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Journal of Soils and Sediments

, Volume 18, Issue 4, pp 1729–1742 | Cite as

Comparison of direct benthic flux to ebullition-facilitated flux of polycyclic aromatic hydrocarbons and heavy metals measured in the field

  • Priscilla Viana
  • Ke Yin
  • Karl Rockne
Sediments, Sec 2 • Physical and Biogeochemical Processes • Research Article

Abstract

Purpose

No studies to date have compared directly the ebullition-facilitated organic and metal contaminant fluxes to direct benthic contaminant fluxes measured in the field. To address this knowledge gap, we measured benthic organic and metal contaminant fluxes at the sediment-water interface and compared them to simultaneously measured ebullition-facilitated contaminant fluxes at nine sites in a contaminated waterway in the Chicago River, IL, USA, to determine the relative importance of each transport mechanism to total sediment release.

Materials and methods

Two benthic flux chambers with integrated gas ebullition samplers were built to measure both gas ebullition and in situ fluxes of polycyclic aromatic hydrocarbons (PAHs), metals, sulfide, ammonia, nitrate, dissolved organic carbon (DOC), total filtered phosphorus (TFP), and dissolved oxygen (DO) across the sediment-water interface over time. Aqueous pH and oxidation-reduction potential (ORP) within the chamber were also monitored. The gas ebullition collection system trapped heavy metals and the 16 United States Environmental Protection Agency (USEPA) priority-pollutant PAHs (Σ16PAH) transported with gas bubbles through sorption and particle entrainment on a pre-combusted glass wool trap as in our previous studies.

Results and discussion

The results demonstrate that gas ebullition contaminant transport is a significant source of pollution release to the water column, as great as or greater than direct benthic transport. In several sites, release rates of Σ16PAHs and some metals from the sediment by gas ebullition were more than an order of magnitude higher than from direct benthic release. The average total PAH ebullition-facilitated release of all sites is predicted to be nearly 0.5 g m−2 on an annual basis.

Conclusions

Gas ebullition is an important pathway for release of PAHs and heavy metal pollutants to the water column and monitoring of this important release pathway should be performed to adequately address the true environmental impacts of polluted sediments.

Keywords

Benthic flux Contaminated sediment Gas ebullition Metals PAHs Transport 

Notes

Acknowledgements

This work was supported by grant BES-0348512 from the National Science Foundation and funding from the USACE Chicago District. Priscilla Viana also received a fellowship from the CAPES-Fulbright foundation to support part of this work. We thank MWRD of Greater Chicago personnel for assistance with sampling.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2017

Authors and Affiliations

  1. 1.ArcadisChicagoUSA
  2. 2.Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research InstituteNanyang Technological UniversitySingaporeSingapore
  3. 3.Department of Civil and Materials Engineering, 3077 Engineering Research FacilityUniversity of Illinois at ChicagoChicagoUSA

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