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Water-induced reversible dissolution/reorganization transformations of Cu(II)-K(I) heterometallic coordination polymers

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Abstract

Three new heterometallic coordination compounds, namely, [KCu(I3)(L)2(H2O)2] n (1), [KCu(I3)(L)2(H2O)] n (2) and [CuK4(I3)2(L′)4] n (3), were prepared and characterized (HL=5-methylpyrazine-2-carboxylic acid, HL′=p-tolylacetic acid). Structural studies revealed that 1 and 2 exhibit 3D frameworks with rectangular channels occupied by triiodide ions. Both compounds can be symbolized as a 5-connected net with pcu topology. In compound 3, a one-dimensional polyhedral chain is connected by hexanuclear mask like clusters [Cu2K4O8]. These chains are further linked each other via rare (1,1,3,3)-triiodide ion-bridging units to generate a 3D (4,5,6)-connected net with the point symbol of {12}2{4·122}4{46}{48·62}4{49·66}4. It is noteworthy that water-induced reversible dissolution/reorganization processes occur between 1/2 and [Cu(L)2(H2O)] n ·3nH2O. The thermal and photoluminescence properties of compounds 1, 2, and 3 were investigated as well.

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  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an, 710069, China

    Sheng Zhang, Qing Wei, XiangYu Liu, Qi Yang, Gang Xie & SanPing Chen

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Zhang, S., Wei, Q., Liu, X. et al. Water-induced reversible dissolution/reorganization transformations of Cu(II)-K(I) heterometallic coordination polymers. Sci. China Chem. 57, 1225–1234 (2014). https://doi.org/10.1007/s11426-014-5070-6

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