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Sunlight-activated AlFeO3/TiO2 photocatalyst

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Abstract

A nanocomposite photocatalyst composed of AlFeO3 and TiO2 is prepared, and characterized through X-ray diffraction. Application of the nanocomposite for the photodegradations of eosin dye and methyl orange gives an improved photoactivity compared with TiO2-only nanomaterials. The optimal concentration of AlFeO3 in the composite is about 1.0 wt% under UV excitation, and 9.0 wt% under sunlight excitation for the improved photoactivity. Furthermore, this nanocomposite is more active for eosin photodegradation if natural sunlight rather than UV is used. This may be due to the reason that adding AlFeO3 nanoparticles into TiO2 matrix can promote the separation of photogener-ated charge carriers, and extend the photoresponse of TiO2 toward visible region, which results in an increase in the solar energy utilization efficiency.

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References

  1. Olis, D. F., Pelizzetti, E., Serpone, N., Photocatalyzed destruction of water contaminants, Environ. Soc. Technol., 1991, 25(9): 1522–1529.

    Google Scholar 

  2. Serpone, N., Brief introductory remarks on heterogeneous photocatalysis, Solar Energy Mater. Solar Cells, 1995, 38: 369–379.

    Article  CAS  Google Scholar 

  3. Hodes, G., Howell, I. D., Peter, L., Nanocrystalline photoelectrochemical cells—A new concept in photovoltaic cells, J. Electrochem. Soc., 1992, 139(11): 3136–3140.

    CAS  Google Scholar 

  4. Sodergren, S., Hagfeldt, A., Olsson, J. et al., Theoretical models for the action spectrum and the current-voltage characteristics of microporous semiconductor films in photoelectrochemical cells, J. Phys. Chem., 1994, 98(21): 5552–5556.

    Google Scholar 

  5. Choi, W., Termin, A., Hoffmann, M. R., The role of metal ion dopants in quantum-sized TiO2: Correlation between photoreactivity and charge carrier recombination dynamics, J. Phys. Chem., 1994, 98(51): 13669–13679.

    Article  Google Scholar 

  6. Mills, A., Davies, R. H., Worsley, D., Water-purification by semiconductor photocatalysis, Chem. Soc. Rev., 1993, 22(6): 417–425.

    Article  CAS  Google Scholar 

  7. Gerisher, H., Heller, A., The role of oxygen in photooxidation of organic molecules on semiconductor particles, J. Phys. Chem., 1991, 95(13): 5261–5267.

    Google Scholar 

  8. Asahi, A., Morikawa, T., Ohwaki, T. et al., Visible-light photocatalysis in nitrogen-doped titanium oxides, Science, 2001, 293(5528): 269–271.

    Article  CAS  Google Scholar 

  9. Fuerte, A., Hernández-Alonso, M. D., Maira, A. J. et al., Visible light-activated nanosized doped-TiO2 photocatalysts, Chem. Commun., 2001, (24): 2718-2719.

  10. Lettmann, C., Hildenbrand, K., Kisch, H. et al., Visible light photodegradation of 4-chlorophenol with a coke-containing titanium dioxide photocatalyst, Appl. Catal. B: Environ., 2001, 32: 215–227.

    Article  CAS  Google Scholar 

  11. Bolton, J. R., The photochemical conversion and storage of solar energy: an historical perspective, Solar Energy Mater. Solar Cells, 1995, 38: 543–554.

    Article  CAS  Google Scholar 

  12. Ross, H., Bending, J., Hecht, S., Sensitized photocatalytical oxidation of terbutylazine, Solar Energy Mater. Solar Cells, 1994, 33: 475–481.

    Article  CAS  Google Scholar 

  13. Vinodgopal, K., Wynkop, D. E., Kamat, P. V., Environmental photochemistry on semiconductor surfaces: Photosensitized degradation of a textile azo dye, acid orange 7, on TiO2 particles using visible light, Environ. Sci. Technol., 1996, 30(5): 1660–1666.

    Article  CAS  Google Scholar 

  14. O’Regan, B., Grätzel, M., A low-cost, high-efficiency solar-cell based on dye-sensitized colloidal TiO2 films, Nature, 1991, 353(6346): 737–740.

    CAS  Google Scholar 

  15. Martin, S. T., Morrison, C. L., Hoffmann, M. R., Photochemical mechanism of size-quantized vanadium-doped TiO2 particles, J. Phys. Chem., 1994, 98(51): 13695–13704.

    Article  CAS  Google Scholar 

  16. Qu, Q., Zhao, J. C., Shou, T., TiO2-assisted photodegradation of dyes: A study of two competitive primary processes in the degradation of RB in an aqueous TiO2 colloidal solution, J. Mol. Catal. A: Chem., 1998, 129: 257–268.

    Article  CAS  Google Scholar 

  17. Herrmann, J. M., Disdier, J., Pichat, P., Effect of chromium doping on the electrical and catalytic properties of powder titania under UV and visible illumination, Chem. Phys. Lett., 1984, 108(6): 618–622.

    Article  CAS  Google Scholar 

  18. Vogel, R., Hoye, P., Weller, H., Sensitization of highly porous, polycrystalline TiO2 electrodes by quantum sized CdS, Chem. Phys. Lett., 1990, 174(3-4): 241–246.

    Article  CAS  Google Scholar 

  19. Liu, D., Kamat, P. V., Photoelectrochemical behavior of thin CdSe and coupled TiO2/CdSe semiconductor films, J. Phys. Chem., 1993, 97(41): 10769–10773.

    Article  CAS  Google Scholar 

  20. Ennaoui, A., Fiechter, S., Tributsch, H. et al., Photoelectrochemical energy-conversion obtained with ultrathin organo-metallic-chemical-vapor-deposition layer of FeS2 (pyrite) on TiO2, J. Elec-trochem. Soc., 1992, 139(9): 2514–2518.

    CAS  Google Scholar 

  21. Yuan, Z. H., You, W., Jia, J. H. et al., Optical absorption red shift of capped ZnFe2O4 nanoparticles, Chinese Phys. Lett., 1998, 15(7): 535–536.

    CAS  Google Scholar 

  22. De Harrt, L. G. J., Blasse, G., Photoelectrochemical properties of ferrites with the spinel structure, J. Electrochem. Soc., 1985, 132(12): 2933–2938.

    Google Scholar 

  23. Liu, J. J., Lu, G. X., He, H. L. et al., Studies on photocatalytic activity of zinc ferrite catalysis synthesized by shock waves, Mater. Res. Bull., 1996, 31(9): 1049–1056.

    Article  CAS  Google Scholar 

  24. Li, X. Y., Li, S. B., Lie, G. X., Characterization of nanometer-size ZnFe2O4 semiconductor catalyst and the iron catalytic activity study, J. Mol. Catal.(in Chinese), 1996, 31(3): 187–193.

    Google Scholar 

  25. Yuan, Z. H., Zhang, L. D., Synthesis, characterization and photocatalytic activity of ZnFe2O4/TiO2 nanocomposite, J. Mater. Chem., 2001, 11: 1265–1268.

    Article  CAS  Google Scholar 

  26. Yuan, Z. H., Zhang, L. D., Influence of ZnO+Fe2O3 additives on the anatase-to-rutile transformation of nanometer TiO2 powders, Nanostru. Mater., 1998, 10(7): 1127–1133.

    CAS  Google Scholar 

  27. Sato, T., Haneda, K., Seki, M. et al., Morphology and magnetic-properties of ultrafine ZnFe2O4 particles, Appl. Phys. A, 1990, 50(1): 13–16.

    Article  Google Scholar 

  28. Al-Ani, S. K. J., Al-Hassany, I. H. O., Al-Dahan, Z. T., The optical-properties and ac conductivity of magnesium phosphate-glasses, J. Mater. Sci., 1995, 30(14): 3720–3729.

    Article  CAS  Google Scholar 

  29. Zhang, C. L., Li, S., Peng, Y. B., Studies on the property of oxygen-deficient ferrite MFe2O4-D, Chem. J. Chinese University (in Chinese), 1998, 19(10): 1537–1541.

    CAS  Google Scholar 

  30. Moser, J., Grätzel, M., Gallay, R., Inhibition of electron-hole recombination in substitutionally doped colloidal semiconductor crystallites, Helv. Chim. Acta, 1987, 70(6): 1596–1604.

    Article  CAS  Google Scholar 

  31. Butler, E. C., Davis, A. P., Photocatalytic oxidation in aqueous titanium-dioxide suspensions—The influence of dissolved transition-metals, J. Photochem. Photobiol. A: Chem., 1993, 70(3): 273–283.

    Article  CAS  Google Scholar 

  32. Schafani, A., Mozzanaga, M. N., Pichat, P., Effect of silver deposits on the photocatalytic activity of titanium-dioxide samples for the dehydrogenation or oxidation of 2-propanol, J. Photochem. Photobio. A: Chem., 1991, 59(2): 181–189.

    Google Scholar 

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Authors and Affiliations

  1. Nanomaterials & Nanotechnology Research Center, School of Materials Science & Engineering, Tianjin University of Technology, Tianjin, 300191, China

    Yuan Zhihao, Wang Yuhong, Sun Yongchang, Wang Jing, Bie Lijian & Duan Yueqing

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  1. Yuan Zhihao
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  2. Wang Yuhong
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  3. Sun Yongchang
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  4. Wang Jing
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  5. Bie Lijian
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  6. Duan Yueqing
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Correspondence to Yuan Zhihao.

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Yuan, Z., Wang, Y., Sun, Y. et al. Sunlight-activated AlFeO3/TiO2 photocatalyst. SCI CHINA SER B 49, 67–74 (2006). https://doi.org/10.1007/s11426-004-0106-y

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  • DOI: https://doi.org/10.1007/s11426-004-0106-y

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