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Anion coordination complex [Cl⊂Pt(bpt)4]Cl (bpt=N,N′-bis(3-pyridylmethyl)-2-thiourea)

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Abstract

The anion coordination complex, [Cl⊂Pt(bpt)4]Cl (bpt=N,N′-bis(3-pyridylmethyl)-2-thiourea), was synthesized and studied by X-ray crystal structure analysis, NMR and FAB mass spectra. In the solid state, the Pt(bpt)4 anion receptor adopts a cone conformation to bind the chloride anion through hydrogen bonds and electrostatic interaction in which the four branches of the thiourea ligands bind the chloride anion to form N-H⋯Cl− hydrogen bonds (3.49–3.81 Å). The entraped chloride anion is situated above the Pt(II) center at 3.52 Å. Further second-sphere coordination assemby from the Pt(bpt)4 core with 8 zinc(II) tetraphenylporphyrins (ZnPr) is discussed.

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References

  1. Lehn J M. Supramolecular Chemistry: Concepts and Perspectives. Weinheim: VCH, 1995

    Google Scholar 

  2. Bianchi A. Bowman J K, García-España E (eds). Supramolecular Chemistry of Anions. New York: Wiley-VCH, 1997

    Google Scholar 

  3. Gale P A. Anion receptor chemistry: Highlights from 1999. Coord Chem Rev, 2001, 213: 79–128

    Article  CAS  Google Scholar 

  4. Gale P A. Anion coordination and anion-directed assembly: Highlights from 1997 and 1998. Coord Chem Rev, 2000, 199: 181–233

    Article  CAS  Google Scholar 

  5. Bowman-James K. Alfred Werner revisited: The coordination chemistry of anions. Acc Chem Res, 2005, 38: 671–678

    Article  CAS  Google Scholar 

  6. Beer P D. Gale P A. Anion recognition and sensing: The state of the art and future perspectives. Angew Chem Int Ed, 2001, 40: 487–516

    Article  Google Scholar 

  7. Vilar R. Anion-templated synthesis. Angew Chem Int Ed, 2003, 42: 1460–1477

    Article  CAS  Google Scholar 

  8. Snowden T S, Anslyn E V. Anion recognition: Synthetic receptors for anions and their application in sensors. Curr Opin Chem Bio, 1999, 3: 740–746

    Article  CAS  Google Scholar 

  9. Martnez-Mez R, Sancenn F. Fluorogenic and chromogenic chemosensors and reagents for anions. Chem Rev, 2003, 103: 4419–4476

    Article  Google Scholar 

  10. Bondy C R, Gale P A, Loeb S J. Metal-organic anion receptors: Arranging urea hydrogen-bond donors to encapsulate sulfate ions. J Am Chem Soc, 2004, 126(16): 5030–5031

    Article  Google Scholar 

  11. Custelcean R, Remy P, Bonnesen P V, Jiang D, Moyer B A. Sulfate recognition by persistent crystalline capsules with rigidified hydrogen-bonding cavities. Angew Chem Int Ed, 2008, 47: 1866–1870

    Article  CAS  Google Scholar 

  12. Wu B, Liang J, Yang J, Jia C, Yang X J, Zhang H, Tang N, Janiak C. Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination. Chem Commun, 2008, 48: 1762–1764

    Article  Google Scholar 

  13. Yu S Y, Huang H., Liu H B. Modular cavity-tunable self-assembly of molecular bows and crowns as structural analogues of calix[3]arenes. Angew Chem Int Ed, 2003, 42: 686–690

    Article  CAS  Google Scholar 

  14. Li S H, Huang H P, Yu S Y. Self-assembly of coordination molecular baskets as inorganic analogues of cyclotriveratrylenes (CTV). Dalton Trans, 2005, 14: 2346–2349

    Article  Google Scholar 

  15. Liu L X, Huang H P, Li X, Sun Q F, Sun C R, Li Y Z, Yu S Y. Coordination molecular hats binding acetonitrile via C-H⋯π interactions. Dalton Trans, 2008, 12: 1544–1546

    Article  Google Scholar 

  16. Battaglia L P, Bonamartini C A, Vidoni T M E. Tetrakis (N,N′-diethylthiourea) platinum(II) chloride monohydrate, C20H50Cl21N8OPtS4. Cryst Struct Commun, 1975, 4: 361

    Google Scholar 

  17. Sanders J K M. Comprehensive Supramolecular Chemistry (Chair ed Lehn J M). Oxford: Pergamon, 1996, Vol 9. 132–162

    Google Scholar 

  18. Xu H, Ng D P. Construction of Subphthalocyanine-Porphyrin and Subphthalocyanine-Phthalocyanine Heterodyads through Axial Coordination. Inorg Chem, 2008, 47: 7921–7927

    Article  CAS  Google Scholar 

  19. Shmilovits M, Vinodu M, Goldberg I. Coordination polymers of tetra(4-carboxyphenyl)porphyrins sustained by tetrahedral zinc ion linkers. Crys Grow Des, 2004, 3: 633–638

    Article  Google Scholar 

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Authors and Affiliations

  1. Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing, 100872, China

    Xin Li & ShuYan Yu

  2. School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, China

    Hui Li

  3. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, China

    YiZhi Li

  4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

    ShuYan Yu

Authors
  1. Xin Li
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  2. Hui Li
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  3. ShuYan Yu
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  4. YiZhi Li
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Corresponding author

Correspondence to Hui Li.

Additional information

Supported by the National Natural Science Foundation of China (Grant Nos. 50673098 & 20772152), Renmin University of China, State Key Laboratory of Structure Chemistry (Grant No. 20080052)

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Li, X., Li, H., Yu, S. et al. Anion coordination complex [Cl⊂Pt(bpt)4]Cl (bpt=N,N′-bis(3-pyridylmethyl)-2-thiourea). Sci. China Ser. B-Chem. 52, 471–474 (2009). https://doi.org/10.1007/s11426-009-0099-7

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  • DOI: https://doi.org/10.1007/s11426-009-0099-7

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