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Synthesis, structure and physical properties of the one-dimensional chain complex of tetrathiafulvalene carboxylate

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Abstract

A new Co(II) coordination polymer bearing TTF carboxylate group, [{Co2(trioTTF)2(H2O)6}·5H2O]n (1) (trioTTF = 2-(5,6,8,9,11,12,14,15-octahydro-[1,3]dithiolo[4,5-h][1,4,13,7,10]trioxadithiacyclopentadecin-2-ylidene)-1,3-dithiole-4,5-dicarboxylate), has been prepared and characterized. In the structure of 1, shorter intermolecular S····S contacts (3.565 Å) are found between the trioTTF groups from neighboring chains. The electric conductivity of 1 is poor due to the bulky crown-ether group, but it exhibits ferromagnetic interaction at low temperature.

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Authors and Affiliations

  1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, 210093, China

    Ya Chen, ChengHui Li, CaiFeng Wang, JingLin Zuo & XiaoZeng You

  2. Solid State Microstructure Laboratory, Department of Physics, Nanjing University, Nanjing, 210093, China

    Di Wu

Authors
  1. Ya Chen
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  2. ChengHui Li
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  3. CaiFeng Wang
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  4. Di Wu
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  5. JingLin Zuo
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  6. XiaoZeng You
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Corresponding authors

Correspondence to JingLin Zuo or XiaoZeng You.

Additional information

Supported by the Major State Basic Research Development Program (2006CB806104 and 2007CB925100), and the National Science Fund for Distinguished Young Scholars (20725104)

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Chen, Y., Li, C., Wang, C. et al. Synthesis, structure and physical properties of the one-dimensional chain complex of tetrathiafulvalene carboxylate. Sci. China Ser. B-Chem. 52, 1596–1601 (2009). https://doi.org/10.1007/s11426-009-0237-2

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  • DOI: https://doi.org/10.1007/s11426-009-0237-2

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