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Assessment of potentially toxic element contamination in soils from Portman Bay (SE, Spain)

Abstract

Purpose

The present study deals with the geochemical fractions of Pb, Cd, Zn, Cu and As present on profiles using chemical simple extraction process. This work was conducted on Portman Bay, located in the SE Spain and strongly affected by mining activities.

Materials and methods

Four simple extractions were applied to selected samples in order to evaluate the potential mobility of metals. X-ray diffraction (XRD) was applied to the characterisation of samples and the residues remaining after each extraction, providing additional information about the sediment phases carrying the elements studied.

Results and discussion

The results obtained after the extractions suggested that the highest potentially toxic element (PTE) content was obtained in the oxidising medium. The mineralogical composition is an important factor that should be taken into account in the evaluation of PTE mobility, firstly because the mineral phases react differently in the proposed situations depending on their chemical nature, and secondly, because the presence of a particular phase depends on the degree of weathering.

Conclusions

The evaluation of PTE mobility and mineralogical composition under different environmental conditions may be very important in the execution of restoration projects which could involve dredging and mobilisation of materials.

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References

  • Álvarez MB, Domini CE, Garrido M, Lista AG, Fernández-Band BS (2011) Single-step chemical extraction procedures and chemometrics for assessment of heavy metal behaviour in sediment samples from the Bahía Blanca estuary, Argentina. J Soils Sediments 11:657–666

    Article  Google Scholar 

  • Adamo P, Denaix L, Terribile F, Zampella M (2003) Characterization of heavy metals in contaminated volcanic soils of the Solofrana river valley (southern Italy). Geoderma 117:347–366

    CAS  Article  Google Scholar 

  • Arenas-Lago D, Andrade ML, Lago-Vila M, Rodríguez-Seijo A, Vega FA (2014) Sequential extraction of heavy metals in soils from a copper mine: distribution in geochemical fractions. Geoderma 230-231:108–118

    CAS  Article  Google Scholar 

  • Burges A, Epelde L, Garbisu C (2015) Impact of repeated single-metal and multimetal pollution events on soil quality. Chemosphere 120:8–15

    CAS  Article  Google Scholar 

  • Daldou G, Souissi R, Souissi F, Jemmali N (2015) Chakroun HK (2015) assessment and mobility of heavy metals in carbonated soils contaminated by old mine tailings in North Tunisia. J Afr Earth Sci 110:150–159

    Article  Google Scholar 

  • FAO (2006) In: IUSS (ed) World reference base for soil resources. Rome, ISRIC

    Google Scholar 

  • Furness RW, Rainbow PS (1990) Heavy metals in the marine environment. CRC Press, Florida

    Google Scholar 

  • García-Lorenzo ML, Pérez-Sirvent C, Molina-Ruiz J, Martínez-Sánchez MJ (2014) Mobility indices for the assessment of metal contamination in soils affected by old mining activities. J Geochem Explor 147:117–129

    Article  Google Scholar 

  • García-Lorenzo ML, Martínez-Sánchez MJ, Pérez-Sirvent C, Molina-Ruiz J (2012) Trace elements contamination in an abandoned mining site in a semiarid zone. J Geochem Explor 113:23–35

    Article  Google Scholar 

  • Gómez-García C, Martín-Hernández F, López-García JA, Martínez-Pagán P, Manteca JI, Carmona C (2015) Rock magnetic characterization of the mine tailings in Portman Bay (Murcia, Spain) and its contribution to the understanding of the bay infilling process. J Appl Geophys 120:48–59

    Article  Google Scholar 

  • Haney EB, Haney RL, Hossner LR, White GN (2006) Neutralization potential determination of siderite (FeCO3) using selected oxidants. J Environ Qual 35:871–879

    CAS  Article  Google Scholar 

  • Legrand L, Abdelmoula M, Géhin A, Chaussé A, Génin J-MR (2001) Electrochemical formation of a new Fe(II)-Fe(III) hydroxycarbonate green rust: characterisation and morphology. Electrochim Acta 46:1815–1822

    CAS  Article  Google Scholar 

  • Leleyter L, Rousseau C, Biree L, Baraud F (2012) Comparison of EDTA, HCl and sequential extraction procedures, for selected metals (Cu, Mn, Pb, Zn), in soils, riverine and marine sediments. J Geochem Explor 116-117:51–59

    CAS  Article  Google Scholar 

  • López-García JA, Manteca JI, Astudillo J (1986) Geoquímica de las zonas de oxidación de los yacimientos de Fe-Pb-Zn de la Sierra de Cartagena (SE de España). Boletín de la Sociedad Española de Mineralogía 9:367–373

    Google Scholar 

  • López-García JA, Lunar R, Oyarzun R (1988) Silver and lead mineralogy in gossan-type deposits of Sierra de Cartagena, southeast Spain. Trans Inst Min Metall, Sect B 97:82–88

    Google Scholar 

  • Luo X-S, Xue Y, Wang Y-L, Cang L, Xu B, Ding J (2015) Source identification and apportionment of heavy metals in urban soil profiles. Chemosphere 127:152–157

    CAS  Article  Google Scholar 

  • Martínez-Sánchez MJ, Navarro MC, Pérez-Sirvent C, Marimón J, Vidal J, García-Lorenzo ML, Bech J (2008) Assessment of the mobility of metals in a mining-impacted coastal area (Spain, Western Mediterranean). J Geochem Explor 96:171–182

    Article  Google Scholar 

  • Martínez-Sánchez MJ, García-Lorenzo ML, Pérez-Sirvent C, González E, Pérez V, Martínez S, Martínez L, Molina J (2014) Heavy metal immobilisation by limestone filler in soils contaminated by mining activities: effects on metal leaching and ecotoxicity. Int J Min Reclam Environ 28(6):414–425

    Article  Google Scholar 

  • Mehra OP, Jackson ML (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate. Clay Miner Bull 7:317–327

    Article  Google Scholar 

  • Navarro MC, Pérez-Sirvent C, Martínez-Sánchez MJ, Vidal J, Tovar PJ, Bech J (2008) Abandoned mine sites as a source of contamination by heavy metals: a case study in a semi-arid zone. J Geochem Explor 96:183–193

    CAS  Article  Google Scholar 

  • Oen IS, Fernández JC, Manteca JI (1975) The lead-zinc and associated ores of La Unión, Sierra de Cartagena, Spain. Econ Geol 70:1259–1278

    Article  Google Scholar 

  • Pandey M, Tripathi S, Pandey AK, Tripathi BD (2014) Risk assessment of metal species in sediments of the river Ganga. Catena 122:140–149

    CAS  Article  Google Scholar 

  • Passos EA, Alves JC, dos Santos IS, Alves JPH, García CAB, Spínola AC (2010) Assessment of trace metals contamination in estuarine sediments using a sequential extraction technique and principal component analysis. Microchem J 96:50–57

  • Peña JA, Manteca JI, Martínez-Pagán P, Teixidó T (2013) Magnetic gradient map of the mine tailings in Portman Bay (Murcia, Spain) and its contribution to the understanding of the bay infilling process. J Appl Geophys 95:115–120

    Article  Google Scholar 

  • Pérez-Sirvent C, Hernández-Pérez C, Martínez-Sánchez MJ, García-Lorenzo ML, Bech J (2016) Geochemical characterisation of surface waters, topsoils and efflorescences in a historic metal-mining area in Spain. J Soils Sediments 16:1238–1252

    Article  Google Scholar 

  • Rauret G, Lopez-Sanchez JF, Luck D, Yli-Halla M, Muntau H, Quevauviller P (2001) The certification of the extractable contents (mass fractions) of Cd, Cr, Cu, Ni, Pb and Zn in fresh water sediment following a sequential extraction procedure BCR-701. European Commission, EUR 19775 EN, Luxembourg

    Google Scholar 

  • Sutherland RA (2010) BCR®-701: a review of 10-years of sequential extraction analyses. Anal Chim Acta 680:10–20

    CAS  Article  Google Scholar 

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Correspondence to Carmen Pérez-Sirvent.

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Responsible editor: Claudio Bini

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Pérez-Sirvent, C., García-Lorenzo, M.L., Hernández-Pérez, C. et al. Assessment of potentially toxic element contamination in soils from Portman Bay (SE, Spain). J Soils Sediments 18, 2248–2258 (2018). https://doi.org/10.1007/s11368-017-1756-7

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  • DOI: https://doi.org/10.1007/s11368-017-1756-7

Keywords

  • Environmental risk
  • Geochemical fractions
  • Potentially toxic elements
  • Selective chemical extraction