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White-light emission and tunable room temperature phosphorescence of dibenzothiophene

Communications
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Abstract

Molecular materials exhibiting room temperature phosphorescence (RTP) have received much attention during last few years. It has been known that different stacking fashions (e.g., formation of polymorph) and aggregation/crystal states could largely influence the RTP efficiency. However, whether the crystal morphology or shape could play a key role in modulation of the RTP has not been detected yet. In this work, we report that the dibenzothiophene (DBT) with the same molecular stacking fashion but different crystal morphologies can present alternated RTP performances. By modulation of the fluorescence and phosphorescence dual emission, a direct warm-white color light-emitting has also been successfully achieved. Moreover, the RTP emission can be further tuned through hybridization with β-cyclodextrin in different ratios, with the longest lifetime of 0.43 s.

Keywords

molecular crystal white-light emission room temperature phosphorescence hybrid 

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Notes

Acknowledgements

This work was supported by the National Basic Research Program (2014CB932103), the National Natural Science Foundation of China (21301016, 21473013), the Beijing Municipal Natural Science Foundation (2152016), and the Fundamental Research Funds for the Central Universities.

Supplementary material

11426_2017_9183_MOESM1_ESM.pdf (3.3 mb)
Supplementary Information for white-light emission and tunable room temperature phosphorescence of dibenzothiophene

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Beijing Key Laboratory of Energy Conversion and Storage Materials, College of ChemistryBeijing Normal UniversityBeijingChina
  2. 2.State Key Laboratory of Chemical Resource EngineeringBeijing University of Chemical TechnologyBeijingChina

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