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The glyco-regioisomerism effect on dynamic interactions between glycopolymers with galactose pendants and benzoxaborole-containing polymer

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Abstract

This work investigated the effect of glyco-regioisomerism of glycopolymers on their dynamic interaction with benzoxaborole-containing polymers. Two kinds of glycopolymers, P-1-Gal and P-6-Gal, i.e. galactoside pendant group linked to the identical main chain through its anomeric (C1) and C6-hydroxyl group position, respectively, were studied. We found that P-6-Gal showed stronger binding strength to the PNIPAM-co-PBOB polymer than P-1-Gal did, which controlled the macroscopic property of the resultant hydrogels at a molecular level.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (21604042, 21504016, 91527305), the Natural Science Foundation of Jiangsu Province of China (BK20150843), and NUPTSF (NY215017, NY215080). We also thank Prof. Ming Jiang for his valuable suggestions and comments.

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Authors and Affiliations

  1. Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing, 210023, China

    Pengfei Sun & Sichao Tian

  2. The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science, Fudan University, Shanghai, 200433, China

    Mingchang Lin & Guosong Chen

Authors
  1. Pengfei Sun
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  2. Sichao Tian
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  3. Mingchang Lin
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  4. Guosong Chen
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Correspondence to Guosong Chen.

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11426_2017_9130_MOESM1_ESM.pdf

The glyco-regioisomerism effect on dynamic interactions between glycopolymers with galactose pendants and benzoxaborole-containing polymer

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Sun, P., Tian, S., Lin, M. et al. The glyco-regioisomerism effect on dynamic interactions between glycopolymers with galactose pendants and benzoxaborole-containing polymer. Sci. China Chem. 61, 71–75 (2018). https://doi.org/10.1007/s11426-017-9130-5

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  • DOI: https://doi.org/10.1007/s11426-017-9130-5

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