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Organothorium complexes containing terminal metal-ligand multiple bonds

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Abstract

Organoactinide complexes containing terminal metal-ligand multiple bonds have received widespread attention over the past three decades. In the last few years, significant progress has been made in the synthesis and characterization of the imido, oxo, sulfido, and carbene-containing complexes of thorium. Such thorium complexes are of interest because of their unique structural properties, their potential application in novel group transfer reactions and catalysis, as well as their ability to engage the 5f orbitals in metal-ligand bonding. This short review summarizes the synthesis and reactivity of these thorium complexes.

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Authors and Affiliations

  1. Department of Chemistry, Beijing Normal University, Beijing, 100875, China

    GuoFu Zi

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Correspondence to GuoFu Zi.

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Dedicated to Professor Qian Changtao on the occasion of his 80th birthday.

ZI GuoFu studied chemistry at Beijing Normal University from 1992 to 1998, where he received his BSc and MSc degrees in 1996 and 1998, respectively. After finished his PhD in 2002 under guidance of Professor Zuowei Xie at the Chinese University of Hong Kong, he joined the group of Professor Richard A. Andersen at the University of California at Berkeley as a postdoctoral fellow. In 2005 he began his independent research career as a principal investigator at Beijing Normal University. His research interests include organometallic chemistry and organic synthesis. He has co-authored about 80 publications in peer-reviewed journals.

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Zi, G. Organothorium complexes containing terminal metal-ligand multiple bonds. Sci. China Chem. 57, 1064–1072 (2014). https://doi.org/10.1007/s11426-014-5094-y

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