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Two new compounds with microporous constructed by Waugh-type polyoxoanion and transition metal ions

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  • Special Topic · Coordination Polymer
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Abstract

Two new compounds with microporous Co3[MnMo9O32]·15H2O (1) and Cu3[MnMo9O32]·15H2O (2) have been synthesized, and characterized by IR, element analysis, TG and single-crystal X-ray analysis. The structure analyses reveal that compounds 1 and 2 are isostructural. In crystal, the Waugh-type polyoxoanions [MnMo9O32]6− are connected by Co2+ or Cu2+ cations to a 3D open-framework, which possesses channels along the [1 2 2] direction of approximately 8.27 × 11.97 Å. The photocatalytic performances of compounds 1 and 2 for photodegradation of RhB with UV irradiation have been studied, which show a good photocatalytic activity for photodegradation of RhB.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China

    HuaQiao Tan, WeiLin Chen, Ding Liu, AiXue Yan & EnBo Wang

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  1. HuaQiao Tan
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  2. WeiLin Chen
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  3. Ding Liu
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  4. AiXue Yan
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  5. EnBo Wang
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Correspondence to EnBo Wang.

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Tan, H., Chen, W., Liu, D. et al. Two new compounds with microporous constructed by Waugh-type polyoxoanion and transition metal ions. Sci. China Chem. 54, 1418–1422 (2011). https://doi.org/10.1007/s11426-011-4340-9

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  • DOI: https://doi.org/10.1007/s11426-011-4340-9

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