Skip to main content
Log in

A new treatment step of bioelectrochemically treated leachate using natural clay adsorption towards sustainable leachate treatment

  • Research Article
  • Published:
Environmental Science and Pollution Research Aims and scope Submit manuscript

Abstract

Standalone and combined leachate treatment mechanisms suffer from low treatment efficiencies due to leachate’s complex, toxic, and recalcitrant nature. Bioelectrochemical system (BES) was used for the first time to investigate the treatment of leachate mixed wastewater (WW) (i.e., diluted leachate, DL) (DL ≈ L:WW = 1:4) to minimize these complexities. A natural clay (palygorskite) was used as adsorbent material for further treatment on the BES effluent (EBES) while using two different masses and sizes (i.e., 3 g and 6 g of raw crushed clay (RCC) and 75 μ of sieved clay (75 μSC)). According to bioelectrochemical performance, BES, when operated with low external resistance (Rext = 1 Ω) (BES 1), showed a high removal of COD and NH3-N with 28% and 36%, respectively. On the other hand, a high Rext (100 Ω, BES 100) resulted in low removal of NH3-N with 10% but revealed high COD removal by 78.26%. Moreover, the 6 g doses of 75 μSC and RCC showed the maximum COD removals of 62% and 38% and showed the maximum removal of NH3-N with an average range of 40% for both sizes. After efficient desorption, both clay sizes resulted in regeneration performance which was observed with high COD (75%) and NH3-N (34%) on EBES. Therefore, when BES and clay adsorption technique sequentially treated and achieved with combined removal of ~ 98% for COD and ~ 80% of NH3-N, it demonstrated an efficient treatment method for DL treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Data availability

The reported data can be made available upon request to the corresponding author Dr. Abdullah Al-Mamun.

Abbreviations

75SC:

75-μ sieved clay

AE:

Adsorption efficiency

APHA:

American Public Health Association

BDL:

Below detection limits

BES:

Bioelectrochemical system

BES 1:

Bioelectrochemical system operated with 1-Ω resistance

BES 100:

Bioelectrochemical system operated with 100-Ω resistance

BOD:

Biochemical oxygen demand

C/N:

Carbon/nitrogen

COD:

Chemical oxygen demand

DE:

Desorption efficiency

DL:

Diluted leachate

EBES:

Effluent bioelectrochemical system

EC:

Electrical conductivity

WWTP:

Wastewater treatment plant

IC:

Inorganic carbon

MFC:

Microbial fuel cell

MLL:

Multaqa landfill leachate

NH3-N:

Ammonia-nitrogen

pH:

Hydrogen ion concentration

RCC:

Raw crushed clay of 200-μ particle size

RE:

Regeneration efficiency

Rext :

External resistance

Rint :

Internal resistance

TC:

Total carbon

TDS:

Total dissolved solids

TFS:

Total fixed solids

TOC:

Total organic carbon

TS:

Total solids

TVS:

Total volatile solids

WW:

Municipal wastewater

References

Download references

Acknowledgements

The authors wish to extend their appreciation to Sultan Qaboos University (SQU), Muscat, Oman, for the financial support through Project Fund (CR/ENG/CAED/19/01). We extend our sincere gratitude to SQU for the technical, logistic, and scholarship support for the Ph.D. student. The authors would like to express their appreciation to Arch. Fakehatul Jannat Khan for preparing 3D visualization of the reactor.

Author information

Authors and Affiliations

Authors

Contributions

Dr. Sajjad Ahmad Siddiqi is recently serving as a consultant specialist in the global enviroquest LLC. He has developed the main concept and studied the current literature to prepare the manuscript during his studies. Sadik Rahman is a graduate student. He analyzed the data the presented data and research work to be accomplished. Dr. Abdullah Al-Mamun is the supervisor. He assisted in developing the concept, comments on the critical phase of data analysis was analyzed and made improvements in the manuscript. Dr. Jagdeep Kumar Nayak has also made critical improvements to the manuscript. Dr. Ahmad Sana is the co-supervisor and committee member; he has helped in revising the manuscript. Prof. Mahad Said Baawain has analyzed several critical points of the study and revised the manuscript.

Corresponding author

Correspondence to Abdullah Al-Mamun.

Ethics declarations

Ethical approval and consent to participate

Not applicable.

Consent for publication

Not applicable.

Competing interests

The authors declare no competing interests.

Additional information

Responsible Editor: Guilherme Luiz Dotto

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Siddiqi, S.A., Rahman, S., Al-Mamun, A. et al. A new treatment step of bioelectrochemically treated leachate using natural clay adsorption towards sustainable leachate treatment. Environ Sci Pollut Res 30, 111903–111915 (2023). https://doi.org/10.1007/s11356-023-28997-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11356-023-28997-6

Keywords

Navigation