Science China Chemistry

, Volume 60, Issue 6, pp 701–720 | Cite as

Recent advances in direct dehydrogenative biphenyl couplings

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Abstract

Biphenyl moiety represents a unique structural motif of many natural and unnatural products with biological interests, and dehydrogenative couplings of two aryl C–H bonds under oxidative conditions is unambiguously the most efficient and direct preparation of these compounds. However, higher oxidation potential of benzene derivatives makes such oxidative couplings much more difficult than other arenes. Only very limited advances have been achieved on direct formation of the crucial C–C bond between two phenyl derivatives by dehydrogenative phenyl coupling in the last two decades. This article briefly summarized and commented a number of representative recent achievements in this attractive field, including homo-, cross- and intramolecular rearrangement and couplings, as well as their applications in organic synthesis.

Keywords

biphenyl dehydrogenative coupling oxidation arene C–H bond activation 

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Notes

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21472087).

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Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  1. 1.State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical EngineeringNanjing UniversityNanjingChina
  2. 2.Collaborative Innovation Center of Chemistry for Life SciencesNanjing UniversityNanjingChina

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