Abstract
There is considerable interest in using ionic liquids (ILs) as protic electrolytes. However, the reported proton transfer rate in ILs is quite slow. In this study, we report functionalizing imidazolium ILs with alcohol hydroxyls, aiming at constructing hydrogen bonding networks in the electrolyte, can stimulate fast proton hopping transfer. For demonstration, the diffusion of proton and Cl− in 1-(3-hydroxypropyl)-3-methylimidazolium tetrafluoroboride (C3OHmimBF4) were studied using cyclic voltammetry and potentiostatic method at 30 °C. The diffusion coefficient of proton is about one order of magnitude higher than that of Cl− in the same electrolyte, and about 5 times that of proton in the non-hydydroxyl 1-(butyl)-3-methylimidazolium tetrafluoroboride (BmimBF4) when normalized to the diffusion coefficients of Cl− in respective ILs. In the meantime, 1H NMR spectra revealed a strong hydrogen bonding interaction between proton and C3OHmimBF4 which is absent between proton and BmimBF4, thus the significantly higher diffusion coefficient of proton in C3OHmimBF4 may suggest the formation of effective hydrogen bonding networks, enabling rapid proton hopping via the Grotthuss mechanism.
References
Armand M, Endres F, MacFarlane DR, Ohno H, Scrosati B. Nat Mater, 2009, 8: 621–629
Wang MY, Ma R, He LN. Sci China Chem, 2016, 59: 507–516
Zhang QB, Hua YX, Wang R. Sci China Chem, 2014, 57: 397–401
Yan Y, Yin YX, Guo YG, Wan LJ. Sci China Chem, 2014, 57: 1564–1569
Zhang L, Dong K, Chen S, Zhang S. Sci China Chem, 2016, 59: 547–550
Li Q, Jiang J, Li G, Zhao W, Zhao X, Mu T. Sci China Chem, 2016, 59: 571–577
Bhatt AI, Bond AM. J Electroanal Chem, 2008, 619-620: 1–10
Lloyd D, Vainikka T, Murtomäki L, Kontturi K, Ahlberg E. Electrochim Acta, 2011, 56: 4942–4948
Yang YY, Xu CY, Hua YX, Li J, Li FY, Jie YF. Int J Hydrogen Energy, 2015, 10: 1979–1991
Su C, An M, Yang P, Gu H, Guo X. Appl Surface Sci, 2010, 256: 4888–4893
Ejigu A, Lovelock KRJ, Licence P, Walsh DA. Electrochim Acta, 2011, 56: 10313–10320
Bentley CL, Bond AM, Hollenkamp AF, Mahon PJ, Zhang J. J Phys Chem C, 2014, 118: 22439–22449
Zhang Q, Hua Y, Wang R. Electrochim Acta, 2013, 105: 419–423
Sun H, Yu L, Jin X, Hu X, Wang D, Chen GZ. Electrochem Commun, 2005, 7: 685–691
Villagrán C, Banks CE, Hardacre C, Compton RG. Anal Chem, 2004, 76: 1998–2003
Yu L, Jin X, Chen GZ. J Electroanal Chem, 2013, 688: 371–378
Allen GD, Buzzeo MC, Villagrán C, Hardacre C, Compton RG. J Electroanal Chem, 2005, 575: 311–320
Cha QX. Introduction to Kinetics of Electrode Processes (in Chinese). 3rd Ed. Beijing: Academic Press, 2002
Meng Y, Aldous L, Belding SR, Compton RG. Chem Commun, 2012, 48: 5572–5574
Meng Y, Norman S, Hardacre C, Compton RG. Phys Chem Chem Phys, 2013, 15: 2031–2036
Meng Y, Aldous L, Belding SR, Compton RG. Phys Chem Chem Phys, 2012, 14: 5222–5228
Li Q, Pan C, Jensen JO, Noyé P, Bjerrum NJ. Chem Mater, 2007, 19: 350–352
Nakamoto H, Watanabe M. Chem Commun, 2007, 2539–2541
Li Y, Shi Y, Mehio N, Tan M, Wang Z, Hu X, Chen GZ, Dai S, Jin X. Appl Energy, 2016, 175: 451–458
Lee SY, Ogawa A, Kanno M, Nakamoto H, Yasuda T, Watanabe M. J Am Chem Soc, 2010, 132: 9764–9773
Kreuer K. Solid State Ion, 1997, 94: 55–62
Yoshizawa-Fujita M, Kousa Y, Kidena K, Ohira A, Takeoka Y, Rikukawa M. Phys Chem Chem Phys, 2011, 13: 13427–13432
Wei X, Yu L, Wang D, Jin X, Chen GZ. Green Chem, 2008, 10: 296–305
Wei X, Yu L, Jin X, Wang D, Chen GZ. Adv Mater, 2009, 21: 776–780
Zhao C, Bond AM, Lu X. Anal Chem, 2012, 84: 2784–2791
Ciocirlan O, Croitoru O, Iulian O. J Chem Eng Data, 2011, 56: 1526–1534
Huang Q, Li Y, Jin X, Zhao D, Chen GZ. Energy Environ Sci, 2011, 4: 2125–2133
Winlove CP, Parker KH, Oxenham RKC. J Electroanal Chem, 1984, 170: 293–304
Mele A, Tran CD, De Paoli Lacerda SH. Angew Chem, 2003, 115: 4500–4502
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This work was supported by the National Natural Science Foundation of China (21173161, 21673164), and the Large-scale Instrument and Equipment Sharing Foundation of Wuhan University.
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Li, Y., Hu, Y., Chen, G. et al. Rapid proton diffusion in hydroxyl functionalized imidazolium ionic liquids. Sci. China Chem. 60, 734–739 (2017). https://doi.org/10.1007/s11426-016-0459-2
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DOI: https://doi.org/10.1007/s11426-016-0459-2