Abstract
Self-assembly of cadmium ions and the rigid bridging ligand 4,4′-methylenebis(3-hydroxy-2-naphthoic acid) (pamoic acid, H4PA) leads to a one-dimensional metal-organic framework with open cube-like M2(H2PA)2 cages within its backbone, and exhibiting interesting yellow fluorescence.
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Férey G, Mellot-Draznieks C, Serre C, Millange F. Crystallized frameworks with giant pores: Are there limits to the possible? Acc Chem Res, 2005, 38: 217–225
Evans OR, Lin WB. Crystal engineering of NLO materials based on metal-organic coordination networks. Acc Chem Res, 2002, 35: 511–522
Gianneschi NC, Bertin PA, Nguyen ST, Mirkin CA, Zakharov LN, Rheingold AL. A supramolecular approach to an allosteric catalyst. J Am Chem Soc, 2003, 125: 10508–10509
Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers. Angew Chem Int Ed, 2004, 43: 2334–2375
Lee JW, Samal S, Selvapalam N, Kimand HJ, Kim K. Cucurbituril homologues and derivatives: New opportunities in supramolecular chemistry. Acc Chem Res, 2003, 36: 621–630
Chen BL. Eddaoudi M. Hyde ST. O’Keeffe M. Yaghi OM. Interwoven metal-organic framework on a periodic minimal surface with extra-large pores. Science, 2001, 291: 1021–1023
Rosi N, Eckert J, Eddaoudi M, Vodak D, Kim J, O’Keeffe M, Yaghi OM. Hydrogen storage in microporous metal-organic frameworks. Science, 2003, 300: 1127–1129
Wang CF, Gao EQ, He Z, Yan CH. A novel mixed-valence complex containing CoII 2CoIII 2 molecular squares with 4,5-imidazoledicarboxylate bridges. Chem Commun, 2004: 720–721
Du M, Li CP, Zhao XJ, Yu Q. Interplay of coordinative and supramolecular interactions in engineering unusual crystalline architectures of low-dimensional metal-pamoate complexes under co-ligand intervention. CrystEngComm, 2007, 9: 1011–1028
Romero MA, Moreno MN, Ruh J, Sanchez MP, Nieto F. A novel type of tetradentate uracil derivative in a dodecahedral eight-coordinate chelate complex: Catena-bis(.mu.-6-amino-3-methyl-5-nitrosouracilato-N5,O4,N1,O2)-cadmium(II). Inorg Chem, 1986, 25: 1498–1501
Langs DA, Hare CR. The crystal structure of calcium copper acetate hexahydrate and its isomorph calcium cadmium acetate hexahydrate. Chem Commun, 1967: 890–891
Kim J, Chen B, Reineke TM, Li HL, Eddaoudi M, Moler DB, O’Keeffe M, Yaghi OM. Assembly of metal-organic frameworks from large organic and inorganic secondary building units: New examples and simplifying principles for complex structures. J Am Chem Soc, 2001, 123: 8239–8247
Stang PJ, Olenyuk B. Self-assembly, symmetry, and molecular architecture: Coordination as the motif in the rational design of supramolecular metallacyclic polygons and polyhedra. Acc Chem Res, 1997, 30: 502–518
Belanger S, Keefe MH, Welch JL, Hupp JT. Rapid derivatization of mesoporous thin-film materials based on Re(I) zinc-porphyrin ‘molecular squares’: Selective modification of mesopore size and shape by binding of aromatic nitrogen donor ligands. Coord Chem Rev, 1999, 192: 29–45
Fujita M, Ogura G. Preparation of a macrocyclic polynuclear complex, [(en)Pd(4,4′-bpy)]4(NO3)8 (en = ethylenediamine, bpy = bipyridine), which recognizes an organic molecule in aqueous media. J Am Chem Soc, 1990, 112: 5645–5647
Zaworotko MJ. Superstructural diversity in two dimensions: crystal engineering of laminated solids. Chem Commun, 2001: 1–10
Oh M, Stern CL, Mirkin CA. Coordination polymers with macrocyclic cages and pockets within their backbones. Chem Commun, 2004: 2684–2685
Tadokoro M, Mizugaki S, Kozaki M, Okada K, One-dimensional void-space arrays constructed from a coordination polymer with bowl-like frameworks of cavitands. Chem Commun, 2005: 1140–1142
Chatterjee B, Noveron JC, Resendiz MJE, Liu J, Yamamoto T, Parker D, Cinke M, Nguyen CV, Arif AM, Stang PJ. Self-assembly of flexible supramolecular metallacyclic ensembles: Structures and adsorption properties of their nanoporous crystalline frameworks. J Am Chem Soc, 2004, 126: 10645–10656
Li XQ, Cao R, Bi WH, Wang YQ, Wang YL, Li X, Guo ZG. A new family of cadmium(II) coordination polymers from coligands: Effect of the coexistent groups (R = H, -HO2, -OH) on crystal structures and properties. Cryst Growth Des, 2005, 5: 1651–1656
Wang XL, Qin C, Wang EB, Xu L, Su ZM, Hu CW. Interlocked and interdigitated architectures from self-assembly of long flexible ligands and cadmium salts. Angew Chem Int Ed, 2004, 43: 5036–5040
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Wang, C., Zhang, Z., Zhang, L. et al. A luminescent metal-organic framework with an open cubic cage and eight-coordinate cadmium nodes. Sci. China Chem. 53, 2079–2082 (2010). https://doi.org/10.1007/s11426-010-4098-5
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DOI: https://doi.org/10.1007/s11426-010-4098-5