Abstract
Methanesulfonic acid (MSA) has been identified as one of the most important intermediate products of DMS reactions in the atmosphere. Although considerable amounts of MSA have been found in the marine boundary layer, little is known about the interaction of gaseous MSA with sea salt particles. To understand the fate of MSA in the atmosphere and its potential importance in atmospheric chemistry, the heterogeneous reactions of gaseous MSA with micron-scale NaCl and sea salt particles were studied using diffuse reflectance infrared Fourier transform spectrometry, X-ray photoelectron spectroscopy, and scanning electron microscopy. The CH3SO3Na and CH3SO3 − were the major products of the condensed phase of the reaction of gaseous MSA with NaCl and with sea salt particles. The steady-state uptake coefficient was determined to be (5.94±2.32)×10−7 (1 σ) for the reaction of gaseous MSA with NaCl particles and (2.23±1.25)×10−7 (1 σ) for the reaction of gaseous MSA with sea salt particles. The heterogeneous reaction of MSA with NaCl particles was found to be first-order for MSA. The reaction mechanisms were discussed.
Similar content being viewed by others
References
Charlson R J, Lovelock J E, Andreae M O, Warren S G. Oceanic phytoplankton, atmospheric sulfur, cloud albedo and climate. Nature, 1987, 326(16): 655–661
Yin F, Grosjean D, Seinfeld J H. Photooxidation of dimethyl sulfide and dimethyl disulfide. I: Mechanism development. J Atmos Chem, 1990, 11(4): 309–364
Stickel R E, Nicovich J M, Wang S, Zhao Z, Wine P H. Kinetic and mechanistic study of the reaction of atomic chlorine with dimethyl sulfide. J Phys Chem, 1992, 96(24): 9875–9883
Butkovskaya N I, Lebras G. Mechanism of the NO3 + DMS reaction by discharge flow mass spectrometry. J Phys Chem, 1994, 98(10): 2582–2591
Butkovskaya N I, Poulet G, Lebras G. Discharge flow study of the reactions of chlorine and fluorine atoms with dimethyl sulfide. J Phys Chem, 1995, 99(13): 4536–4543
Barnes I, Becker K H, Patroescu I. FTIR product study of the OH initiated oxidation of dimethyl sulphide observation of carbonyl sulphide and dimethyl sulphoxide. Atmos Environ, 1996, 30(10–11): 1805–1814
BeDjanian Y, Poulet G, Lebras G. Kinetic study of the reaction of BrO radicals with dimethylsulfide. Int J Chem Kinet, 1996, 28(5): 383–389
Ingham T, Bauer D, Sander R, Crutzen P J, Crowley J N. Kinetics and products of the reactions BrO+DMS and Br+DMS at 298 K. J Phys Chem A, 1999, 103(36): 7199–7209
Patroescu I V, Barnes I, Becker K H, Mihalopoulos N. FT-IR product study of the OH-initiated oxidation of DMS in the presence of NOx. Atmos Environ, 1999, 33(1): 25–35
Arsene C, Barnes I, Becker K H, Mocanu R. FT-IR product study on the photo-oxidation of dimethyl sulphide in the presence of NOx-temperature dependence. Atmos Environ, 2001, 35(22): 3769–3780
Ballesteros B, Jensen N R, Hjorth J. FT-IR study of the kinetics and products of the reactions of dimethylsulphide, dimethylsulphoxide and dimethylsulphone with Br and BrO. J Atmos Chem, 2002, 43(2): 135–150
Du L, Xu Y F, Ge M F, Jia L, Yao L, Wang W G. Rate constant of the gas phase reaction of dimethyl sulfide (CH3SCH3) with ozone. Chem Phys Lett, 2007, 46(1–3): 36–40
Barnes I, Hjorth J, Mihalopoulos N. Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere. Chem Rev, 2006, 106(3): 940–975
Berresheim H, Huey J W, Thorn R P, Eisele F L, Tanner D J, Jefferson A. Measurements of dimethyl sulfide, dimethyl sulfoxide, dimethyl sulfone, and aerosol ions at Palmer Station, Antarctica. J Geophys Res Atmos, 1998, 103(D1): 1629–1637
Davis D, Chen G, Kasibhatla P, Jefferson A, Tanner D, Eisele F, Lenschow D, Neff W, Berresheim H. DMS oxidation in Antarctic marine boundary layer: Comparison of model simulations and field observations of DMS, DMSO, DMSO2, H2SO4(g), MSA(g), and MSA(p). J Geophys Res-Atmos, 1998, 103(D1): 1657–1678
Davis D, Chen G, Bandy A, Thronton D, Eisele F, Mauldin L, Tanner D, Lenschow D, Fuelberg H, Herbert B, Heath J, Clarke A, Blake D. Dimethyl sulfide oxidation in the equatorial Pacific: Comparison of model simulations and field observations of DMS, SO2, H2SO4(g), MSA(g), MS, and NSS. J Geophys, Res Atmos, 1999, 104(D5): 5765–5784
Bardouki H, Berresheim F, Vrekoussis M, Sciare J, Kouvarakis G, Oikonomou K, Schneider J, Mihalopoulos N. Gaseous (DMS, MSA, SO2, H2SO4, and DMSO) and particulate (sulfate and methanesulfonate) sulfur species over the northeastern coast of Crete. Atmos Chem Phys, 2003, 3(5): 1871–1886
De Bruyn W J, Shorter J A, Davidovits P, Worsnop D R, Zahniser M S, Kolb C E. Uptake of gas phase sulfur species methanesulfonic acid, dimethylsulfoxide, and dimethyl sulfone by aqueous surfaces. J Geophys Res Atmos, 1994, 16(D8): 16927–16932
Schweitzer F, Magi L, Mirabel P, George C. Uptake rate measurement of methanesulfonic acid and glyoxal by aqueous droplet. J Phys Chem A, 1998, 102(3): 593–600
Hanson D R. Mass accommodation of H2SO4 and CH3SO3H on water-sulfuric acid solutions from 6% to 97% RH. J Phys Chem A, 2005, 109(31): 6919–6927
Tang I N, Munkelwitz H R. Determination of vapor pressure from droplet evaporation kinetics. J Colloid Interf Sci, 1991, 141(1), 109–118
Hoffman R C, Kaleuati M A, Finlayson-Pitts B J. Knudsen cell studies of the reaction of gaseous HNO3 with NaCl using less than a single layer of particles at 298K: A modified mechanism. J Phys Chem A, 2003, 107(39): 7818–7826
Vogt R, Finlayson-Pitts B J. A diffuse reflectance infrared transform spectroscopic (DRIFTS) study of the surface reaction of NaCl with gaseous NO2 and HNO3. J Phys Chem A, 1994, 98(14): 3747–3755
Li H J, Zhu T, Ding J, Chen Q, Xu B Y. Heterogeneous reaction of NO2 on the surface of NaCl particles. Sci China Ser B-Chem, 2006, 49(4): 371–378
Jefferson A, Tanner D J, Eisele F L, Davis D, Chen G, Crawford J, Huey J W, Torres A L, Berresheim H. OH photochemistry and methane sulfonic acid formation in the coastal Antarctic boundary layer. J Geophys Res Atmos, 1998, 103(D1): 1647–1656
Mihalopoulos N, Kerminen V M, Kanakidou M, Berresheim H, Sciare J. Formation of particulate sulfur species (sulfate and methanesulfonate) during summer over the eastern Mediterranean: A modelling approach. Atmos Environ, 2007, 41(32): 6860–687
Author information
Authors and Affiliations
Corresponding author
Additional information
Supported by the National Natural Science Foundation of China (Grant No. 40490265) and the National Basic Research Priorities Program (Grant No. 2002CB410802)
Rights and permissions
About this article
Cite this article
Tang, M., Zhu, T. Heterogeneous reactions of gaseous methanesulfonic acid with NaCl and sea salt particles. Sci. China Ser. B-Chem. 52, 93–100 (2009). https://doi.org/10.1007/s11426-008-0137-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11426-008-0137-x