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An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration

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Abstract

A dicarboxylate ligand, 5-carboxyl-1-carboxymethyl-2-oxidopyridinium (H2L), was utilized to form four complexes with the general formula [M(HL)2(H2O)]·2H2O, M = CuII (1), ZnII (2), MnII (3), CdII (4). The crystals were isomorphous, belonging to the monoclinic C2/c space group. They were constructed from 1D chains and further linked by hydrogen bonds into a novel binodal (6,8)-connected 3D supramolecular network with twofold self-penetration. Photoluminescence studies revealed that complexes 2–4 displayed intense structure-related fluorescent emission bands.

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Authors and Affiliations

  1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, 321004, China

    CaiHong Zhan, WenXuan Cai, YunLong Feng & YinHua He

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  1. CaiHong Zhan
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  2. WenXuan Cai
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  3. YunLong Feng
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  4. YinHua He
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Correspondence to YunLong Feng.

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Zhan, C., Cai, W., Feng, Y. et al. An unusual binodal (6,8)-connected 3D supramolecular network with twofold self-penetration. Sci. China Chem. 53, 1261–1265 (2010). https://doi.org/10.1007/s11426-010-3178-x

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  • DOI: https://doi.org/10.1007/s11426-010-3178-x

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