Skip to main content
Log in

Layered intercalated functional materials based on efficient utilization of magnesium resources in China

  • Reviews
  • Published:
Science China Chemistry Aims and scope Submit manuscript

Abstract

Mg-based layered intercalated functional materials of the layered double hydroxide type are a significant class of magnesium compounds. Based on long-term studies of these materials in the State Key Laboratory of Chemical Resource Engineering in Beijing University of Chemical Technology, two principles of “using the intended application of a material as a guide to its structure design and synthesis process” and “the design of controlled intercalation processes in the light of future production processing requirements” have been developed. To achieve these objectives, the composition of the host layers and guest interlayer anions was tailored at the microlevel, while the mesostructure and macrostructure were controlled to fabricate different kinds of Mg-based layered intercalated functional materials. These materials have diverse applications in key areas such as catalysis, the environment, and construction, and as polymer additives. Therefore, China’s magnesium resources may be utilized more efficiently for the benefit of society.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Wu ZM, Ma PH. Summary of magnesium, magnesium resources and magnesium materials. J Salt Lake Res, 2007, 15(4): 65–72

    Google Scholar 

  2. Hu QF, Liu JZ, Song LY, Hu XX. The predominance of magnesium resource and development of magnesium chemical materials in China. Inorg Chem Ind, 2006, 38(9): 13–16

    CAS  Google Scholar 

  3. Hu QF, Song LY, Liu BS. Present status and prospect of industrial magnesium compounds in China. Inorg Chem Ind, 2009, 41(4): 8–10

    Google Scholar 

  4. Cavani F, Trifiro F, Vaccari A. Hydrotalcite-type anionic clays: Preparation, properties and applications. Catal Today, 1991, 11(2): 173–301

    Article  CAS  Google Scholar 

  5. Evans DG, Slade RCT. Structural aspects of layered double hydroxides. Struct Bond, 2006, 119: 1–87

    CAS  Google Scholar 

  6. Li F, Duan X. Applications of layered double hydroxides. Struct Bond, 2006, 119: 193–223

    Article  CAS  Google Scholar 

  7. Zhao Y, Li F, Zhang R, Evans DG, Duan X. Preparation of layered double-hydroxide nanomaterials with a uniform crystallite size using a new method involving separate nucleation and aging steps. Chem Mater, 2002, 14(10): 4286–4291

    Article  CAS  Google Scholar 

  8. Zhao Y, Jiao QZ, Li F, Evans DG, Duan X. Control of particle size of layered double hydroxides using non-equilibrium aging conditions. Chin J Inorg Chem, 2001, 17(6): 830–834

    CAS  Google Scholar 

  9. Williams GR, O’Hare D. Towards understanding, control and application of layered double hydroxide chemistry. J Mater Chem, 2006, 16(30): 3065–3074

    Article  CAS  Google Scholar 

  10. Yan H, Lu J, Wei M, Ma J, Li H, He J, Evans DG, Duan X. Theoretical study of the hexahydrated metal cations for the understanding of their template effects in the construction of layered double hydroxides. J Mol Struc: Theochem, 2008, 866(1–3): 34–45

    Article  CAS  Google Scholar 

  11. Chai H, Lin Y, Evans DG., Li D. Synthesis and UV absorption properties of 2-naphthylamine-1,5-disulfonic acid intercalated Zn-Al layered double hydroxides. Ind Eng Chem Res, 2008, 47(9): 2855–2860

    Article  CAS  Google Scholar 

  12. Wei M, Xu X, Wang XY, Li F, Zhang H, Lu YL, Pu M, Evans DG, Duan X. Study on the photochromism of Ni-Al layered double hydroxides containing nitrate anions. Eur J Inorg Chem, 2006, 14: 2831–2838

    Article  CAS  Google Scholar 

  13. Zestos AG, Grinnell CL, Vinh LJ, Pike RD, Starnes WH. Metal-exchanged clay and zeolite additives as smoke suppressants and fire retardants for poly(vinyl chloride). J Vinyl Additive Technol, 2009, 15: 87–91

    CAS  Google Scholar 

  14. Jiao Q, Zhao Y, Xie H, Evans DG, Duan X. Intercalation and selective IR adsorption of hydrotalcite. Chin J Appl Chem, 2002, 19(10): 1011–1013

    CAS  Google Scholar 

  15. Chai H, Xu X, Lin Y, Evans DG, Li D. Synthesis and UV absorption properties of 2,3-dihydroxynaphthalene-6-sulfonate anion-intercalated Zn-Al layered double hydroxides. Polym Degrad Stabil, 2009, 94(4): 744–749

    Article  CAS  Google Scholar 

  16. Shi L, Li D, Wang J, Li S, Evans DG, Duan X. Synthesis, flame-retardant and smoke-suppressant properties of a borate-intercalated layered double hydroxide. Clay Clay Miner, 2005, 53(3): 294–300

    Article  CAS  Google Scholar 

  17. Lin YJ, Wang JR, Evans DG, Li DQ. Layered and intercalated hydrotalcite-like material as thermal stabilizers in PVC resin. J Phys Chem Solids, 2006, 67(5–6): 996–1001

    Google Scholar 

  18. Zhang H, Qi R, Evans DG, Duan X. Synthesis and characterization of a novel nano-scale magnetic solid base catalyst involving a layered double hydroxide supported on a ferrite core. J Solid State Chem, 2004, 177(3): 772–780

    Article  CAS  Google Scholar 

  19. Meng J, Zhang H, Evans DG, Duan X. Novel layered pesticide slow/controlled release materials-supramolecular structure and slow release property of glyphosate intercalated layered double hydroxides. Sci China Chem, 2005, 50(8): 745–751

    CAS  Google Scholar 

  20. Sun H, Zhang H, Evans DG, Duan X. Synthesis and characterization of nanoscale magnetic drug-inorganic composites. Sci China Chem, 2005, 50(8): 752–757

    CAS  Google Scholar 

  21. Li DQ, Xu XY, Wang LJ, Lin YJ. Selective infrared absorption material with phosphor-containing intercalation structure. China Patent. CN101376722, 2008-10-10

  22. Wilkes CE, Summers JW, Daniels CA. PVC Handbook, Carl Hanser Verlag, Munich, 2005

    Google Scholar 

  23. Wei M, Yuan Q, Evans DG, Wang Z, Duan X. Layered solids as a “molecular container” for pharmaceutical L-tyrosine-intercalated layered double hydroxides. J Mater Chem, 2005, 15(11): 1197–1203

    Article  CAS  Google Scholar 

  24. Lin YJ, Li DQ, Evans DG, Duan X. Modulating effect of Mg-Al-CO3 LDHs on thermal stability of PVC resin. Polym Degrad Stabil, 2005, 88(2): 286–293

    Article  CAS  Google Scholar 

  25. He J, Li B, Evans DG, Duan X. Synthesis of layered double hydroxides in an emulsion solution. Colloids Surf A, 2004, 251(1–3): 191–196

    Article  CAS  Google Scholar 

  26. Zhang FZ, Sun M, Xu SL, Zhao LL, Zhang BW. Fabrication of oriented layered double hydroxide films by spin coating and their use in corrosion protection. Chem Eng J, 2008, 141(1–3): 362–367

    Article  CAS  Google Scholar 

  27. Zhang X, Wang Y, Chen X, Yang WS. Fabrication and characterization of a novel inorganic MnO2/LDHs multilayer thin film via a layer-by-layer self-assembly method. Mater Lett, 2008, 62(10–11): 1613–1616

    Article  CAS  Google Scholar 

  28. Lü Z, Zhang FZ, Lei XD, Yang L, Xu SL, Duan X. In situ growth of layered double hydroxide films on anodic aluminum oxide/aluminum and its catalytic feature in aldol condensation of acetone. Chem Eng Sci, 2008, 63(16): 4055–4062

    Article  CAS  Google Scholar 

  29. He J, Wei M, Li B, Kang Y, Evans DG, Duan X. Preparation of layered double hydroxides. Struct Bond, 2006, 119: 89–119

    Article  CAS  Google Scholar 

  30. Wang J, Wei M, Rao G, Evans DG, Duan X. Structure and thermal decomposition of sulfated β-cyclodextrin intercalated in a layered double hydroxide. J Solid State Chem, 2004, 177(1): 366–371

    Article  CAS  Google Scholar 

  31. Wei M, Shi S, Wang J, Li Y, Duan X. Studies on the intercalation of naproxen into layered double hydroxide and its thermal decomposition by in situ FT-IR and in situ HT-XRD. J Solid State Chem, 2004, 177(7): 2534–2541

    Article  CAS  Google Scholar 

  32. Yun SK, Pinnavaia TJ. Water content and particle texture of synthetic hydrotalcite-like layered double hydroxides. Chem Mater, 1995, 7(2): 348–354

    Article  CAS  Google Scholar 

  33. Millange F, Walton RI, O’Hare D. Time-resolved in situ X-ray diffraction study of the liquid-phase reconstruction of Mg-Al-carbonate hydrotalcite-like compounds. J Mater Chem, 2000, 10(7): 1713–1720

    Article  CAS  Google Scholar 

  34. Li F, Liu JJ, Evans DG, Duan X. Stoichiometric synthesis of pure MFe2O4 (M=Mg, Co, and Ni) spinel ferrites from tailored layered double hydroxide (hydrotalcite-like) precursors. Chem Mater, 2004, 16(8): 1597–1602

    Article  CAS  Google Scholar 

  35. Reichle WT, Kang SY, Everhardt DS. The nature of the thermal decomposition of a catalytically active anionic clay mineral. J Catal, 1986, 101: 352–359

    Article  CAS  Google Scholar 

  36. Feng Y, Li D, Li C, Wang Z, Evans DG, Duan X. Synthesis of Cu-containing layered double hydroxides with a narrow crystallite-size distribution. Clay Clay Miner, 2003, 51(5): 566–569

    Article  CAS  Google Scholar 

  37. Xu ZP, Braterman PS. High affinity of dodecylbenzene sulfonate for layered double hydroxide and resulting morphological changes. J Mater Chem, 2003, 13: 268–273

    Article  CAS  Google Scholar 

  38. Williams GR, Norquist AJ, O’Hare D. Time-resolved, in situ X-ray diffraction studies of staging during phosphonic acid intercalation into [LiAl2(OH)6]Cl·H2O. Chem Mater, 2004, 16(6): 975–981

    Article  CAS  Google Scholar 

  39. Li F, Zhang LH, Evans DG, Forano C, Duan X. Structure and thermal evolution of Mg-Al layered double hydroxide containing interlayer organic glyphosate anions. Thermochim Acta, 2004, 424(1–2): 15–23

    Article  CAS  Google Scholar 

  40. You YW, Zhao HT, Vance GF. Hybrid organic-inorganic derivatives of layered double hydroxides and dodecylbenzenesulfonate: Preparation and adsorption characteristics. J Mater Chem, 2002, 12(4): 907–912

    Article  CAS  Google Scholar 

  41. Asiawa S, Hirahara H, Ishiyama K, Ogasawara W, Umetsu Y, Natira E. Sugar-anionic clay composite materials: Intercalation of pentoses in layered double hydroxide. J Solid State Chem, 2003, 174(2): 342–348

    Article  CAS  Google Scholar 

  42. Mariko AP, Claude F, Besse JP. Synthesis of Al-rich hydrotalcite-like compounds by using the urea hydrolysis reaction-control of size and morphology. J Mater Chem, 2003, 13: 1988–1993

    Article  CAS  Google Scholar 

  43. Oh JM, Hwang SH, Choy JH. The effect of synthetic conditions on tailoring the size of hydrotalcite particles. Solid State Ionics, 2002, 151(1–4): 285–291

    Article  CAS  Google Scholar 

  44. Mao SB, Li DQ, Zhang FZ, Evans DG, Duan X. In situ synthesis of Ni-Al-CO3 LDHs on the surface of γ-Al2O3. Chin J Inorg Chem, 2004, 20(5): 596–602

    CAS  Google Scholar 

  45. Zhang R, Li DQ, Zhang FZ, Evans DG, Duan X. The in-situ synthesis of LDH in the pores of γ-Al2O3. J Fudan Univ (Nat Sci), 2003, 42(3): 333–338

    CAS  Google Scholar 

  46. He JX, Kobayashi K, Takahashi M, Villemure G, Yamagishi A. Preparation of hybrid films of an anionic Ru(II) cyanide polypyridyl complex with layered double hydroxides by the Langmuir-Blodgett method and their use as electrode modifiers. Thin Solid Films, 2001, 397(1–2): 255–265

    Article  CAS  Google Scholar 

  47. Duan X, Li D, Lv Z, Lin Y, Xu X. A clean method for preparing layered double hydroxides. US Patent Appl No. 11/853,788, 2007-9-11

  48. Tichit D, Lutic D, Coq B. The aldol condensation of acetaldehyde and heptanal on hydrotalcite type catalysts. J Catal, 2003, 219(1): 167–175

    Article  CAS  Google Scholar 

  49. Roelofs JCA, van Dillen AJ, Jong KP. Base-catalyzed condensation of citral and acetone at low temperature using modified hydrotalcite catalysts. Catal Today, 2000, 60(3–4): 297–303

    Article  CAS  Google Scholar 

  50. Unnikrishnan R, Narayanan S. Metal containing layered double hydroxides as efficient catalyst precursors for the selective conversion of acetone. J Mol Catal A, 1999, 144(1): 173–179

    Article  CAS  Google Scholar 

  51. Reichle WT. Catalytic reactions by thermally activated synthetic anionic clay mineral. J Catal, 1985, 94(2): 547–557

    Article  CAS  Google Scholar 

  52. Suzuki E, Nomoto Y, Okamoto M. Disproportionation of triethoxysilane over KF/Al2O3 and heat-treated hydrotalcite. Appl Catal A, 1998, 267(1): 7–10

    Google Scholar 

  53. Palomares AE, Eder-Mirth G, Rep M, Lercher JA. Alkylation of toluene over basic catalysts-key requirements for side chain alkylation. J Catal, 1998, 180(1): 56–65

    Article  CAS  Google Scholar 

  54. José MF, José IG, José AM. Basic solids in the oxidation of organic compounds. Catal Today, 2000, 57(1–2): 3–16

    Google Scholar 

  55. Climent MJ, Corma A, Iborra S. Activated hydrotalcites as catalysts for the synthesis of chalcones of pharmaceutical interest. J Catal, 2004, 221(2): 474–482

    Article  CAS  Google Scholar 

  56. Lv, L, He J, Wei M, Evans DG, Duan X. Uptake of chloride ion from aqueous solution by calcined layered double hydroxides: Equilibrium and kinetic studies. Water Res, 2006, 40(4): 735–743

    Article  CAS  Google Scholar 

  57. Sood A. Process for removing heavy metal ions from solutions using adsorbents containing activated hydrotalcite. US Patent, 4752397, 1988-6-21

  58. Lv, L, He J, Wei M, Evans DG, Duan X. Factors influencing the removal of fluoride from aqueous solution by calcined Mg-Al-CO3 layered double hydroxides. J Hazard Mater, 2006, 133(1–3): 119–128

    Article  CAS  Google Scholar 

  59. Lv, L, He J, Wei M, Evans DG, Duan X. Kinetic studies on fluoride removal by calcined layered double hydroxides. Ind Eng Chem Res, 2006, 45(25): 8623–8628

    Article  CAS  Google Scholar 

  60. Van DVL, Van GMLM, Batenburg LF, Keern JJ, Gielgens LH, Koster TPM, Fischer R. On the action of hydrotalcite-like clay materials as stabilizers in polyvinylchloride. Appl Clay Sci, 2000(1–2), 17: 25–34

    Google Scholar 

  61. Li SF, Li DQ, Shi L, Yang L, Pu M, Evans DG, Duan X. Control of interlayer composition of borate pillared LDHs by varying pH of intercalation. Acta Chim Sinica, 2004, 62(3): 1205–1210

    CAS  Google Scholar 

  62. Xu G, Guo C, Duan X, Jiang C. IR adsorption of layered double hydroxides in polyethylene film. Chin J Appl Chem, 1999, 16(3): 45–48

    CAS  Google Scholar 

  63. Zhang L, Lin Y, Tuo Z, Li D. Synthesis and UV absorption of 5-sulfosalicylic acid anion intercalated zinc-aluminum layered double hydroxides. J Solid State Chem, 2007, 180(4): 1230–1235

    Article  CAS  Google Scholar 

  64. Li DQ, Tuo ZJ, Evans DG, Duan X. Preparation of 5-benzotriazolyl-4-hydroxy-3-sec-butylbenzenesulfonate anion-intercalated layered double hydroxide and its photostabilizing effect on polypropylene. J Solid State Chem, 2006, 179(10): 3114–3120

    Article  CAS  Google Scholar 

  65. Abe Y, Chiba M, Uchiyama H. Hydrotalcite powder comprising nitrite ions, method for preparation thereof, and corrosion inhibitor composition comprising such. Japan Patent, 2005336002, 2005-12-8

  66. Nonaka Y, Sato T. Cement modifier for improving corrosion resistance and durability of mortar and concrete. Japan Patent, 2001089211, 2001-4-3

  67. Tennison S. Current hurdles in the commercial development of inorganic membrane reactors. Membr Tech, 2000, 128: 4–9

    Article  Google Scholar 

  68. Géraud E, Rafqah S, Sarakha M, Forano C, Prevot V, Leroux F. Three dimensionally ordered macroporous layered double hydroxides: Preparation by templated impregnation/coprecipitation and pattern stability upon calcination. Chem Mater, 2008, 20(3): 1116–1125

    Article  CAS  Google Scholar 

  69. Wang Y, Yang WS, Chen C, Evans DG. Fabrication and electrochemical characterization of cobalt-based layered double hydroxide nanosheet thin-film electrodes. J Power Sources, 2008, 184(2): 682–690

    Article  CAS  Google Scholar 

  70. Iyi N, Ebina Y, Sasaki T. Water-swellable MgAl-LDH (layered double hydroxide) hybrids: Synthesis, characterization, and film preparation. Langmuir, 2008, 24: 5591–5598

    Article  CAS  Google Scholar 

  71. Kong X, Shi S, Han J, Zhu F, Wei M, Duan X. Preparation of Glycyl-L-Tyrosine intercalated layered double hydroxide film and its in vitro release behavior. Chem Engineering J, 2010, 157: 598–604

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to YanJun Lin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xu, X., Lin, Y., Evans, D.G. et al. Layered intercalated functional materials based on efficient utilization of magnesium resources in China. Sci. China Chem. 53, 1461–1469 (2010). https://doi.org/10.1007/s11426-010-4031-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11426-010-4031-y

Keywords

Navigation