Abstract
Zinc oxide has been of interest because of its efficient redox capacity in the UV spectral region. However, the high bandwidth limits its application in the visible region. Although synthesizing heterojunctions and doping with other elements have become the focus of the problem, it inevitably has an impact on the environment. In contrast, the template method is not only environmentally friendly but also can be used to increase the degradation rate by changing the nanoparticle mesoporous structure. Microporous/mesoporous zinc oxide with multi-level structure was synthesized using anhydrous ethanol as a green templating agent in a mild and energy-efficient method. The prepared nZnO was characterized using XRD, SEM, BET, and HR-TEM. XRD confirmed that the formation of hexagonal wurtzite zincite nZnO with good crystallinity. SEM results showed that the products were flower-like structures composed of nanosheets with a thickness of 20 nm and an average diameter of 400 nm. TEM and BET confirmed the presence of pits with diameters ranging from about 1 nm to 20 nm existed on the surface of the nanosheets, while the specific surface area of 28.05 m2/g and the pore volume of 0.069 cm3/g also provide advantages for nZnO as a photocatalytic material. The synthesized nZnO overcame the disadvantage of responding only in the UV region, and the photocatalytic degradation efficiency of MB reached 93.2% after 60 min of xenon lamp irradiation, and stabilized at 86.15% after five photocycling tests. Compared with other kinds of templates, anhydrous ethanol has the advantages of environmental friendliness and simple post-processing, and it also provides ideas for the synthesis of multilevel structures of other nanomaterials.
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11 November 2023
A Correction to this paper has been published: https://doi.org/10.1007/s11356-023-31013-6
References
Amiri M, Eskandari K, Salavati-Niasari M (2019) Magnetically retrievable ferrite nanoparticles in the catalysis application. Adv Colloid Interf Sci 271:101982. https://doi.org/10.1016/j.cis.2019.07.003
Amiri M, Salavati-Niasari M, Akbari A et al (2017) Removal of malachite green (a toxic dye) from water by cobalt ferrite silica magnetic nanocomposite: herbal and green sol-gel autocombustion synthesis. Int J Hydrog Energy 42(39):24846–24860. https://doi.org/10.1016/j.ijhydene.2017.08.077
Arsalani N, Bazazi S, Abuali M, Jodeyri S (2019) A new method for preparing ZnO/CNT nanocomposites with enhanced photocatalytic degradation of malachite green under visible light. J Photochem 389:112207. https://doi.org/10.1016/j.jphotochem.2019.112207
Atay F, Gultepe O (2022) Structural, optical and surface properties of sol–gel-derived boron-doped ZnO films for photocatalytic applications. Appl Phys A 128:1–13. https://doi.org/10.1007/s00339-022-05261-1
Balcha A, Yadav OP, Dey T (2016) Photocatalytic degradation of methylene blue dye by zinc oxide nanoparticles obtained from precipitation and sol-gel methods. Environ Sci Pollut Res 23:25485–25493. https://doi.org/10.1007/s11356-016-7750-6
Budhiraja N, Sapna S, Kumar V, Tomar M, Gupta V, Singh SK (2018) Structural, optical and photocatalytic properties of ZnO nanostructures. AIP Conf Proc 2006(1). https://doi.org/10.1063/1.5051302
Castro FD, Bassin JP, Dezotti M (2017) Treatment of a simulated textile wastewater containing the Reactive Orange 16 azo dye by a combination of ozonation and moving-bed biofilm reactor: evaluating the performance, toxicity, and oxidation by-products. Environ Sci Pollut Res Int 24:6307–6316. https://doi.org/10.1007/s11356-016-7119-x
Chauhan A, Shrivastav AK, Oudhia A (2022) The impact of excessive ethanol on synthesis and characterization of zinc oxide nanoparticles. J Cryst Growth 591:126718. https://doi.org/10.1016/j.jcrysgro.2022.126718
Chen Q, Liu C, Ji X, Liu C, Zhao Y, Fang Z (2019) Menthanol templated synthesis of ordered lamellar superstructured zirconia and its outstanding hierarchical thermostabilities. Ceram Int 45:13587–13591. https://doi.org/10.1016/j.ceramint.2019.04.016
Chen Y, Bagnall DM, Koh H-J, Park K-T, Hiraga K, Zhu Z-Q, Yao T (1998) 912 Plasma assisted molecular beam epitaxy of ZnO on c-plane sapphire: growth and 913 characterization. J Appl Phys 84(7):3912–3918
Chong MN, Lei S, Jin B et al (2009) Optimisation of an annular photoreactor process for degradation of Congo Red using a newly synthesized titania impregnated kaolinite nano-photocatalyst. Sep Purif Technol 67(3):355–363. https://doi.org/10.1016/j.seppur.2009.04.001
Divriklioglu M, Akar ST, Akar T (2019) A passively immobilized novel biomagsorbent for the effective biosorptive treatment of dye contamination. Environ Sci Pollut Res Int 26:25834–25843. https://doi.org/10.1007/s11356-019-05716-8
Gomez-Solís C, Ballesteros JC, Torres-Martínez LM et al (2015) Rapid synthesis of ZnO nano-corncobs from Nital solution and its application in the photodegradation of methyl orange. J Photochem Photobiol A 298:49–54. https://doi.org/10.1016/j.jphotochem.2014.10.012
Guo M, Hu Y, Wang R, Yu H, Sun L (2021) Molecularly imprinted polymer-based photocatalyst for highly selective degradation of methylene blue. Environ Res 194:110684. https://doi.org/10.1016/j.envres.2020.110684
He W, Liu Y, Ye J, Wang G (2018) Electrochemical degradation of azo dye methyl orange by anodic oxidation on Ti4O7 electrodes. J Mater Sci Mater Electron 29:14065–14072. https://doi.org/10.1007/s10854-018-9538-6
Huong VH, Nguyen TC, Sai CD et al (2023) Facile synthesis of ZnO/Ag nanostructure with enhanced photocatalytic activity. ChemNanoMat 9(6):e202300080. https://doi.org/10.1002/cnma.202300080
Janotti A, Van de Walle CG (2009) Fundamentals of zinc oxide as a semiconductor. Rep Prog Phys 72(12):126501. https://doi.org/10.1088/0034-4885/72/12/126501
Ji X, Li Q, Liu C et al (2019) A novel surface patterning nanorod: hydroxyapatite nano labyrinth, promoted, induced and stabilized by tetrahydrofuran. Micropor Mesopor Mat 294:109904. https://doi.org/10.1016/j.micromeso.2019.109904
Ji X, Su P, Liu C et al (2015) A novel ethanol induced and stabilized hierarchical nanorods: hydroxyapatite nanopeanut. J Am Ceram Soc 98:1702–1705. https://doi.org/10.1111/jace.13590
Kang S-Z, Wu T, Li X, Mu J (2010) A facile gelatin-assisted preparation and photocatalytic activity of zinc oxide nanosheets. Colloids Surf A: Physicochem and Eng Aspects 369:268–271. https://doi.org/10.1016/j.colsurfa.2010.08.029
Khanna A, Shetty VK (2014) Solar light induced photocatalytic degradation of Reactive Blue 220 (RB-220) dye with highly efficient Ag@TiO2 core–shell nanoparticles: a comparison with UV photocatalysis. Sol Energy 99:67–76. https://doi.org/10.1016/j.solener.2013.10.032
Kozliak EI, Paca J (2012) Journal of Environmental Science and Health, Part A. Toxic/hazardous substances and environmental engineering Foreword. J Environ Sci Health A, Toxic/Hazard Subst Environ Eng 47(7):919–919. https://doi.org/10.1080/10934529.2012.667287
Mehmetd, Mahir A,Aydm T,et al. (2004). Kinetics and mechanism of removal of methylene blue by adsorption onto perlite. J Hazard Mater, (B109): 141-148. https://doi.org/10.1016/j.jhazmat.2004.03.003
Mir N, Salavati-Niasari M (2013) Preparation of TiO2 nanoparticles by using tripodal tetraamine ligands as complexing agent via two-step sol–gel method and their application in dye-sensitized solar cells. Mater Res Bull 48(4):1660–1667. https://doi.org/10.1016/j.materresbull.2013.01.006
Panahi A, Monsef R, Elmuez A et al (2023) Green auto-combustion synthesis and characterization of TmVO4 nanostructures in the presence carbohydrate sugars and their application as visible-light photocatalyst. Sol Energy 258:372–382. https://doi.org/10.1016/j.solener.2023.04.030
Reynolds DC, Look DC, Jogai B, Litton CW, Cantwell G, Harsch WC (1999) Valence-band ordering in ZnO. Phys Rev B 60(4):2340–2344. https://doi.org/10.1103/PhysRevB.60.2340
Sakthivel S, Neppolian B, Shankar MV et al (2003) Solar photocatalytic degradation of azo dye: comparison of photocatalytic efficiency of ZnO and TiO2. Sol Energy Mater Sol Cells 77(1):65–82. https://doi.org/10.1016/S0927-0248(02)00255-6
Sangashekan M, Asan S, Gilani HG (2019) Investigation of eosin B removal from aqueous solution employing combined graphene oxide adsorption and zinc oxide coagulation processes. Fibers Polym 20:1411–1417. https://doi.org/10.1007/s12221-019-8542-7
Shukla AK, Alam J, Rahaman M, Alrehaili A, Alhoshan M, Aldalbahi A (2020) A facile approach for elimination of electroneutral/anionic organic dyes from water using a developed carbon-based polymer nanocomposite membrane. Water Air Soil Poll 231:1–16. https://doi.org/10.1007/s11270-020-04483-4
Sun JH, Dong SY, Feng JL et al (2011) Enhanced sunlight photocatalytic performance of Sn-doped ZnO for Methylene Blue degradation. J Mol Catal A Chem 335(1-2):145–150. https://doi.org/10.1016/j.molcata.2010.11.026
Teymourinia H, Salavati-Niasari M, Amiri O et al (2017) Synthesis of graphene quantum dots from corn powder and their application in reduce charge recombination and increase free charge carriers. J Mol Liq 242:447–455. https://doi.org/10.1016/j.molliq.2017.07.052
Vijay K, Kr L, Veerla SC et al (2020) Synergetic antibacterial potential, dye degrading capability and biocompatibility of Asperagus racemosus root assisted ZnO Nanoparticles. Mater Today Commun 2020:101574. https://doi.org/10.1016/j.mtcomm.2020.101574
Wang X, Yu JC, Ho C et al (2005) Photocatalytic activity of a hierarchically macro/mesoporous titania. Langmuir 21(6):2552–2559. https://doi.org/10.1021/la047979c
Zheng M, Wu J (2009) One-step synthesis of nitrogen-doped ZnO nanocrystallites and their properties. Appl Surf Sci 255:5656–5661. https://doi.org/10.1016/j.apsusc.2008.10.091
Zinatloo-Ajabshir S, Baladi M, Salavati-Niasari M (2021) Enhanced visible-light-driven photocatalytic performance for degradation of organic contaminants using PbWO4 nanostructure fabricated by a new, simple and green sonochemical approach. Ultrason Sonochem 72:105420. https://doi.org/10.1016/j.ultsonch.2020.105420
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All authors contributed to the study conception and design. Ideas and methodology were performed by Yucong Zhang and Xiujie Ji. Material preparation and data collection were completed by Linxin Feng, Binbin Qin, and Yangchen Wu. Data visualization was performed by Lijie Ma. Validation was completed by Xuebo Luo. Supervision and writing-review were performed by Xiujie Ji and Chao Liu. The first draft of the manuscript was written by Yucong Zhang, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Zhang, Y., Luo, X., Ma, L. et al. Ethanol templated synthesis of microporous/mesoporous nanozinc oxide with multi-level structure and its outstanding photo-catalytic properties. Environ Sci Pollut Res 30, 115517–115526 (2023). https://doi.org/10.1007/s11356-023-30523-7
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DOI: https://doi.org/10.1007/s11356-023-30523-7