Skip to main content
Log in

A newly-designed self-powered electrochromic window

  • Articles
  • Special Topic · Electrochromics
  • Published:
Science China Chemistry Aims and scope Submit manuscript

Abstract

By converting incident light into electric power, self-powered electrochromic window (SP-ECW) can achieve color change in electrochromic layer with no need for external voltage. In this work, a newly-designed SP-ECW is proposed for altering its color between deep blue and colorless state according to on/off state of incident light. The device consists of a working electrode with planar integration of photovoltaic (PV) and electrochromic (EC) elements on one electrode, a platinum counter electrode and a redox electrolyte comprising Br/Br 3 couple. A high transmittance modulation of 41% at 582 nm is obtained. Electrical energy converted from light is not only sufficient to drive the device, but also can be outputted to the external circuit.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Lampert CM. Solar Energy Mater, 1984, 11: 1–27

    Article  CAS  Google Scholar 

  2. Rosseinsky DR, Mortimer RJ. Adv Mater, 2001, 13: 783–793

    Article  CAS  Google Scholar 

  3. Xu C, Liu L, Legenski SE, Ning D, Taya M. J Mater Res, 2004, 19: 2072–2080

    Article  CAS  Google Scholar 

  4. Argun AA, Aubert PH, Thompson BC, Schwendeman I, Gaupp CL, Hwang J, Pinto NJ, Tanner DB, Mac Diarmid AG, Reynolds JR. Chem Mater, 2004, 16: 4401–4412

    Article  CAS  Google Scholar 

  5. Yang S, Zheng J, Wu X, Xu C. Acta Chim Sin, 2013, 71: 1041–1046

    Article  CAS  Google Scholar 

  6. Bechinger C, Ferrere S, Zaban A, Sprague J, Gregg BA. Nature, 1996, 383: 608–610

    Article  CAS  Google Scholar 

  7. Wu JJ, Hsieh MD, Liao WP, Wu WT, Chen JS. ACS Nano, 2009, 3: 2297–2303

    Article  CAS  Google Scholar 

  8. Cannavale A, Manca M, Malara F, De Marco L, Cingolani R, Gigli G. Energy Environ Sci, 2011, 4: 2567–2574

    Article  CAS  Google Scholar 

  9. Huang LM, Hu CW, Liu HC, Hsu CY, Chen CH, Ho KC. Sol Energ Mat Sol C, 2012, 99: 154–159

    Article  CAS  Google Scholar 

  10. Deb SK, Lee SH, Edwin Tracy C, Roland Pitts J, Gregg BA, Branz HM. Electrochim Acta, 2001, 46: 2125–2130

    Article  CAS  Google Scholar 

  11. Gao W, Liu P, Crandall RS, Lee SH, Benson DK, Branz HM. J Non-Cryst Solids, 2000, 266: 1140-1144

    Article  Google Scholar 

  12. De Filpo G, Mormile S, Nicoletta FP, Chidichimo G. J Power Sources, 2010, 195: 4365–4369

    Article  Google Scholar 

  13. Leftheriotis G, Syrrokostas G, Yianoulis P. Sol Energ Mat Sol C, 2010, 94: 2304–2313

    Article  CAS  Google Scholar 

  14. Yang S, Zheng J, Li M, Xu C. Sol Energ Mat Sol C, 2012, 97: 186–190

    Article  CAS  Google Scholar 

  15. Cannavale A, Manca M, De Marco L, Grisorio R, Carallo S, Suranna GP, Gigli G. ACS Appl Mater Interfaces, 2014, 6: 2415–2422

    Article  CAS  Google Scholar 

  16. Wu X, Zheng J, Xu C. Electrochim Acta, 2016, 191: 902–907

    Article  CAS  Google Scholar 

  17. Chen M, Yang S, Zheng J, Xu C. Acta Chim Sin, 2013, 71: 713–716

    Article  CAS  Google Scholar 

  18. Dyer AL, Bulloch RH, Zhou Y, Kippelen B, Reynolds JR, Zhang F. Adv Mater, 2014, 26: 4895–4900

    Article  CAS  Google Scholar 

  19. Huang LM, Hu CW, Peng CY, Su CH, Ho KC. Sol Energ Mat Sol C, 2016, 145: 69–75

    Article  CAS  Google Scholar 

  20. Hauch A, Georg A, Baumgärtner S, Opara Krašovec U, Orel B. Electrochim Acta, 2001, 46: 2131–2136

    Article  CAS  Google Scholar 

  21. Hsu CY, Lee KM, Huang JH, Justin Thomas KR, Lin JT, Ho KC. J Power Sources, 2008, 185: 1505–1508

    Article  CAS  Google Scholar 

  22. Jiao Z, Song JL, Sun XW, Liu XW, Wang JM, Ke L, Demir HV. Sol Energ Mat Sol C, 2012, 98: 154–160

    Article  CAS  Google Scholar 

  23. Bella F, Leftheriotis G, Griffini G, Syrrokostas G, Turri S, Grätzel M, Gerbaldi C. Adv Funct Mater, 2016, 26: 1127–1137

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (21274138, 21273207, 21474096) and the Chinese Academy of Sciences (Integrated system of high efficiency building energy saving and its application, KFZD-SW-403).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Chunye Xu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wu, X., Zheng, J. & Xu, C. A newly-designed self-powered electrochromic window. Sci. China Chem. 60, 84–89 (2017). https://doi.org/10.1007/s11426-016-0286-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-016-0286-8

Keywords

Navigation