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Visible and near-infrared luminescence of polycatenated cationic pyridinone lanthanide networks

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Abstract

A series of isomorphic lanthanide coordination polymers [Ln(III)(MBP)2(NO3)2(Br)·2C3H6O] [Ln=Eu, Tb, Er, Yb, and Gd; MBP=N,N′-methylene-bis(pyridin-4-one)] featuring polycatenated sql cationic network and incorporated bromide counter ion were prepared. Their visible and near-infrared (NIR) luminescence properties were characterized by steady-state excitation and emission spectra, as well as luminescence lifetimes and quantum yields. The D 2d dodecahedron coordination geometry causes visible light excitations and strongly monochromatic emissions. The external heavy-atom environment induces remarkable enhancement on the NIR emissions. The sensitization processes are revealed by analyzing the electronic properties of MBP ligand.

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References

  1. Bünzli JCG, Piguet C. Soc Rev, 2005, 34: 1048–1077

    Article  Google Scholar 

  2. Woodruff DN, Winpenny REP, Layfield RA. Chem Rev, 2013, 113: 5110–5148

    Article  CAS  Google Scholar 

  3. Long DL, Blake AJ, Champness NR, Schröder M. Chem Commun, 2000, 1369–1370

    Google Scholar 

  4. Reineke TM, Eddaoudi M, Moler D, O’Keeffe M, Yaghi OM. J Am Chem Soc, 2000, 122: 4843–4844

    Article  CAS  Google Scholar 

  5. Allendorf MD, Bauer CA, Bhakta RK, Houk RJT. Chem Soc Rev, 2009, 38: 1330–1352

    Article  CAS  Google Scholar 

  6. Alexandrov EV, Blatov VA, Proserpio DM. Acta Cryst, 2012, A68: 484–493

    Article  Google Scholar 

  7. Eliseevaa SV, Bünzli JCG. Chem Soc Rev, 2010, 39: 189–227

    Article  Google Scholar 

  8. Eliseevaa SV, Bünzli JCG. New J Chem, 2011, 35: 1165–1176

    Article  Google Scholar 

  9. Rocha J, Carlos LD, Almeida Paz FA, Ananias D. Chem Soc Rev, 2011, 40: 926–940

    Article  CAS  Google Scholar 

  10. Artizzu F, Mercuri ML, Serpe A, Deplano P. Coord Chem Rev, 2011, 255: 2514–2529

    Article  CAS  Google Scholar 

  11. Shu YB, Tang XL, Liu WS. Inorg Chem Front, 2014, 1: 226–230

    Article  CAS  Google Scholar 

  12. King RB. J Am Chem Soc, 1969, 91: 7211–7216

    Article  CAS  Google Scholar 

  13. Bünzli JCG, Eliseeva SV. Basics of lanthanide photophysics. In: Hänninen P, Härmä H. Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects. Berlin Heidelberg: Springer, 2011. 1–46

    Google Scholar 

  14. Miyata K, Nakagawa T, Kawakami R, Kita Y, Sugimoto K, Nakashima T, Harada T, Kawai T, Hasegawa Y. Chem Eur J, 2011, 17: 521–528

    Article  CAS  Google Scholar 

  15. Liu F, Fang Y, Zhang N, Hou J, Ma Z, Zhao G. Ceram Int, 2014, 40: 14781–14786

    Article  CAS  Google Scholar 

  16. Peng Y, Ye H, Li Z, Motevalli M, Hernández I, Gillin WP, Wyatt PB. J Phys Chem Lett, 2014, 5: 1560–1563

    Article  CAS  Google Scholar 

  17. Werts MHV, Duin MA, Hofstraat JW, Verhoeven JW. Chem Commun, 1999: 799–800

    Google Scholar 

  18. Park OH, Seo SY, Bae BS, Shin JH. Appl Phys Lett, 2003, 82: 2787–2789

    Article  CAS  Google Scholar 

  19. Deun RV, Fias P, Driesen K, Binnemans K, Görller-Walrand C. Phys Chem Chem Phys, 2003, 5: 2754–2757

    Article  Google Scholar 

  20. McGlynn SP, Sunseri R, Christodouleas N. J Chem Phys, 1962, 37: 1818–1824

    Article  CAS  Google Scholar 

  21. McGlynn SP, Daigre J, Smith FJ. J Chem Phys, 1963, 39: 675–679

    Article  CAS  Google Scholar 

  22. Yang C, Fu LM, Wang Y, Zhang JP, Wong WT, Ai XC, Qiao YF, Zou BS, Gui LL. Angew Chem Int Ed, 2004, 43: 5010–5013

    Article  CAS  Google Scholar 

  23. Dexter DL. J Chem Phys, 1953, 21: 836–850

    Article  CAS  Google Scholar 

  24. Latva M, Takalo H, Mukkala VM, Matachescu C, Rodriguez-Ubis JC, Kankare J. J Lumin, 1997, 75: 149–169

    Article  CAS  Google Scholar 

  25. Arnaud N, Georges J. Spectrochim Acta, Part A, 2003, 59: 1829–1840

    Article  CAS  Google Scholar 

  26. Klink SI, Grave L, Reinhoudt DN, van Veggel FCJM. J Phys Chem A, 2000, 104: 5457–5468

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province; State Key Laboratory of Applied Organic Chemistry; College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, 730000, China

    Yubo Shu & Weisheng Liu

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  1. Yubo Shu
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  2. Weisheng Liu
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Correspondence to Weisheng Liu.

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Shu, Y., Liu, W. Visible and near-infrared luminescence of polycatenated cationic pyridinone lanthanide networks. Sci. China Chem. 59, 436–441 (2016). https://doi.org/10.1007/s11426-015-5497-4

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  • DOI: https://doi.org/10.1007/s11426-015-5497-4

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