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Stable metal-organic frameworks with high catalytic performance in the cycloaddition of CO2 with aziridines

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Abstract

Based on the mixed ligands XN (4′-(4-pyridine)4,2′:2′,4″-terpyridine) and isophthalic acid (IPA), three new metal-organic frameworks (MOFs) {[M2(XN)2(IPA)2]•2H2O}n (M=Co (1), Mn (2), Ni (3)) were assembled and structurally characterized, presenting 3D pillar-chain feature structures. Stability measurements demonstrate that these compounds possess high thermostability and can endure different organic solvents as well as various acid/base solutions with pH range of 1 to 14. Importantly, compounds 1–3 can serve as high-efficiency catalysts for the transformation of CO2 and aziridines to form high-value oxazolidinones under mild conditions, exhibiting excellent cyclicity at least five times.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21625103, 21571107, 21421001).

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Authors and Affiliations

  1. College of Chemistry and Key Laboratory of Advanced Energy Material Chemistry, Nankai University, Tianjin, 300071, China

    Xiao-Min Kang, Ying Shi, Chun-Shuai Cao & Bin Zhao

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  1. Xiao-Min Kang
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  2. Ying Shi
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  3. Chun-Shuai Cao
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  4. Bin Zhao
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Correspondence to Bin Zhao.

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Kang, XM., Shi, Y., Cao, CS. et al. Stable metal-organic frameworks with high catalytic performance in the cycloaddition of CO2 with aziridines. Sci. China Chem. 62, 622–628 (2019). https://doi.org/10.1007/s11426-018-9420-6

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