Abstract
One green adsorbent, UiO-66-NH2 modified peanut shell (c-PS-MOF), was prepared in a green synthetic route for improving the capture level of aspirin (ASP) and fluoride ion (F–). The adsorption properties of c-PS-MOF were evaluated by batch experiments and its physicochemical properties were explored by various characterization methods. The results showed that c-PS-MOF exhibited a wide range of pH applications (ASP: 2–10; F–: 3–12) and high salt resistance in the capturing processes of ASP and F–. The unit adsorption capacity of c-PS-MOF was as high as 84.7 mg·g–1 for ASP as pH = 3 and 11.2 mg·g–1 for F– under pH = 6 at 303 K from Langmuir model, respectively. When the solid–liquid ratio was 2 g·L–1, the content of ASP (C0 = 100 mg·L–1) and F– (C0 = 20 mg·L–1) in solution can be reduced to 0.48 mg·L–1 and 1.05 mg·L–1 separately. The recycling of c-PS-MOF can be realized with 5 mmol·L–1 NaOH as eluent. Analysis of simulated water samples showed that c-PS-MOF could be used to remove ASP and F– from actual water. The c-PS-MOF is promising to bind ASP and F– from rivers, lakes, etc.
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The research was supported by the National Key Research and Development Program of China (2018YFD0401402–04), Zhongyuan Scholars Foundation (202101510005), and National Natural Science Foundation of China (42077389).
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Xiaoting Zhang: conceptualization, preparation, methodology, data curation, and writing—original draft. Xiaoyu Han: software and drawing. Yang Liu: software and investigation. Runping Han: methodology, data curation, writing—review and editing, and funding acquisition. Rong Wang: writing—review and editing and funding acquisition. Lingbo Qu: writing—review and editing.
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Zhang, X., Han, X., Liu, Y. et al. Remediation of water tainted with noxious aspirin and fluoride ion using UiO-66-NH2 loaded peanut shell. Environ Sci Pollut Res 30, 93877–93891 (2023). https://doi.org/10.1007/s11356-023-28906-x
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DOI: https://doi.org/10.1007/s11356-023-28906-x