Abstract
Ultrafiltration (UF) is widely used in wastewater reclamation treatments. Conventional backwashing is usually performed at regular time intervals (10–120 min) with permeate and without the addition of chemicals. Chemical enhanced backwashing (CEB) is usually applied after 70–90 filtration cycles with added chemicals. These cleaning methods cause membrane fouling and require costly chemicals. Instead of conventional backwashing, we propose herein a new backwashing method involving backwashing the effluent with low doses of sodium hypochlorite (NaClO) named as BELN. The performance and cost of UF backwashing were investigated with Beijing wastewater reclamation treatment. The results showed that the transmembrane pressure (TMP) increased from 33.2 to 48.2 kPa during hydraulic backwashing after 80 filtration cycles but increased from 33.3 to 39.3 kPa during backwashing with a low NaClO content of 20 mg/L. It was also noticed that the hydraulic-irreversible fouling index decreased from 5.58 × 10−3 m2/L to 3.58 × 10−3 m2/L with the new method. According to the three-dimensional fluorescence excitation-emission (3D-EEM), the response increased from 11.9 to 15.2% with BELN. Protein-like material was identified as the main component causing membrane fouling by blocking the membrane pores. The results indicated that the low dosage of NaClO effectively stripped the fouling layer. Finally, based on an economic evaluation, the capacity of the UF process was increased from 76,959 to 109,133 m3/d with the new method. The amount of NaClO consumed for Beijing wastewater reclamation treatment was similarly compared with the conventional backwashing in per year under BELN. The new method has good potential for application.
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References
Al Aani S, Mustafa TN, Hilal N (2020) Ultrafiltration membranes for wastewater and water process engineering: a comprehensive statistical review over the past decade. J Water Process Eng 35:101241
Bailey ES, Casanova LM, Simmons OD, Sobsey MD (2018) Tertiary treatment and dual disinfection to improve microbial quality of reclaimed water for potable and non-potable reuse: a case study of facilities in North Carolina. Sci Total Environ 630:379–388
Cai W, Liu J, Zhang X, Ng WJ, Liu Y (2016) Generation of dissolved organic matter and byproducts from activated sludge during contact with sodium hypochlorite and its implications to on-line chemical cleaning in MBR. Water Res 104:44–52
Chang H, Liang H, Qu F, Shao S, Yu H, Liu B, Gao W, Li G (2016) Role of backwash water composition in alleviating ultrafiltration membrane fouling by sodium alginate and the effectiveness of salt backwashing. J Membr Sci 499:429–441
Chen W, Westerhoff P, Leenheer JA, Booksh K (2003) Fluorescence excitation−emission matrix regional integration to quantify spectra for dissolved organic matter. Environ Sci Technol 37:5701–5710
Cordier C, Eljaddi T, Ibouroihim N, Stavrakakis C, Sauvade P, Coelho F, Moulin P (2020) Optimization of air backwash frequency during the ultrafiltration of seawater. Membranes 10:78
Gao WJ, Qu X, Leung KT, Liao BQ (2012) Influence of temperature and temperature shock on sludge properties, cake layer structure, and membrane fouling in a submerged anaerobic membrane bioreactor. J Membr Sci 421-422:131–144
Lee N, Amy G, Croué J-P, Buisson H (2004) Identification and understanding of fouling in low-pressure membrane (MF/UF) filtration by natural organic matter (NOM). Water Res 38:4511–4523
Li S, Dao G-H, Tao Y, Zhou J, Jiang H-S, Xue Y-M, Yu W-W, Yong X-L, Hu H-Y (2020) The growth suppression effects of UV-C irradiation on Microcystis aeruginosa and Chlorella vulgaris under solo-culture and co-culture conditions in reclaimed water. Sci Total Environ 713:136374
Lin H, Peng W, Zhang M, Chen J, Hong H, Zhang Y (2013) A review on anaerobic membrane bioreactors: applications, membrane fouling and future perspectives. Desalination 314:169–188
Lin H, Zhang M, Wang F, Meng F, Liao B-Q, Hong H, Chen J, Gao W (2014) A critical review of extracellular polymeric substances (EPSs) in membrane bioreactors: characteristics, roles in membrane fouling and control strategies. J Membr Sci 460:110–125
Lipp P (2008) State of the art in drinking water treatment by MF/UF in Germany - a survey among MF/UF plants. Water Sci Technol: Water Supply 8(4):377–381
Long Y, You X, Chen Y, Hong H, Liao B-Q, Lin H (2020) Filtration behaviors and fouling mechanisms of ultrafiltration process with polyacrylamide flocculation for water treatment. Sci Total Environ 703:135540
Mahirullah M, Widiasa IN (2021) Study on ultrafiltration of hospital wastewater treatment effluent. IOP Conf Ser Mater Sci Eng 1053:012120
Nguyen AH, Tobiason JE, Howe KJ (2011) Fouling indices for low pressure hollow fiber membrane performance assessment. Water Res 45:2627–2637
Qu F, Yang Z, Li X, Yu H, Pan Z, Fan G, He J, Rong H (2021) Membrane fouling control by UV/persulfate in tertiary wastewater treatment with ultrafiltration: a comparison with UV/hydroperoxide and role of free radicals. Sep Purif Technol 257:117877
Sun W, Nan J, Xing J, Tian J (2016) Influence and mechanism of different molecular weight organic molecules in natural water on ultrafiltration membrane fouling reversibility. RSC Adv 6:83456–83465
Tong X, Zhang Z-W, Wu Y-H, Bai Y, Ikuno N, Ishii K, Hu H-Y (2022) Ultrafiltration significantly increased the scaling potential of municipal secondary effluent on reverse osmosis membranes. Water Res 220:118672
Verstraete W, Van de Caveye P, Diamantis V (2009) Maximum use of resources present in domestic “used water”. Bioresour Technol 100:5537–5545
Wang Z, Wu Z, Yin X, Tian L (2008) Membrane fouling in a submerged membrane bioreactor (MBR) under sub-critical flux operation: membrane foulant and gel layer characterization. J Membr Sci 325:238–244
Xiao P, Xiao F, Wang D-s, Qin T, He S-p (2012) Investigation of organic foulants behavior on hollow-fiber UF membranes in a drinking water treatment plant. Sep Purif Technol 95:109–117
Ye Y, Chen V, Le-Clech P (2011) Evolution of fouling deposition and removal on hollow fibre membrane during filtration with periodical backwash. Desalination 283:198–205
Yigit NO, Civelekoglu G, Harman I, Koseoglu H, Kitis M (2009) Effects of various backwash scenarios on membrane fouling in a membrane bioreactor. Desalination 237:346–356
Yu T, Meng L, Zhao Q-B, Shi Y, Hu H-Y, Lu Y (2017) Effects of chemical cleaning on RO membrane inorganic, organic and microbial foulant removal in a full-scale plant for municipal wastewater reclamation. Water Res 113:1–10
Zheng X, Khan MT, Croué J-P (2014) Contribution of effluent organic matter (EfOM) to ultrafiltration (UF) membrane fouling: Isolation, characterization, and fouling effect of EfOM fractions. Water Res 65:414–424
Zheng Y, Zhang W, Tang B, Ding J, Zheng Y, Zhang Z (2018) Membrane fouling mechanism of biofilm-membrane bioreactor (BF-MBR): pore blocking model and membrane cleaning. Bioresour Technol 250:398–405
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This study received financial support from the National Natural Science Foundation of China (Grant No. 52030003) and Beijing Engineering Research Center for Wastewater Reuse research and development fund (BPJ201907-2022).
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Lian Yang: design of the work; Haoran Qiu, Chunrui Zhang, Congcong Wu, Zixin Lu, Shuoxun Dong, and Guoliang Liu: the acquisition, analysis; Jiang Chang: interpretation of data; Feng Xiao: the creation of new software used in the work; Shaoxia Yang: drafted the work or substantively revised it.
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Yang, L., Qiu, H., Lu, Z. et al. Identification of performance and cost in a new backwash method to clean the UF membrane: backwashing with low dosage of NaClO. Environ Sci Pollut Res 30, 121983–121992 (2023). https://doi.org/10.1007/s11356-023-31008-3
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DOI: https://doi.org/10.1007/s11356-023-31008-3