Abstract
Purpose
Carbonate components in soils and sediments play a crucial role in the study of surface processes and the reconstruction of paleoclimates. The extraction of carbonate components from soils and sediments is often carried out using different types of acids. However, which reagents can effectively extract the carbonate components while minimizing the destruction of non-carbonate minerals in soils and sediments has not been fully explored yet.
Methods
The present study conducted a series of conditional leaching experiments on six standard soil and sediment samples with diverse geological backgrounds and varying carbonate contents.
Results
The results revealed that dilute acetic acid (HOAc, 0.5 mol/L) performed better than acid solution (HCl) and acetic acid buffer solution (NaOAc-HOAc) in promoting the complete dissolution of carbonate minerals and avoiding the dissolution of clay minerals. It was also observed that pre-treating the samples with neutral ammonium acetate buffer solution (NH4OAc) or potassium chloride buffer solution (KCl) was necessary to remove exchangeable components. The Mg/Ca ratios of the silicate components after leaching carbonate in the standard soil and sediment samples we used exhibited significant differences (ranging from 0.41 to 1.60).
Conclusion
The dilute acetic acid (HOAc, 0.5 mol/L) is advisable for the extraction of carbonate components from soils and sediments, and the pre-treatment of removing exchangeable components is essential for samples with low carbonate content. It is more reasonable to use the element ratios of the dilute acid insoluble fraction or the average compositions of minerals in soils and sediments for individual correction for the contribution of the silicate components.
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Data availability
Data available on request from the authors.
References
Alonso-Zarza AM, Wright VP (2010) Chapter 5 Calcretes. In: Alonso-Zarza AM, Tanner LH (eds) Developments in sedimentology. Elsevier, pp 225–267
Brazier JM, Schmitt AD, Gangloff S, Pelt E, Gocke MI, Wiesenberg GLB (2020) Multi-isotope approach (δ44/40Ca, δ88/86Sr and 87Sr/86Sr) provides insights into rhizolith formation mechanisms in terrestrial sediments of Nussloch (Germany). Chem Geol 545:119641. https://doi.org/10.1016/j.chemgeo.2020.119641
Cerling TE (1984) The stable isotopic composition of modern soil carbonate and its relationship to climate. Earth Planet Sc Lett 71(2):229–240. https://doi.org/10.1016/0012-821X(84)90089-X
Chester R, Hughes MJ (1967) A chemical technique for the separation of ferro-manganese minerals, carbonate minerals and adsorbed trace elements from pelagic sediments. Chem Geol 2:249–262. https://doi.org/10.1016/0009-2541(67)90025-3
Derry LA, Kaufman AJ, Jacobsen SB (1992) Sedimentary cycling and environmental change in the Late Proterozoic: evidence from stable and radiogenic isotopes. Geochim Cosmochim Ac 56(3):1317–1329. https://doi.org/10.1016/0016-7037(92)90064-P
Gupta SK, Chen KY (1975) Partitioning of trace metals in selective chemical fractions of nearshore sediments. Environ Lett 10(2):129–158
Hodgson JF (1960) Cobalt reactions with montmorillonite. Soil Sci Soc Am J 24(3):165–168
Kämpf L, Plessen B, Lauterbach S, Nantke C, Meyer H, Chapligin B, Brauer A (2019) Stable oxygen and carbon isotopes of carbonates in lake sediments as a paleoflood proxy. Geology 48(1):3–7. https://doi.org/10.1130/G46593.1
Li GJ, Ji JF, Zhao L, Mao CP, Chen J (2008) Response of silicate weathering to monsoon changes on the Chinese Loess Plateau. CATENA 72(3):405–412. https://doi.org/10.1016/j.catena.2007.07.006
Li GJ, Chen J, Chen Y (2013) Primary and secondary carbonate in Chinese loess discriminated by trace element composition. Geochim Cosmochim Ac 103:26–35. https://doi.org/10.1016/j.gca.2012.10.049
Liu C, Wang ZR, Raub TD (2013) Geochemical constraints on the origin of Marinoan cap dolostones from Nuccaleena Formation, South Australia. Chem Geol 351:95–104. https://doi.org/10.1016/j.chemgeo.2013.05.012
Ma L, Sun YB, Jin ZD, Bao ZA, Zhang P, Meng ZK, Yuan HL, Long XP, He MY, Huang KJ (2019) Tracing changes in monsoonal precipitation using Mg isotopes in Chinese loess deposits. Geochim Cosmochim Ac 259:1–16. https://doi.org/10.1016/j.gca.2019.05.036
Pogge von Strandmann PAE, Jenkyns HC, Woodfine RG (2013) Lithium isotope evidence for enhanced weathering during Oceanic Anoxic Event 2. Nat Geosci 6(8):668–672. https://doi.org/10.1038/ngeo1875
Quevauviller P (1998) Operationally defined extraction procedures for soil and sediment analysis I. Standardization Trac-Trend Anal Chem 17(5):289–298
Rapuc W, Bouchez J, Sabatier P, Genuite K, Poulenard J, Gaillardet J, Arnaud F (2021) Quantitative evaluation of human and climate forcing on erosion in the alpine critical zone over the last 2000 years. Quaternary Sci Rev 268:107127. https://doi.org/10.1016/j.quascirev.2021.107127
Rauret G, López-Sánchez JF, Sahuquillo A, Rubio R, Davidson C, Ure A, Quevauviller P (1999) Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials. J Environ Monitor 1(1):57–61. https://doi.org/10.1039/A807854H
Ray S, Gault HR, Dodd CG (1957) The separation of clay minerals from carbonate rocks. Am Mineral 42:681–686
Rea DK, Janecek TR (1981) Mass-accumulation rates of the non-authigenic inorganic crystalline (Eolian) component of deep-sea sediments from the western mid-pacific mountains, deep sea drilling project site 463. In: Stout LN (ed) Initial reports of the deep sea drilling project volume 62. U.S. Government Printing Office, Washington, D.C., pp 653–659. https://doi.org/10.2973/dsdp.proc.62.125.1981
Ruan XB, Yang YB, Fang XM, Yang RS, Ye CC (2018) The experimental investigation of acetic acid extraction of non-carbonate Mg in sediments: an example from the mid-Miocene to Pliocene sediments of Xining Basin. Quaternary Sci 38(1):118–129. https://doi.org/10.11928/j.issn.10017410.2018.01.10. (In Chinese with English abstract)
Stuut JBW, Prins MA, Schneider RR, Weltje GJ, Jansen JHF, Postma G (2002) A 300-kyr record of aridity and wind strength in southwestern Africa: inferences from grain-size distributions of sediments on Walvis Ridge. SE Atlantic Mar Geol 180(1):221–233. https://doi.org/10.1016/s0025-3227(01)00215-8
Tachambalath AP, France-Lanord C, Galy A, Rigaudier T, Charreau J (2023) Data report: major and trace element composition of silicates and carbonates from Bengal Fan sediments, IODP Expedition 354. Proceedings of the International Ocean Discovery Program 354(204):1–9
Tessier A, Campbell PGC, Bisson M (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal Chem 51(7):844–851
Yang S, Liu DQ, Yang Z, Wang CX, Chen XH, Li H, Li Q, Yang BG, Li YL (2021) Occurrence and mobility of trace elements during oxidant stimulation of shales in Yichang. Hubei Province of China Appl Geochem 127:104913. https://doi.org/10.1016/j.apgeochem.2021.104913
Yokoo Y, Nakano T, Nishikawa M, Quan H (2004) Mineralogical variation of Sr–Nd isotopic and elemental compositions in loess and desert sand from the central Loess Plateau in China as a provenance tracer of wet and dry deposition in the northwestern Pacific. Chem Geol 204(1):45–62. https://doi.org/10.1016/j.chemgeo.2003.11.004
Zhang X, Xu ZF, Liu WJ, Moon S, Zhao T, Zhou XD, Zhang JY, Wu Y, Zhou L (2019) Hydro-geochemical and Sr isotope characteristics of the Yalong River Basin, eastern Tibetan Plateau: implications for chemical weathering and controlling factors. Geochem Geophy Geosy 20:1221–1239. https://doi.org/10.1029/2018GC007769
Acknowledgements
This work was financially supported by the National Key Research and Development Program of China (Grant No. 2022YFC3901205).
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Xu, Y., Li, Y., Wang, P. et al. The extraction of carbonate components from soils and sediments: an experimental investigation by using different leaching acids. J Soils Sediments (2024). https://doi.org/10.1007/s11368-024-03779-w
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DOI: https://doi.org/10.1007/s11368-024-03779-w