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Photocatalytic intercalated material based on HLaNb2O7 as host and Cd0.8Zn0.2S as guest

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Abstract

A novel photocatalytic material (Pt,Cd0.8Zn0.2S)/HLaNb2O7 was fabricated by successive intercalation and exchange reactions. The (Pt,Cd0.8Zn0.2S)/HLaNb2O7 possessed a gallery height less than 0.5 nm and showed a broad absorption with wavelength over 370–500 nm. Using (Pt,Cd0.8Zn0.2S)/HLaNb2O7 as catalyst, the photocatalytic H2 evolution was more than 160 cm3 · h−1 · g−1 in the presence of Na2S as a sacrificial agent under irradiation with wavelength more than 290 nm from a 100-W mercury lamp. Furthermore, the catalyst showed photocatalytic activity even under visible light irradiation.

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Correspondence to Wu JiHuai.

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Supported by the National Natural Science Foundation of China (Grant Nos. 50572030 and 50372022) and the Functional Nanomaterials Scientific Special Program of Fujian Province (Grant No. 2005HZ01-4)

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Wu, J., Cheng, Y., Lin, J. et al. Photocatalytic intercalated material based on HLaNb2O7 as host and Cd0.8Zn0.2S as guest. SCI CHINA SER B 50, 514–519 (2007). https://doi.org/10.1007/s11426-007-0087-8

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  • DOI: https://doi.org/10.1007/s11426-007-0087-8

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