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Synthesis and characterization of dendronized hyperbranched polymers through the “A3+B2” approach

Science China Chemistry volume 59, pages 1561–1567 (2016)Cite this article

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Abstract

Dendronized hyperbranched polymer (DHP) is a new kind of polymer, which combines the advantages of dendrimers and hyperbranched polymers. In this work, two dendronized hyperbranched polymers, DHPG0 and DHPG1, were successfully prepared through the simple “A3+B2” type Sonogashira coupling reaction. The nonlinear optical (NLO) effects of DHPG0 and DHPG1, characterized by the d 33 values, were 183 and 220 pm V–1 respectively, higher than those of their analogues of dendronized polymers and dendrimers, thanks to the special topological structure. Also, the obtained polymers displayed excellent solubility, good processability, and high thermal stability.

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, Wuhan, 430072, China

    Guangchao Liu, Pengyu Chen, Runli Tang & Zhen Li

Authors
  1. Guangchao Liu
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  2. Pengyu Chen
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  3. Runli Tang
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  4. Zhen Li
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Correspondence to Zhen Li.

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Liu, G., Chen, P., Tang, R. et al. Synthesis and characterization of dendronized hyperbranched polymers through the “A3+B2” approach. Sci. China Chem. 59, 1561–1567 (2016). https://doi.org/10.1007/s11426-016-0250-5

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  • DOI: https://doi.org/10.1007/s11426-016-0250-5

Keywords

  • dendronized hyperbranched polymer
  • nonlinear optic
  • Sonogashira coupling reaction