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Porous zinc(II)-organic framework with potential open metal sites: Synthesis, structure and property

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  • Special Topic · Coordination Polymer
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Abstract

Reaction of Zn(NO3)2·6H2O with 5-(isonicotinamido) isophthalic acid (H2INAIP) in N,N-dimethylformamide (DMF) affords a new three-dimensional (3D) coordination polymer {[Zn(INAIP)(DMF)]·0.5DMF·4H2O} n (1). The X-ray crystallographic structural analysis reveals that complex 1 is a 3D porous framework containing a potential open metal site inside the pores. Topology analysis confirms that complex 1 is a two-fold interpenetrated (10, 3)-b net with both metal ion and ligand acting as 3-connecting nodes. The thermal stability, variable temperature X-ray diffraction pattern and N2 adsorption property of the complex are investigated.

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Authors and Affiliations

  1. KLGHEI of Environment and Energy Chemistry; Laboratory of Bioinorganic and Synthetic Chemistry, Ministry of Education; School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China

    JiJun Jiang, Rui Yang, Ying Xiong, Lei Li, Mei Pan & ChengYong Su

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  1. JiJun Jiang
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  2. Rui Yang
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  3. Ying Xiong
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  4. Lei Li
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  6. ChengYong Su
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Correspondence to ChengYong Su.

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Jiang, J., Yang, R., Xiong, Y. et al. Porous zinc(II)-organic framework with potential open metal sites: Synthesis, structure and property. Sci. China Chem. 54, 1436–1440 (2011). https://doi.org/10.1007/s11426-011-4348-1

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  • DOI: https://doi.org/10.1007/s11426-011-4348-1

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