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Recent advances in heterogeneous catalytic conversion of glucose to 5-hydroxymethylfurfural via green routes

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Abstract

With concerns of diminishing fossil fuel reserves and environmental deterioration, great efforts have been made to explore novel approaches of efficiently utilizing bio-renewable feedstocks to produce chemicals and fuels. 5-Hydroxymethylfurfural (HMF), generated from dehydration of six-carbon ketose, is regarded as a primary and versatile renewable building block to realize the goal of production of these high valued products from renewable biomass resources transformation. In this review, we summarize the recent advances via green routes in the heterogeneous reaction system for the catalytic production of HMF from glucose conversion, and emphasize reaction pathways of these reaction approaches based on the fundamental mechanistic chemistry as well as highlight the challenges (such as separation and purification of products, reusing and regeneration of catalyst, recycling solvent) in this field.

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References

  1. Cai H, Li C, Wang A, Zhang T. Catal Today, 2014, 234: 59–65

    Article  CAS  Google Scholar 

  2. Delidovich I, Palkovits R. ChemSusChem, 2016, 9: 547–561

    Article  CAS  Google Scholar 

  3. Deng W, Zhang Q, Wang Y. Catal Today, 2014, 234: 31–41

    Article  CAS  Google Scholar 

  4. Farrán A, Cai C, Sandoval M, Xu Y, Liu J, Hernáiz MJ, Linhardt RJ. Chem Rev, 2015, 115: 6811–6853

    Article  CAS  Google Scholar 

  5. Liu X, Wang X, Yao S, Jiang Y, Guan J, Mu X. RSC Adv, 2014, 4: 49501–49520

    Article  CAS  Google Scholar 

  6. Luterbacher JS, Martin Alonso D, Dumesic JA. Green Chem, 2014, 16: 4816–4838

    Article  CAS  Google Scholar 

  7. Wang L, Xiao FS. Green Chem, 2015, 17: 24–39

    Article  CAS  Google Scholar 

  8. Zhang X, Wilson K, Lee AF. Chem Rev, 2016, 116: 12328–12368

    Article  CAS  Google Scholar 

  9. Caratzoulas S, Davis ME, Gorte RJ, Gounder R, Lobo RF, Nikolakis V, Sandler SI, Snyder MA, Tsapatsis M, Vlachos DG. J Phys Chem C, 2014, 118: 22815–22833

    Article  CAS  Google Scholar 

  10. Chatterjee C, Pong F, Sen A. Green Chem, 2015, 17: 40–71

    Article  CAS  Google Scholar 

  11. Wang J, Xi J, Wang Y. Green Chem, 2015, 17: 737–751

    Article  CAS  Google Scholar 

  12. Rosatella AA, Simeonov SP, Frade RFM, Afonso CAM. Green Chem, 2011, 13: 754–793

    Article  CAS  Google Scholar 

  13. Chinnappan A, Baskar C, Kim H. RSC Adv, 2016, 6: 63991–64002

    Article  CAS  Google Scholar 

  14. Saha B, Abu-Omar MM. Green Chem, 2014, 16: 24–38

    Article  CAS  Google Scholar 

  15. Teong SP, Yi G, Zhang Y. Green Chem, 2014, 16: 2015–2026

    Article  CAS  Google Scholar 

  16. Wang T, Nolte MW, Shanks BH. Green Chem, 2014, 16: 548–572

    Article  CAS  Google Scholar 

  17. Xue Z, Ma MG, Li Z, Mu T. RSC Adv, 2016, 6: 98874–98892

    Article  CAS  Google Scholar 

  18. Chheda JN, Huber GW, Dumesic JA. Angew Chem Int Ed, 2007, 46: 7164–7183

    Article  CAS  Google Scholar 

  19. Tong X, Ma Y, Li Y. Appl Catal A-Gen, 2010, 385: 1–13

    Article  CAS  Google Scholar 

  20. Assary RS, Curtiss LA. Energy Fuels, 2012, 26: 1344–1352

    Article  CAS  Google Scholar 

  21. Boronat M, Concepcion P, Corma A, Renz M, Valencia S. J Catal, 2005, 234: 111–118

    Article  CAS  Google Scholar 

  22. Li G, Pidko EA, Hensen EJM. ACS Catal, 2016, 6: 4162–4169

    Article  CAS  Google Scholar 

  23. Li J, Li J, Zhang D, Liu C. J Phys Chem B, 2015, 119: 13398–13406

    Article  CAS  Google Scholar 

  24. Li YP, Head-Gordon M, Bell AT. ACS Catal, 2014, 4: 1537–1545

    Article  CAS  Google Scholar 

  25. Loerbroks C, van Rijn J, Ruby MP, Tong Q, Schüth F, Thiel W. Chem Eur J, 2014, 20: 12298–12309

    Article  CAS  Google Scholar 

  26. Pidko EA, Degirmenci V, Hensen EJM. ChemCatChem, 2012, 4: 1263–1271

    Article  CAS  Google Scholar 

  27. Pidko EA, Degirmenci V, van Santen RA, Hensen EJM. Angew Chem Int Ed, 2010, 49: 2530–2534

    Article  CAS  Google Scholar 

  28. Qian X. J Phys Chem B, 2013, 117: 11460–11465

    Article  CAS  Google Scholar 

  29. Qian X, Wei X. J Phys Chem B, 2012, 116: 10898–10904

    Article  CAS  Google Scholar 

  30. Rai N, Caratzoulas S, Vlachos DG. ACS Catal, 2013, 3: 2294–2298

    Article  CAS  Google Scholar 

  31. Saravanamurugan S, Riisager A, Taarning E, Meier S. ChemCatChem, 2016, 8: 3107–3111

    Article  CAS  Google Scholar 

  32. Yang G, Pidko EA, Hensen EJM. ChemSusChem, 2013, 6: 1688–1696

    Article  CAS  Google Scholar 

  33. Yang L, Tsilomelekis G, Caratzoulas S, Vlachos DG. ChemSusChem, 2015, 8: 1334–1341

    Article  CAS  Google Scholar 

  34. Zhang ZC. Adv Catal, 2006, 49: 153–237

    CAS  Google Scholar 

  35. Zhao H, Holladay JE, Brown H, Zhang ZC. Science, 2007, 316: 1597–1600

    Article  CAS  Google Scholar 

  36. Fenn TD, Ringe D, Petsko GA. Biochemistry, 2004, 43: 6464–6474

    Article  CAS  Google Scholar 

  37. Moliner M, Román-Leshkov Y, Davis ME. Proc Natl Acad Sci USA, 2010, 107: 6164–6168

    Article  CAS  Google Scholar 

  38. Nikolla E, Román-Leshkov Y, Moliner M, Davis ME. ACS Catal, 2011, 1: 408–410

    Article  CAS  Google Scholar 

  39. Román-Leshkov Y, Moliner M, Labinger JA, Davis ME. Angew Chem Int Ed, 2010, 49: 8954–8957

    Article  CAS  Google Scholar 

  40. Bermejo-Deval R, Gounder R, Davis ME. ACS Catal, 2012, 2: 2705–2713

    Article  CAS  Google Scholar 

  41. Bermejo-Deval R, Assary RS, Nikolla E, Moliner M, Román-Leshkov Y, Hwang SJ, Palsdottir A, Silverman D, Lobo RF, Curtiss LA, Davis ME. Proc Natl Acad Sci USA, 2012, 109: 9727–9732

    Article  CAS  Google Scholar 

  42. Yu Y, Wu H. Ind Eng Chem Res, 2011, 50: 10500–10508

    Article  CAS  Google Scholar 

  43. Aida TM, Sato Y, Watanabe M, Tajima K, Nonaka T, Hattori H, Arai K. J Supercrit Fluid, 2007, 40: 381–388

    Article  CAS  Google Scholar 

  44. Lee YC, Chen CT, Chiu YT, Wu KCW. ChemCatChem, 2013, 5: 2153–2157

    Article  CAS  Google Scholar 

  45. Vennestrøm PNR, Christensen CH, Pedersen S, Grunwaldt JD, Woodley JM. ChemCatChem, 2010, 2: 249–258

    Article  CAS  Google Scholar 

  46. Huang R, Qi W, Su R, He Z. Chem Commun, 2010, 46: 1115–1117

    Article  CAS  Google Scholar 

  47. Grande PM, Bergs C, Domínguez de María P. ChemSusChem, 2012, 5: 1203–1206

    Article  CAS  Google Scholar 

  48. Simeonov SP, Coelho JAS, Afonso CAM. ChemSusChem, 2013, 6: 997–1000

    Article  CAS  Google Scholar 

  49. Huang H, Denard CA, Alamillo R, Crisci AJ, Miao Y, Dumesic JA, Scott SL, Zhao H. ACS Catal, 2014, 4: 2165–2168

    Article  CAS  Google Scholar 

  50. Delidovich I, Palkovits R. Catal Sci Technol, 2014, 4: 4322–4329

    Article  CAS  Google Scholar 

  51. Liu C, Carraher JM, Swedberg JL, Herndon CR, Fleitman CN, Tessonnier JP. ACS Catal, 2014, 4: 4295–4298

    Article  CAS  Google Scholar 

  52. Yang Q, Sherbahn M, Runge T. ACS Sustain Chem Eng, 2016, 4: 3526–3534

    Article  CAS  Google Scholar 

  53. Yang Q, Zhou S, Runge T. J Catal, 2015, 330: 474–484

    Article  CAS  Google Scholar 

  54. Watanabe M, Aizawa Y, Iida T, Aida TM, Levy C, Sue K, Inomata H. Carbohyd Res, 2005, 340: 1925–1930

    Article  CAS  Google Scholar 

  55. Qi X, Watanabe M, Aida TM, Smith Jr RL. Catal Commun, 2008, 9: 2244–2249

    Article  CAS  Google Scholar 

  56. Ohara M, Takagaki A, Nishimura S, Ebitani K. Appl Catal A-Gen, 2010, 383: 149–155

    Article  CAS  Google Scholar 

  57. Takagaki A, Ohara M, Nishimura S, Ebitani K. Chem Commun, 2009: 6276–6278

    Google Scholar 

  58. Yu S, Kim E, Park S, Song IK, Jung JC. Catal Commun, 2012, 29: 63–67

    Article  CAS  Google Scholar 

  59. Despax S, Estrine B, Hoffmann N, Le Bras J, Marinkovic S, Muzart J. Catal Commun, 2013, 39: 35–38

    Article  CAS  Google Scholar 

  60. Román-Leshkov Y, Davis ME. ACS Catal, 2011, 1: 1566–1580

    Article  CAS  Google Scholar 

  61. Cao Q, Guo X, Yao S, Guan J, Wang X, Mu X, Zhang D. Carbohyd Res, 2011, 346: 956–959

    Article  CAS  Google Scholar 

  62. Hu L, Sun Y, Lin L. Ind Eng Chem Res, 2012, 51: 1099–1104

    Article  CAS  Google Scholar 

  63. Liu W, Holladay J. Catal Today, 2013, 200: 106–116

    Article  CAS  Google Scholar 

  64. Pidko EA, Degirmenci V, van Santen RA, Hensen EJM. Inorg Chem, 2010, 49: 10081–10091

    Article  CAS  Google Scholar 

  65. Binder JB, Cefali AV, Blank JJ, Raines RT. Energy Environ Sci, 2010, 3: 765–771

    Article  CAS  Google Scholar 

  66. Zhang Y, Pidko EA, Hensen EJM. Chem Eur J, 2011, 17: 5281–5288

    Article  CAS  Google Scholar 

  67. He J, Zhang Y, Chen EYX. ChemSusChem, 2013, 6: 61–64

    Article  CAS  Google Scholar 

  68. Yong G, Zhang Y, Ying JY. Angew Chem Int Ed, 2008, 47: 9345–9348

    Article  CAS  Google Scholar 

  69. Qi X, Watanabe M, Aida TM, Smith Jr RL. ChemSusChem, 2010, 3: 1071–1077

    Article  CAS  Google Scholar 

  70. Zhang Z, Zhao ZK. Bioresource Tech, 2011, 102: 3970–3972

    Article  CAS  Google Scholar 

  71. Degirmenci V, Pidko EA, Magusin PCMM, Hensen EJM. ChemCatChem, 2011, 3: 969–972

    Article  CAS  Google Scholar 

  72. Choudhary V, Mushrif SH, Ho C, Anderko A, Nikolakis V, Marinkovic NS, Frenkel AI, Sandler SI, Vlachos DG. J Am Chem Soc, 2013, 135: 3997–4006

    Article  CAS  Google Scholar 

  73. Pagán-Torres YJ, Wang T, Gallo JMR, Shanks BH, Dumesic JA. ACS Catal, 2012, 2: 930–934

    Article  CAS  Google Scholar 

  74. Zhou X, Zhang Z, Liu B, Xu Z, Deng K. Carbohyd Res, 2013, 375: 68–72

    Article  CAS  Google Scholar 

  75. Deng T, Cui X, Qi Y, Wang Y, Hou X, Zhu Y. Chem Commun, 2012, 48: 5494–5496

    Article  CAS  Google Scholar 

  76. Zhang Z, Wang Q, Xie H, Liu W, Zhao ZK. ChemSusChem, 2011, 4: 131–138

    Article  CAS  Google Scholar 

  77. Zhang Z, Liu B, Zhao ZK. Starch-Stärke, 2012, 64: 770–775

    Article  CAS  Google Scholar 

  78. Hu S, Zhang Z, Song J, Zhou Y, Han B. Green Chem, 2009, 11: 1746–1749

    Article  CAS  Google Scholar 

  79. Assary RS, Redfern PC, Hammond JR, Greeley J, Curtiss LA. J Phys Chem B, 2010, 114: 9002–9009

    Article  CAS  Google Scholar 

  80. Ding D, Wang J, Xi J, Liu X, Lu G, Wang Y. Green Chem, 2014, 16: 3846–3853

    Article  CAS  Google Scholar 

  81. Upare PP, Yoon JW, Kim MY, Kang HY, Hwang DW, Hwang YK, Kung HH, Chang JS. Green Chem, 2013, 15: 2935–2943

    Article  CAS  Google Scholar 

  82. Weingarten R, Cho J, Xing R, Conner Jr WC, Huber GW. ChemSusChem, 2012, 5: 1280–1290

    Article  CAS  Google Scholar 

  83. Weingarten R, Kim YT, Tompsett GA, Fernández A, Han KS, Hagaman EW, Conner Jr WC, Dumesic JA, Huber GW. J Catal, 2013, 304: 123–134

    Article  CAS  Google Scholar 

  84. Liu B, Zhang Z. RSC Adv, 2013, 3: 12313–12319

    Article  CAS  Google Scholar 

  85. Liu B, Zhang Z, Huang K, Fang Z. Fuel, 2013, 113: 625–631

    Article  CAS  Google Scholar 

  86. Peng L, Lin L, Zhang J, Shi J, Liu S. Appl Catal A-Gen, 2011, 397: 259–265

    Article  CAS  Google Scholar 

  87. Saravanamurugan S, Riisager A. ChemCatChem, 2013, 5: 1754–1757

    Article  CAS  Google Scholar 

  88. Saravanamurugan S, Nguyen Van Buu O, Riisager A. ChemSusChem, 2011, 4: 723–726

    Article  CAS  Google Scholar 

  89. Chang CC, Wang Z, Dornath P, Je Cho H, Fan W. RSC Adv, 2012, 2: 10475–10477

    Article  CAS  Google Scholar 

  90. Dijkmans J, Gabriëls D, Dusselier M, de Clippel F, Vanelderen P, Houthoofd K, Malfliet A, Pontikes Y, Sels BF. Green Chem, 2013, 15: 2777–2785

    Article  CAS  Google Scholar 

  91. Corma A, Domine ME, Nemeth L, Valencia S. J Am Chem Soc, 2002, 124: 3194–3195

    Article  CAS  Google Scholar 

  92. Roy S, Bakhmutsky K, Mahmoud E, Lobo RF, Gorte RJ. ACS Catal, 2013, 3: 573–580

    Article  CAS  Google Scholar 

  93. Lew CM, Rajabbeigi N, Tsapatsis M. Micropor Mesopor Mater, 2012, 153: 55–58

    Article  CAS  Google Scholar 

  94. Saravanamurugan S, Paniagua M, Melero JA, Riisager A. J Am Chem Soc, 2013, 135: 5246–5249

    Article  CAS  Google Scholar 

  95. Zhang L, Xi G, Chen Z, Qi Z, Wang X. Chem Eng J, 2017, 307: 877–883

    Article  CAS  Google Scholar 

  96. Gardner DW, Huo J, Hoff TC, Johnson RL, Shanks BH, Tessonnier JP. ACS Catal, 2015, 5: 4418–4422

    Article  CAS  Google Scholar 

  97. Otomo R, Yokoi T, Tatsumi T. ChemCatChem, 2015, 7: 4180–4187

    Article  CAS  Google Scholar 

  98. Faria J, Pilar Ruiz M, Resasco DE. ACS Catal, 2015, 5: 4761–4771

    Article  CAS  Google Scholar 

  99. Wang J, Ren J, Liu X, Xi J, Xia Q, Zu Y, Lu G, Wang Y. Green Chem, 2012, 14: 2506–2512

    Article  CAS  Google Scholar 

  100. Osatiashtiani A, Lee AF, Brown DR, Melero JA, Morales G, Wilson K. Catal Sci Technol, 2014, 4: 333–342

    Article  CAS  Google Scholar 

  101. Dutta A, Patra AK, Dutta S, Saha B, Bhaumik A. J Mater Chem, 2012, 22: 14094–14100

    Article  CAS  Google Scholar 

  102. Atanda L, Mukundan S, Shrotri A, Ma Q, Beltramini J. ChemCatChem, 2015, 7: 781–790

    Article  CAS  Google Scholar 

  103. Dutta A, Gupta D, Patra AK, Saha B, Bhaumik A. ChemSusChem, 2014, 7: 925–933

    Article  CAS  Google Scholar 

  104. Ordomsky VV, van der Schaaf J, Schouten JC, Nijhuis TA. ChemSusChem, 2013, 6: 1697–1707

    Article  CAS  Google Scholar 

  105. Ordomsky VV, Sushkevich VL, Schouten JC, van der Schaaf J, Nijhuis TA. J Catal, 2013, 300: 37–46

    Article  CAS  Google Scholar 

  106. Osatiashtiani A, Lee AF, Granollers M, Brown DR, Olivi L, Morales G, Melero JA, Wilson K. ACS Catal, 2015, 5: 4345–4352

    Article  CAS  Google Scholar 

  107. Atanda L, Silahua A, Mukundan S, Shrotri A, Torres-Torres G, Beltramini J. RSC Adv, 2015, 5: 80346–80352

    Article  CAS  Google Scholar 

  108. Nakajima K, Baba Y, Noma R, Kitano M, Kondo NJ, Hayashi S, Hara M. J Am Chem Soc, 2011, 133: 4224–4227

    Article  CAS  Google Scholar 

  109. Yang F, Liu Q, Bai X, Du Y. Bioresource Tech, 2011, 102: 3424–3429

    Article  CAS  Google Scholar 

  110. Zhang Y, Wang J, Ren J, Liu X, Li X, Xia Y, Lu G, Wang Y. Catal Sci Technol, 2012, 2: 2485–2491

    Article  CAS  Google Scholar 

  111. Zhang Y, Wang J, Li X, Liu X, Xia Y, Hu B, Lu G, Wang Y. Fuel, 2015, 139: 301–307

    Article  CAS  Google Scholar 

  112. Kreissl HT, Nakagawa K, Peng YK, Koito Y, Zheng J, Tsang SCE. J Catal, 2016, 338: 329–339

    Article  CAS  Google Scholar 

  113. Jiao H, Zhao X, Lv C, Wang Y, Yang D, Li Z, Yao X. Sci Rep, 2016, 6: 34068

    Article  CAS  Google Scholar 

  114. Fan W, Zhang Q, Deng W, Wang Y. Chem Mater, 2013, 25: 3277–3287

    Article  CAS  Google Scholar 

  115. Yue C, Li G, Pidko EA, Wiesfeld JJ, Rigutto M, Hensen EJM. ChemSusChem, 2016, 9: 2421–2429

    Article  CAS  Google Scholar 

  116. Yang F, Liu Q, Yue M, Bai X, Du Y. Chem Commun, 2011, 47: 4469–4471

    Article  CAS  Google Scholar 

  117. Jiménez-Morales I, Teckchandani-Ortiz A, Santamaría-González J, Maireles-Torres P, Jiménez-López A. Appl Catal B-Environ, 2014, 144: 22–28

    Article  CAS  Google Scholar 

  118. Zhang Y, Degirmenci V, Li C, Hensen EJM. ChemSusChem, 2011, 4: 59–64

    Article  CAS  Google Scholar 

  119. Fan C, Guan H, Zhang H, Wang J, Wang S, Wang X. Biomass Bioenergy, 2011, 35: 2659–2665

    Article  CAS  Google Scholar 

  120. Su Y, Chang G, Zhang Z, Xing H, Su B, Yang Q, Ren Q, Yang Y, Bao Z. AIChE J, 2016, 62: 4403–4417

    Article  CAS  Google Scholar 

  121. Zhang Z, Du B, Zhang LJ, Da YX, Quan ZJ, Yang LJ, Wang XC. RSC Adv, 2013, 3: 9201–9205

    Article  CAS  Google Scholar 

  122. Cao X, Teong SP, Wu D, Yi G, Su H, Zhang Y. Green Chem, 2015, 17: 2348–2352

    Article  CAS  Google Scholar 

  123. Ståhlberg T, Rodriguez-Rodriguez S, Fristrup P, Riisager A. Chem Eur J, 2011, 17: 1456–1464

    Article  CAS  Google Scholar 

  124. Wang HY, Liu SY, Zhao YL, Zhang HC, Wang JJ. ACS Sustain Chem Eng, 2016, doi: 10.1021/acssuschemeng.1026b01652

    Google Scholar 

  125. Zhou J, Huang T, Zhao Y, Xia Z, Xu Z, Jia S, Wang J, Zhang ZC. Ind Eng Chem Res, 2015, 54: 7977–7983

    Article  CAS  Google Scholar 

  126. Liu W, Richard Zheng F, Li J, Cooper A. AIChE J, 2014, 60: 300–314

    Article  CAS  Google Scholar 

  127. Su Y, Brown HM, Huang X, Zhou X, Amonette JE, Zhang ZC. Appl Catal A-Gen, 2009, 361: 117–122

    Article  CAS  Google Scholar 

  128. Shuai L, Luterbacher J. ChemSusChem, 2016, 9: 133–155

    Article  CAS  Google Scholar 

  129. Simeonov SP, Coelho JAS, Afonso CAM. ChemSusChem, 2012, 5: 1388–1391

    Article  CAS  Google Scholar 

  130. Alonso DM, Wettstein SG, Dumesic JA. Green Chem, 2013, 15: 584–595

    Article  CAS  Google Scholar 

  131. Azadi P, Carrasquillo-Flores R, Pagán-Torres YJ, Gürbüz EI, Farnood R, Dumesic JA. Green Chem, 2012, 14: 1573–1576

    Article  CAS  Google Scholar 

  132. Alonso DM, Wettstein SG, Bond JQ, Root TW, Dumesic JA. ChemSusChem, 2011, 4: 1078–1081

    Article  CAS  Google Scholar 

  133. Román-Leshkov Y, Chheda JN, Dumesic JA. Science, 2006, 312: 1933–1937

    Article  CAS  Google Scholar 

  134. Wrigstedt P, Keskiväli J, Repo T. RSC Adv, 2016, 6: 18973–18979

    Article  CAS  Google Scholar 

  135. Mohammad S, Held C, Altuntepe E, Köse T, Sadowski G. J Phys Chem B, 2016, 120: 3797–3808

    Article  CAS  Google Scholar 

  136. Mohammad S, Held C, Altuntepe E, Köse T, Gerlach T, Smirnova I, Sadowski G. Fluid Phase Equilibr, 2016, 416: 83–93

    Article  CAS  Google Scholar 

  137. Wrigstedt P, Keskiväli J, Leskelä M, Repo T. ChemCatChem, 2015, 7: 501–507

    Article  CAS  Google Scholar 

  138. Teong SP, Yi G, Zeng H, Zhang Y. Green Chem, 2015, 17: 3751–3755

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (91545103, 21273071, 21403065), and the Commission of Science and Technology of Shanghai Municipality (10dz2220500).

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Correspondence to Jianjian Wang or Yanqin Wang.

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Wang, J., Xi, J., Xia, Q. et al. Recent advances in heterogeneous catalytic conversion of glucose to 5-hydroxymethylfurfural via green routes. Sci. China Chem. 60, 870–886 (2017). https://doi.org/10.1007/s11426-016-9035-1

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