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Rare-earth metal catalysts for alkene hydrosilylation

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Abstract

Rare-earth metal catalyzed hydrosilylation of alkenes has emerged as a powerful and selective strategy for the synthesis of organosilanes. This transformation can offer distinctive catalytic sequences and reaction patterns from other catalysts because of the high electropositivity and lack of oxidative-addition process of rare-earth metal. This review summarizes the rare-earth metal catalysts for hydrosilylation of alkene according to the type of ligands. The synthesis and structure of rare-earth metal catalysts, the substrate scope as well as some preliminary structure-activity relationship and mechanism are discussed.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (21632006, 21472098) and Natural Science Foundation of Tianjin (16JCQNJC05800).

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Authors and Affiliations

  1. State Key Laboratory of Elemento-organic Chemistry and College of Chemistry, Nankai University, Tianjin, 300071, China

    Deshuai Liu, Boyu Liu, Zexiong Pan, Jianfeng Li & Chunming Cui

  2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, China

    Chunming Cui

Authors
  1. Deshuai Liu
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  2. Boyu Liu
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  3. Zexiong Pan
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  4. Jianfeng Li
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  5. Chunming Cui
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Correspondence to Jianfeng Li or Chunming Cui.

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Liu, D., Liu, B., Pan, Z. et al. Rare-earth metal catalysts for alkene hydrosilylation. Sci. China Chem. 62, 571–582 (2019). https://doi.org/10.1007/s11426-018-9403-7

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  • DOI: https://doi.org/10.1007/s11426-018-9403-7

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