Abstract
The research on the supramolecular hyperbranched polymers (SHPs) that combines the advantages of supramolecular polymer and hyperbranched architecture has attracted considerable interests in many applications. Here we demonstrate a simple approach to prepare POSS-embedded supramolecular hyperbranched polymers (POSS-SHPs) with varied morphology and size by controlling monomer concentration and mixed solvents. The SHPs formations can further transfer into the core-shell structured micelles by addition of competitive guests based on the double supramolecular driving forces.
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Acknowledgments
This work was supported by the National Natural Science Foundation of China (21504096, 21674120, 21474115), Ministry of Science and Technology of China (2014CB932200) and “Young Thousand Talents” Program.
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POSS-embedded supramolecular hyperbranched polymers constructed from a 1→7 branching monomer with controllable morphology transitions
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Wang, X., Yang, Y., Fan, L. et al. POSS-embedded supramolecular hyperbranched polymers constructed from a 1→7 branching monomer with controllable morphology transitions. Sci. China Chem. 61, 311–318 (2018). https://doi.org/10.1007/s11426-017-9168-3
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DOI: https://doi.org/10.1007/s11426-017-9168-3