang R, Li Y, Zou K, Meng L, Zhang X, Chen J. Chem Commun, 2018, 54: 4830–4833
Wang B, Cao JT, Dong YX, Liu FR, Fu XL, Ren SW, Ma SH, Liu YM. Chem Commun, 2018, 54: 806–809
Wen G, Wang P, Tu W, Lei J, Ju H. Sci China Chem, 2015, 58: 879–884
Xu R, Wei D, Du B, Cao W, Fan D, Zhang Y, Wei Q, Ju H. Biosens Bioelectron, 2018, 122: 37–42
Han Q, Wang R, Xing B, Zhang T, Khan MS, Wu D, Wei Q. Biosens Bioelectron, 2018, 99: 493–499
Cai G, Yu Z, Ren R, Tang D. ACS Sens, 2018, 3: 632–639
Song JP, Yin PF, Mao J, Qiao SZ, Du XW. Nanoscale, 2017, 9: 6296–6301
Fu Y, Cao F, Wu F, Diao Z, Chen J, Shen S, Li L. Adv Funct Mater, 2018, 28: 1706785
Wang L, Wang W, Chen Y, Yao L, Zhao X, Shi H, Cao M, Liang Y. ACS Appl Mater Interfaces, 2018, 10: 11652–11662
Ibrahim I, Lim HN, Abou-Zied OK, Huang NM, Estrela P, Pandikumar A. J Phys Chem C, 2016, 120: 22202–22214
Wang Q, Ruan YF, Zhao WW, Lin P, Xu JJ, Chen HY. Anal Chem, 2018, 90: 3759–3765
Moriya M, Minegishi T, Kumagai H, Katayama M, Kubota J, Domen K. J Am Chem Soc, 2013, 135: 3733–3735
Pareek A, Kim HG, Paik P, Borse PH. J Mater Chem A, 2017, 5: 1541–1547
Fan GC, Zhu H, Du D, Zhang JR, Zhu JJ, Lin Y. Anal Chem, 2016, 88: 3392–3399
Li H, Li J, Zhu Y, Xie W, Shao R, Yao X, Gao A, Yin Y. Anal Chem, 2018, 90: 5496–5502
Miao R, Mu L, Zhang H, She G, Zhou B, Xu H, Wang P, Shi W. Nano Lett, 2014, 14: 3124–3129
Li J, Lin X, Zhang Z, Tu W, Dai Z. Biosens Bioelectron, 2019, 126: 332–338
Iqbal S, Pan Z, Zhou K. Nanoscale, 2017, 9: 6638–6642
Khanchandani S, Kumar S, Ganguli AK. ACS Sustain Chem Eng, 2016, 4: 1487–1499
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This work was supported by the National Natural Science Foundation of China (21625502), Priority Academic Program Development and Postgraduate Research & Practice Innovation Program of Jiangsu Province (KYCX18_1188).
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Component reconstitution-driven photoelectrochemical sensor for sensitive detection of Cu2+ based on advanced CuS/CdS p-n junction
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Liu, J., Liu, Y., Wang, W. et al. Component reconstitution-driven photoelectrochemical sensor for sensitive detection of Cu2+ based on advanced CuS/CdS p-n junction. Sci. China Chem. 62, 1725–1731 (2019). https://doi.org/10.1007/s11426-019-9579-2
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DOI: https://doi.org/10.1007/s11426-019-9579-2