Abstract
A two-step treatment of mahua oil was conducted to synthesize mahua biodiesel using heterogeneous biomass-based catalyst derived from mahua shell. Mahua oil having higher free fatty acid (FFA) content (about 19%) was esterified to reduce the FFA content up to 1%. The esterification process was carried out using 200 mL mahua oil, 5:1 molar ratio (methanol:oil), and 2.25 weight% of H2SO4 at a temperature of 60 °C for 3 h. Post esterification, a set of 16 experiments were created using a Box–Behnken design (BBD)–based response surface methodology (RSM) approach to conduct the transesterification of the esterified oil. Molar ratio, catalyst loading, reaction temperature, and reaction time were the four input variables chosen for the design of experiments. The optimized conditions for maximum biodiesel yield (87.7%) were found to be 14.88 molar ratio, 3.578% catalyst loading, 69.7 °C reaction temperature, and 81.9 min reaction time. The Diesel RK engine simulation tool which was experimentally validated for baseline diesel fuel was used for numerical simulation of mahua biodiesel. The performance, combustion, and emission behavior of mahua biodiesel analyzed using numerical simulation presented the sustainability of mahua biodiesel as an alternate fuel.
Similar content being viewed by others
Data availability
The datasets used and/or analyzed during the current study are available from the corresponding author upon reasonable request.
References
Abdullahi Khadijat O, Sunday YS, Samuel-Musa Umaru M, Aris O-A, Folorunsho A (2023) Optimization of biodiesel production from Allamanda seed oil using design of experiment. Fuel Commun 14:100081. https://doi.org/10.1016/j.jfueco.2022.100081
Ahmed M, Ahmad KA, Vo D-V, Yusuf M, Haq A, Abdullah A, Aslam M, Patle DS, Ahmad Z, Ahmad E, Athar M (2023) Recent trends in sustainable biodiesel production using heterogeneous nanocatalysts: function of supports, promoters, synthesis techniques, reaction mechanism, and kinetics and thermodynamic studies. Energy Convers Manag 280:116821. https://doi.org/10.1016/j.enconman.2023.116821
Ansari K, Goga G, Mohan R (2022) Performance and emission characteristics of mahua blended biodiesel. Mater Today Proc 71:293–299. https://doi.org/10.1016/j.matpr.2022.09.154
Bai H, Tian J, Talifu D, Okitsu K, Abulizi A (2022) Process optimization of esterification for deacidification in waste cooking oil: RSM approach and for biodiesel production assisted with ultrasonic and solvent. Fuel 318:123697. https://doi.org/10.1016/j.fuel.2022.123697
Bora AP, Dhawane SH, Anupam K, Halder G (2018) Biodiesel synthesis from Mesua ferrea oil using waste shell derived carbon catalyst. Renew Energy 121:195–204. https://doi.org/10.1016/j.renene.2018.01.036
Chowdhury S, Dhawane SH, Jha B, Pal S, Sagar R, Hossain A, Halder G (2021) Biodiesel synthesis from transesterified Madhuca indica oil by waste egg shell–derived heterogeneous catalyst: parametric optimization by Taguchi approach. Biomass Convers Biorefinery 11:1171–1181. https://doi.org/10.1007/s13399-019-00512-3
Dharmalingam B, Balamurugan S, Wetwatana U et al (2023) Comparison of neural network and response surface methodology techniques on optimization of biodiesel production from mixed waste cooking oil using heterogeneous biocatalyst. Fuel 340:127503. https://doi.org/10.1016/j.fuel.2023.127503
Gnanasekaran S, Saravanan N, Ilangkumaran M (2016) Influence of injection timing on performance, emission and combustion characteristics of a DI diesel engine running on fish oil biodiesel. Energy 116:1218–1229. https://doi.org/10.1016/j.energy.2016.10.039
Jena PC, Raheman H, Prasanna Kumar GV, Machavaram R (2010) Biodiesel production from mixture of mahua and Simarouba oils with high free fatty acids. Biomass Bioenerg 34:1108–1116. https://doi.org/10.1016/j.biombioe.2010.02.019
Karimshoushtari M, Novara C (2020) Design of experiments for nonlinear system identification: a set membership approach. Automatica 119:109036. https://doi.org/10.1016/j.automatica.2020.109036
Karmakar A, Karmakar S, Mukherjee S (2010) Properties of various plants and animals feedstocks for biodiesel production. Bioresour Technol 101:7201–7210. https://doi.org/10.1016/j.biortech.2010.04.079
Karmakar B, Dhawane SH, Halder G (2018) Optimization of biodiesel production from castor oil by Taguchi design. J Environ Chem Eng 6:2684–2695. https://doi.org/10.1016/j.jece.2018.04.019
Karthickeyan V, Ashok B, Nanthagopal K, Thiyagarajanc S, Edwin Geo V (2019) Investigation of novel Pistacia khinjuk biodiesel in DI diesel engine with post combustion capture system. Appl Therm Eng 159:113969. https://doi.org/10.1016/j.applthermaleng.2019.113969
Kesharvani S, Dwivedi G, Verma TN (2023) Optimization of performance characteristics in diesel engine utilizing Chlorella vulgaris fuel—a green approach towards sustainable development. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-023-27310-9
Khan TMY, Atabani AE, Badruddin IA, Ahmad Badarudin MS, Khayoon ST (2014) Recent scenario and technologies to utilize non-edible oils for biodiesel production. Renew Sustain Energy Rev 37:840–851. https://doi.org/10.1016/j.rser.2014.05.064
Kumaran M, Sapit A, Razali A et al (2023) Effect of algae biodiesel on ignition delay and heat release of internal combustion engine. fuel, mix form combust process 5:1–6
Ma F, Hanna MA (1999) Biodiesel production: a review1Journal Series #12109, Agricultural Research Division, Institute of Agriculture and Natural Resources, University of Nebraska-Lincoln. 1. Bioresour Technol 70:1–15. https://doi.org/10.1016/S0960-8524(99)00025-5
Mohammed AS, Atnaw SM, Ramaya AV, Alemayehu G (2023) A comprehensive review on the effect of ethers, antioxidants, and cetane improver additives on biodiesel-diesel blend in CI engine performance and emission characteristics. J Energy Inst 108:101227. https://doi.org/10.1016/j.joei.2023.101227
Moshood TD, Nawanir G, Mahmud F (2021) Microalgae biofuels production: a systematic review on socioeconomic prospects of microalgae biofuels and policy implications. Environ Challenges 5:100207. https://doi.org/10.1016/j.envc.2021.100207
Muthukumaran C, Praniesh R, Navamani P, Swathi R, Sharmil G, Kumar NM (2017) Process optimization and kinetic modeling of biodiesel production using non-edible Madhuca indica oil. Fuel 195:217–225. https://doi.org/10.1016/j.fuel.2017.01.060
Naeem MM, Al-Sakkari EG, Boffito DC, Rene ER, Gadalla MA, Ashour FH (2023) Single-stage waste oil conversion into biodiesel via sonication over bio-based bifunctional catalyst: optimization, preliminary techno-economic and environmental analysis. Fuel 341:127587. https://doi.org/10.1016/j.fuel.2023.127587
Nagappan B, Devarajan Y, Kariappan E, Philip SB, Gautam S (2020) Influence of antioxidant additives on performance and emission characteristics of beef tallow biodiesel-fuelled C.I engine. Environ Sci Pollut Res 28:12041–12055
Naraki M, mehdi, Parvasi P, Jokar SM, Iulianelli A, (2023) Experimental and theoretical feasibility study of methanol application for Echium oil-based biodiesel production. Renew Energy 202:1241–1247. https://doi.org/10.1016/j.renene.2022.11.118
Padhi SK, Singh RK (2010) Optimization of esterification and transesterification of mahua (Madhuca Indica) oil for production of biodiesel. J Chem Pharm Res 2:599–608
Pandian AK, Ramakrishnan RBB, Devarajan Y (2017) Emission analysis on the effect of nanoparticles on neat biodiesel in unmodified diesel engine. Environ Sci Pollut Res 24:23273–23278. https://doi.org/10.1007/s11356-017-9973-6
Paramasivam B, Kasimani R, Rajamohan S (2019) Experimental assessment and multi-response optimization of diesel engine performance and emission characteristics fuelled with Aegle marmelos seed cake pyrolysis oil-diesel blends using grey relational analysis coupled principal component analysis. Environ Sci Pollut Res 26:6980–7004. https://doi.org/10.1007/s11356-019-04164-8
Pradhan D, Singh RK, Bendu H, Mund R (2016) Pyrolysis of mahua seed (Madhuca indica) - production of biofuel and its characterization. Energy Convers Manag 108:529–538. https://doi.org/10.1016/j.enconman.2015.11.042
Puhan S, Vedaraman N, Ram BVB, et al (2005) Mahua oil (Madhuca Indica seed oil) methyl ester as biodiesel-preparation and emission characterstics. Biomass and Bioenergy 28:87–93. https://doi.org/10.1016/j.biombioe.2004.06.002
Rahman MM, Pourkhesalian AM, Jahirul MI, Stevanovic S, Pham PX, Wang H, Masri AR, Brown RJ, Ristovski ZD (2014) Particle emissions from biodiesels with different physical properties and chemical composition. Fuel 134:201–208. https://doi.org/10.1016/j.fuel.2014.05.053
Rahman SMA, Masjuki HH, Kalam MA et al (2013) Production of palm and Calophyllum inophyllum based biodiesel and investigation of blend performance and exhaust emission in an unmodified diesel engine at high idling conditions. Energy Convers Manag 76:362–367. https://doi.org/10.1016/J.ENCONMAN.2013.07.061
Rajak U, Nashine P, Verma TN, Pugazhendhi A (2019) Performance, combustion and emission analysis of microalgae Spirulina in a common rail direct injection diesel engine. Fuel 255:115855. https://doi.org/10.1016/j.fuel.2019.115855
Rajak U, Verma TN, Viswanath Allamraju K, Kumar R, Le QH, Pugazhendhi A (2023) Effects of different biofuels and their mixtures with diesel fuel on diesel engine performance and exhausts. Sci Total Environ 903:166501. https://doi.org/10.1016/j.scitotenv.2023.166501
Samuel OD, Okwu MO (2019) Comparison of response surface methodology (RSM) and artificial neural network (ANN) in modelling of waste coconut oil ethyl esters production. Energy Sources, Part A Recover Util Environ Eff 41:1049–1061. https://doi.org/10.1080/15567036.2018.1539138
Saravanan A, Murugan M, Sreenivasa Reddy M, Parida S (2020) Performance and emission characteristics of variable compression ratio CI engine fueled with dual biodiesel blends of Rapeseed and Mahua. Fuel 263:116751. https://doi.org/10.1016/j.fuel.2019.116751
Senthil M, Visagavel K, Saravanan CG, Rajendran K (2016) Investigations of red mud as a catalyst in mahua oil biodiesel production and its engine performance. Fuel Process Technol 149:7–14. https://doi.org/10.1016/j.fuproc.2016.03.027
Singh D, Sharma D, Sharma PK, amit jhalani, Dinesh kumar sharma, et al (2023) Characterization of homogenous acid catalyzed biodiesel production from palm oil: experimental investigation and numerical simulation. Environ Sci Pollut Res 30:34481–34502. https://doi.org/10.1007/s11356-022-24515-2
Singh Rajpoot A, Choudhary T, Chelladurai H et al (2023) Performance analysis of a CI engine powered by different generations of biodiesel; Palm oil, Jatropha, and microalgae. Mater Today Proc. https://doi.org/10.1016/j.matpr.2023.02.037
Tamilvana A, Balamurugan K, Ashok B, Selvakumar P, Dhamotharan S, Bharathiraja M, Karthickeyan V (2021) Effect of diethyl ether and ethanol as an oxygenated additive on Calophyllum inophyllum biodiesel in CI engine. Environ Sci Pollut Res 28:33880–33898. https://doi.org/10.1007/s11356-020-10624-3
Tiwari C, Dwivedi G, Verma TN (2023a) Sustainability evaluation, optimization and research dynamics of microalgae methyl ester in a research diesel engine. https://doi.org/10.1177/09544089231162318
Tiwari C, Verma TN, Dwivedi G, Verma P (2023b) Energy-exergy analysis of diesel engine fueled with microalgae biodiesel-diesel blend. Appl Sci 13. https://doi.org/10.3390/app13031857
Tukaram Bai M, Swarna U, Mahalakshmi ChAI, Raju V, shridevi, (2021) Production of methyl ester from mahua oil: characterization and optimization by using RSM. Mater Today Proc 44:1609–1616. https://doi.org/10.1016/j.matpr.2020.11.815
Author information
Authors and Affiliations
Contributions
All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Lawalesh Kumar Prajapati, Chandrabhushan Tiwari, Gaurav Dwivedi, Tikendra Nath Verma, and Deepak Paliwal. The first draft of the manuscript was written by Lawalesh Kumar Prajapati and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
Lawalesh Kumar Prajapati: writing the first draft, material preparation, data collection, and analysis.
Chandrabhushan Tiwari: methodology, conception, design, and editing manuscript
Tikendra Nath Verma: supervision.
Gaurav Dwivedi: supervision.
Deepak Paliwal: methodology.
Corresponding author
Ethics declarations
Ethics approval and consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Ta Yeong Wu
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Prajapati, L.K., Tiwari, C., Verma, T.N. et al. Production and testing of mahua oil–based biodiesel synthesized through heterogeneous catalyst using experimental and numerical method. Environ Sci Pollut Res (2024). https://doi.org/10.1007/s11356-024-33558-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11356-024-33558-6