Abstract
1,10-Phenanthroline (PHN) is a nitrogen-containing heterocyclic organic compound that is widely used in a variety of applications, including chemosensors, biological studies, and pharmaceuticals, which promotes its use as an organic inhibitor to reduce corrosion of steel in acidic solution. In this regard, the inhibition ability of PHN was examined for carbon steel (C48) in a 1.0 M HCl environment by performing electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP), mass loss, and thermometric/kinetic. Additionally, scanning electron microscopy (SEM) was used to examine the surface morphology of C48 immersed in 1.0 M HCl protected with our inhibitor. According to the PDP tests, increasing the PHN concentration resulted in an improvement in corrosion inhibition efficiency. Besides, the maximum corrosion inhibition efficiency is about 90% at 328 K. Furthermore, the PDP assessments demonstrated that PHN functions as a mixed-type inhibitor. The adsorption analysis reveals that our title molecule mechanism is due to physical–chemical adsorption, as predicted by the Frumkin, Temkin, Freundlich, and Langmuir isotherms. The SEM technique exhibited that the corrosion barrier occurs due to the adsorption of the PHN compound through the metal/1.0 M HCl interface. In addition, the computational investigations based on a quantum calculation using density functional theory (DFT), reactivity (QTAIM, ELF, and LOL), and molecular-scale by Monte Carlo (MC) simulations confirmed the experimental results by providing further insight into the mode of adsorption of PHN on the metal surface, thus forming a protective film against corrosion on the C48 surface.
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Data availability
The datasets used and/or analyzed during the present study are available from the corresponding author on reasonable request.
References
Abdelshafi NS, Ibrahim MA, Badran AS, Halim SA (2022) Experimental and theoretical evaluation of a newly synthesized quinoline derivative as corrosion inhibitor for iron in 1.0 M hydrochloric acid solution. J Mol Struct 1250. https://doi.org/10.1016/j.molstruc.2021.131750
Akinbulumo OA, Odejobi OJ, Odekanle EL (2020) Thermodynamics and adsorption study of the corrosion inhibition of mild steel by Euphorbia heterophylla L. extract in 1.5 M HCl. Results Mater 5(October 2019):100074. https://doi.org/10.1016/j.rinma.2020.100074
Al Lawati HAJ, Al Dahmani ZM, Suliman FEO, Al Kindy SMZ, Al-Lawati AM (2011) Analysis of fexofenadine in pharmaceutical formulations using tris(1,10-phenanthroline)-ruthenium(II) peroxydisulphate chemiluminescence system in a multichip device. Luminescence 26(6):762–767. https://doi.org/10.1002/bio.1310
Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M (2018) Glycyrrhiza glabra leaves extract as a green corrosion inhibitor for mild steel in 1 M hydrochloric acid solution: experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J Mol Liq 255:185–198. https://doi.org/10.1016/j.molliq.2018.01.144
Anandan K, Kolandaivel P, Kumaresan R (2004) Ab initio and DFT studies on tautomerism of indazole in gaseous and aqueous phases. J Mol Struct (thoechem) 686(1–3):83–89. https://doi.org/10.1016/j.theochem.2004.08.014
Arulraj R, Sivakumar S, Suresh S, Anitha K (2020) Synthesis, vibrational spectra, DFT calculations, Hirshfeld surface analysis and molecular docking study of 3-chloro-3-methyl-2,6-diphenylpiperidin-4-one. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 232:118166. https://doi.org/10.1016/j.saa.2020.118166
Asadi N, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B (2019) Utilizing Lemon Balm extract as an effective green corrosion inhibitor for mild steel in 1M HCl solution: a detailed experimental, molecular dynamics, Monte Carlo and quantum mechanics study. J Taiwan Inst Chem Eng 95:252–272. https://doi.org/10.1016/j.jtice.2018.07.011
Belghiti ME, Bouazama S, Echihi S, Mahsoune A, Elmelouky A, Dafali A, Emran KM, Hammouti B, Tabyaoui M (2020) Understanding the adsorption of newly benzylidene-aniline derivatives as a corrosion inhibitor for carbon steel in hydrochloric acid solution: experimental, DFT and molecular dynamic simulation studies. Arab J Chem 13(1):1499–1519. https://doi.org/10.1016/j.arabjc.2017.12.003
Benzbiria N, Echihi S, Belghiti ME, Thoume A, Elmakssoudi A, Zarrouk A, Zertoubi M, Azzi M (2020) Novel synthetized benzodiazepine as efficient corrosion inhibitor for copper in 3.5% NaCl solution. Mater Today: Proceedings 37:3932–3939. https://doi.org/10.1016/j.matpr.2020.09.030
Chafi M, Byadi S, Barhoumi A, Limouni W, Tizliouine A, Jama C, El Hachemi Omari L (2022) Study of copper removal by modified biomaterials using the response surface methodology, DFT Calculation, and molecular dynamic simulation. J Mol Liq 363:119799. https://doi.org/10.1016/j.molliq.2022.119799
Chafiq M, Chaouiki A, Albayati MR, Lgaz H, Salghi R, AbdelRaheem SK, Ali IH, Mohamed SK, Chung IM (2020) Unveiled understanding on corrosion inhibition mechanisms of hydrazone derivatives based on naproxen for mild steel in HCl: a joint experimental/theoretical study. J Mol Liq 320. https://doi.org/10.1016/j.molliq.2020.114442
Chaouiki A, Chafiq M, Rbaa M, Salghi R, Lakhrissi B, Ali IH, Bashir S, Chung IM (2020) Comprehensive assessment of corrosion inhibition mechanisms of novel benzimidazole compounds for mild steel in HCl: an experimental and theoretical investigation. J Mol Liq 320. https://doi.org/10.1016/j.molliq.2020.114383
Chen L, Lu D, Zhang Y (2022) Organic compounds as corrosion inhibitors for carbon steel in HCl solution: a comprehensive review. Materials 15(6):1–59. https://doi.org/10.3390/ma15062023
Cherrak K, El Massaoudi M, Outada H, Taleb M, Lgaz H, Zarrouk A, Radi S, Dafali A (2021) Electrochemical and theoretical performance of new synthetized pyrazole derivatives as promising corrosion inhibitors for mild steel in acid environment: molecular structure effect on efficiency. J Mol Liq 342:117507. https://doi.org/10.1016/j.molliq.2021.117507
Chkirate K, Azgaou K, Elmsellem H, El Ibrahimi B, Sebbar NK, Anouar EH, Benmessaoud M, El Hajjaji S, Essassi EM (2021) Corrosion inhibition potential of 2-[(5-methylpyrazol-3-yl)methyl]benzimidazole against carbon steel corrosion in 1 M HCl solution: combining experimental and theoretical studies. J Mol Liq, 321(December 2020). https://doi.org/10.1016/j.molliq.2020.114750
Chraka A, Raissouni I, Ben Seddik N, Khayar S, El Amrani S, El Hadri M, Chaouket F, Bouchta D (2020a) Croweacin and Ammi visnaga (L.) lam essential oil derivatives as green corrosion inhibitors for brass in 3% NaCl medium: quantum mechanics investigation and molecular dynamics simulation approaches. Mediterr J Chem 10(4):378. https://doi.org/10.13171/mjc10402004281338ac
Chraka A, Raissouni I, Seddik Ben N, Khayar S, Mansour AI, Tazi S, Chaouket F, Bouchta D (2020b) Identification of potential green inhibitors extracted from Thymbra capitata (L.) Cav. for the corrosion of brass in 3% NaCl solution: experimental, SEM–EDX analysis, DFT computation and Monte Carlo simulation studies. J Bio- and Tribo-Corrosion, 6(3). https://doi.org/10.1007/s40735-020-00377-4
Chugh B, Singh AK, Chaouiki A, Salghi R, Thakur S, Pani B (2020) A comprehensive study about anti-corrosion behaviour of pyrazine carbohydrazide: gravimetric, electrochemical, surface and theoretical study. J Mol Liq 299:112160. https://doi.org/10.1016/j.molliq.2019.112160
Damej M, Benmessaoud M, Zehra S, Kaya S, Lgaz H, Molhi A, Labjar N, El Hajjaji S, Alrashdi AA, Lee HS (2021a) Experimental and theoretical explorations of S-alkylated mercaptobenzimidazole derivatives for use as corrosion inhibitors for carbon steel in HCl. J Mol Liq 331:115708. https://doi.org/10.1016/j.molliq.2021.115708
Damej M, Kaya S, EL Ibrahimi B, Lee HS, Molhi A, Serdaroğlu G, Benmessaoud M, Ali IH, EL Hajjaji S, Lgaz H (2021b) The corrosion inhibition and adsorption behavior of mercaptobenzimidazole and bis-mercaptobenzimidazole on carbon steel in 1.0 M HCl: experimental and computational insights. Surf Interfaces, 24(December 2020). https://doi.org/10.1016/j.surfin.2021.101095
Dehghani A, Bahlakeh G, Ramezanzadeh B (2019) A detailed electrochemical/theoretical exploration of the aqueous Chinese gooseberry fruit shell extract as a green and cheap corrosion inhibitor for mild steel in acidic solution. In Journal of Molecular Liquids. Elsevier B.V. Vol. 282. https://doi.org/10.1016/j.molliq.2019.03.011
Djenane M, Chafaa S, Chafai N, Kerkour R, Hellal A (2019) Synthesis, spectral properties and corrosion inhibition efficiency of new ethyl hydrogen [(methoxyphenyl) (methylamino) methyl] phosphonate derivatives: experimental and theoretical investigation. J Mol Struct 1175:398–413. https://doi.org/10.1016/j.molstruc.2018.07.087
Dutta A, Saha SK, Adhikari U, Banerjee P, Sukul D (2017) Effect of substitution on corrosion inhibition properties of 2-(substituted phenyl) benzimidazole derivatives on mild steel in 1 M HCl solution: a combined experimental and theoretical approach. Corros Sci 123(April):256–266. https://doi.org/10.1016/j.corsci.2017.04.017
Echihi S, Hsissou R, Benzbiria N, Afrokh M, Boudalia M, Bellaouchou A, Guenbour A, Azzi M, Tabyaoui M (2021) Performance of methanolic extract of artemisia herba alba as a potential green inhibitor on corrosion behavior of mild steel in hydrochloric acid solution. Biointerface Res Appl Chem 11(6):14751–14763. https://doi.org/10.33263/BRIAC116.1475114763
El Foulani AA, Hammoudan I, Byoud F, Jamal-eddine J, Lekhlif B (2022) Synthesis, characterization, and evaluation of new composites coagulants polyaluminum chloride-sodium alginate. Water Air Soil Pollut 233(8):1–12. https://doi.org/10.1007/s11270-022-05786-4
El-Hajjaji F, Messali M, Aljuhani A, Aouad MR, Hammouti B, Belghiti ME, Chauhan DS, Quraishi MA (2018) Pyridazinium-based ionic liquids as novel and green corrosion inhibitors of carbon steel in acid medium: electrochemical and molecular dynamics simulation studies. J Mol Liq 249:997–1008. https://doi.org/10.1016/j.molliq.2017.11.111
Erdoğan Ş, Safi ZS, Kaya S, Işın DÖ, Guo L, Kaya C (2017) A computational study on corrosion inhibition performances of novel quinoline derivatives against the corrosion of iron. J Mol Struct 1134:751–761. https://doi.org/10.1016/j.molstruc.2017.01.037
Fernine Y, Ech-chihbi E, Arrousse N, El Hajjaji F, Bousraf F, Ebn Touhami M, Rais Z, Taleb M (2021) Ocimum basilicium seeds extract as an environmentally friendly antioxidant and corrosion inhibitor for aluminium alloy 2024–T3 corrosion in 3 wt% NaCl medium. Colloids SurfA: Physicochem Eng Aspects 627(July):127232. https://doi.org/10.1016/j.colsurfa.2021.127232
Flores-Holguín N, Frau J, Glossman-Mitnik D (2020) A fast and simple evaluation of the chemical reactivity properties of the Pristinamycin family of antimicrobial peptides. Chem Phys Lett 739:137021. https://doi.org/10.1016/j.cplett.2019.137021
Frau J, Muñoz F, Glossma-Mitnik D (2016) A molecular electron density theory study of the chemical reactivity of cis- and trans-resveratrol. Molecules 21(12):1–13. https://doi.org/10.3390/molecules21121650
Galai M, Rbaa M, Ouakki M, Abousalem AS, Ech-chihbi E, Dahmani K, Dkhireche N, Lakhrissi B, EbnTouhami M (2020) Chemically functionalized of 8-hydroxyquinoline derivatives as efficient corrosion inhibition for steel in 1.0 M HCl solution: experimental and theoretical studies. Surf Interfaces 21(September):100695. https://doi.org/10.1016/j.surfin.2020.100695
Galai M, Rbaa M, Ouakki M, Guo L, Dahmani K, Nouneh K, Briche S, Lakhrissi B, Dkhireche N, Ebn Touhami M (2021) Effect of alkyl group position on adsorption behavior and corrosion inhibition of new naphthol based on 8-hydroxyquinoline: electrochemical, surface, quantum calculations and dynamic simulations. J Mol Liq 335:116552. https://doi.org/10.1016/j.molliq.2021.116552
Hafez B, Mokhtari M, Elmsellem H, Steli H (2019) Environmentally friendly inhibitor of the corrosion of mild steel: commercial oil of eucalyptus. Int J Corros Scale Inhib 8(3):573–585. https://doi.org/10.17675/2305-6894-2019-8-3-8
Hamadi L, Mansouri S, Oulmi K, Kareche A (2018) The use of amino acids as corrosion inhibitors for metals : A review. Egypt J Pet. https://doi.org/10.1016/j.ejpe.2018.04.004
Hammoudan I, Chtita S, Riffi-Temsamani D (2020) QTAIM and IRC studies for the evaluation of activation energy on the C=P, C=N and C=O Diels-Alder reaction. Heliyon 6(8):3–7. https://doi.org/10.1016/j.heliyon.2020.e04655
Hammoudan I, Aboulmouhajir A, Dakir M, Temsamani DR, Bakhouch M, Bazi El D, Chtita S (2022) Mechanistic elucidation of Diels–Alder cycloaddition reactions between quinoflavonoid and substituted butadiene using LOL, ELF, QTAIM, and DFT studies. Struct Chem 0123456789. https://doi.org/10.1007/s11224-022-02058-z
Haque J, Verma C, Srivastava V, Quraishi MA, Ebenso EE (2018) Experimental and quantum chemical studies of functionalized tetrahydropyridines as corrosion inhibitors for mild steel in 1 M hydrochloric acid. Results Phys 9(March):1481–1493. https://doi.org/10.1016/j.rinp.2018.04.069
Hau NN, Huong DQ (n.d.) Pr ep rin t n ot pe er r er r Pr ep t n ed
Hegazy MA, Hasan AM, Emara MM, Bakr MF, Youssef AH (2012) Evaluating four synthesized Schiff bases as corrosion inhibitors on the carbon steel in 1 M hydrochloric acid. Corros Sci 65:67–76. https://doi.org/10.1016/j.corsci.2012.08.005
Hrimla M, Bahsis L, Boutouil A, Laamari MR, Julve M, Stiriba SE (2021) Corrosion inhibition performance of a structurally well-defined 1,2,3-triazole derivative on mild steel-hydrochloric acid interface. J Mol Struct 1231:129895. https://doi.org/10.1016/j.molstruc.2021.129895
Hsissou R, Abbout S, Berisha A, Berradi M, Assouag M, Hajjaji N, Elharfi A (2019) Experimental, DFT and molecular dynamics simulation on the inhibition performance of the DGDCBA epoxy polymer against the corrosion of the E24 carbon steel in 1.0 M HCl solution. J Mol Struct 1182:340–351. https://doi.org/10.1016/j.molstruc.2018.12.030
Hsissou R, Benhiba F, Dagdag O, El Bouchti M, Nouneh K, Assouag M, Briche S, Zarrouk A, Elharfi A (2020) Development and potential performance of prepolymer in corrosion inhibition for carbon steel in 1.0 M HCl: outlooks from experimental and computational investigations. J Colloid Interface Sci 574:43–60. https://doi.org/10.1016/j.jcis.2020.04.022
Hsissou R, Benhiba F, Echihi S, Benzidia B, Cherrouf S, Haldhar R, Ahmad Alvi P, Kaya S, Serdaroğlu G, Zarrouk A (2021) Performance of curing epoxy resin as potential anticorrosive coating for carbon steel in 3.5% NaCl medium: combining experimental and computational approaches. Chem Phys Lett 783(September2021). https://doi.org/10.1016/j.cplett.2021.139081
Hu RG, Zhang S, Bu JF, Lin CJ, Song GL (2012) Recent progress in corrosion protection of magnesium alloys by organic coatings. Prog Org Coat 73(2–3):129–141. https://doi.org/10.1016/j.porgcoat.2011.10.011
Idir B, Kellou-Kerkouche F (2018) Experimental and theoretical studies on corrosion inhibition performance of phenanthroline for cast iron in acid solution. J Electrochem Sci Technol 9(4):260–275. https://doi.org/10.5229/JECST.2018.9.4.260
Kamburova K, Boshkova N, Boshkov N, Radeva T (2021) Composite coatings with polymeric modified ZnO nanoparticles and nanocontainers with inhibitor for corrosion protection of low carbon steel. Colloids Surf A: Physicochem Eng Aspects 609(August 2020):125741. https://doi.org/10.1016/j.colsurfa.2020.125741
Khaled KF, El-Maghraby A (2014) Experimental, Monte Carlo and molecular dynamics simulations to investigate corrosion inhibition of mild steel in hydrochloric acid solutions. Arab J Chem 7(3):319–326. https://doi.org/10.1016/j.arabjc.2010.11.005
Kokalj A (2010) Is the analysis of molecular electronic structure of corrosion inhibitors sufficient to predict the trend of their inhibition performance. Electrochim Acta 56(2):745–755. https://doi.org/10.1016/j.electacta.2010.09.065
Labjar N, Lebrini M, Bentiss F, Chihib NE, Hajjaji SE, Jama C (2010) Corrosion inhibition of carbon steel and antibacterial properties of aminotris-(methylenephosphonic) acid. Mater Chem Phys 119(1–2):330–336. https://doi.org/10.1016/j.matchemphys.2009.09.006
Lgaz H, Saha SK, Chaouiki A, Bhat KS, Salghi R, Shubhalaxmi Banerjee P, Ali IH, Khan MI, Chung IM (2020) Exploring the potential role of pyrazoline derivatives in corrosion inhibition of mild steel in hydrochloric acid solution: Insights from experimental and computational studies. Construct Build Mater 233:117320. https://doi.org/10.1016/j.conbuildmat.2019.117320
Lgaz H, Salghi R, Subrahmanya Bhat K, Chaouiki A, Shubhalaxmi, Jodeh S (2017) Correlated experimental and theoretical study on inhibition behavior of novel quinoline derivatives for the corrosion of mild steel in hydrochloric acid solution. In Journal of Molecular Liquids. Elsevier B.V. Vol. 244. https://doi.org/10.1016/j.molliq.2017.08.121
Lotfi A, Manzoori JL, Mohagheghi A (2017) Determination of sertraline in pharmaceutical and biological samples using 1, 10-phenanthroline-terbium probe and silver nanoparticles enhanced fluorescence. J Lumin 185:132–140. https://doi.org/10.1016/j.jlumin.2016.12.053
Luo W, Lin Q, Ran X, Li W, Tan B, Fu A, Zhang S (2021) A new pyridazine derivative synthesized as an efficient corrosion inhibitor for copper in sulfuric acid medium: experimental and theoretical calculation studies. J Mol Liq 341:117370. https://doi.org/10.1016/j.molliq.2021.117370
Madkour LH, Kaya S, Obot IB (2018) Computational, Monte Carlo simulation and experimental studies of some arylazotriazoles (AATR) and their copper complexes in corrosion inhibition process. J Mol Liq 260(2017):351–374. https://doi.org/10.1016/j.molliq.2018.01.055
Mazumder MAJ, Al-Muallem HA, Faiz M, Ali SA (2014) Design and synthesis of a novel class of inhibitors for mild steel corrosion in acidic and carbon dioxide-saturated saline media. Corros Sci 87:187–198. https://doi.org/10.1016/j.corsci.2014.06.026
Metropolis N, Rosenbluth AW, Rosenbluth MN, Teller AH, Teller E (1953) Equation of state calculations by fast computing machines. J Chem Phys 21(6):1087–1092. https://doi.org/10.1063/1.1699114
Morad MS, El-Dean AMK (2006) 2,2′-Dithiobis(3-cyano-4,6-dimethylpyridine): a new class of acid corrosion inhibitors for mild steel. Corros Sci 48(11):3398–3412. https://doi.org/10.1016/j.corsci.2005.12.006
Nady H, Elgendy A, Arafa WAA, Gad ES (2022) Insight into the inhibition performance of thiosemicarbazones as efficient inhibitors for copper in acidic environment: combined experimental and computational investigations. Colloids SurfA: Physicochem Eng Aspects 647(March):129208. https://doi.org/10.1016/j.colsurfa.2022.129208
Obot IB, Macdonald DD, Gasem ZM (2015) Density functional theory (DFT) as a powerful tool for designing new organic corrosion inhibitors: part 1: an overview. Corros Sci 99:1–30. https://doi.org/10.1016/j.corsci.2015.01.037
Oguzie EE (2008) Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel. Corros Sci 50(11):2993–2998. https://doi.org/10.1016/j.corsci.2008.08.004
Ojha LK, Tüzün B, Bhawsar J (2020) Experimental and theoretical study of effect of Allium sativum extracts as corrosion inhibitor on mild steel in 1 M HCl medium. J Bio- and Tribo-Corros 6(2):1–10. https://doi.org/10.1007/s40735-020-00336-z
Olasunkanmi LO, Obot IB, Kabanda MM, Ebenso EE (2015) Some quinoxalin-6-yl derivatives as corrosion inhibitors for mild steel in hydrochloric acid: experimental and theoretical studies. J Phys Chem C 119(28):16004–16019. https://doi.org/10.1021/acs.jpcc.5b03285
Olivares GZ, Gayosso MJH (2015) Corrosion of steel pipelines transporting hydrocarbon condensed products, obtained from a high pressure separator system: a failure analysis study. Mater Sci Appl 06(08):760–772. https://doi.org/10.4236/msa.2015.68078
Ongun Yüce A, Doǧru Mert B, Kardaş G, Yazici B (2014) Electrochemical and quantum chemical studies of 2-amino-4-methyl-thiazole as corrosion inhibitor for mild steel in HCl solution. Corros Sci 83:310–316. https://doi.org/10.1016/j.corsci.2014.02.029
Ouakki M, Galai M, Rbaa M, Abousalem AS, Lakhrissi B, Touhami ME, Cherkaoui M (2020) Electrochemical, thermodynamic and theoretical studies of some imidazole derivatives compounds as acid corrosion inhibitors for mild steel. J Mol Liq 319:114063. https://doi.org/10.1016/j.molliq.2020.114063
Qiang Y, Zhang S, Yan S, Zou X, Chen S (2017) Three indazole derivatives as corrosion inhibitors of copper in a neutral chloride solution. Corros Sci 126(July):295–304. https://doi.org/10.1016/j.corsci.2017.07.012
Rbaa M, Benhiba F, Obot IB, Oudda H, Warad I, Lakhrissi B, Zarrouk A (2019) Two new 8-hydroxyquinoline derivatives as an efficient corrosion inhibitors for mild steel in hydrochloric acid: synthesis, electrochemical, surface morphological, UV–visible and theoretical studies. J Mol Liq 276:120–133. https://doi.org/10.1016/j.molliq.2018.11.104
Rouifi Z, Rbaa M, Abousalem AS, Benhiba F, Laabaissi T, Oudda H, Lakhrissi B, Guenbour A, Warad I, Zarrouk A (2020) Synthesis, characterization and corrosion inhibition potential of newly benzimidazole derivatives: combining theoretical and experimental study. Surf Interfaces 18(January). https://doi.org/10.1016/j.surfin.2020.100442
Roy P, Karfa P, Adhikari U, Sukul D (2014) Corrosion inhibition of mild steel in acidic medium by polyacrylamide grafted guar gum with various grafting percentage: effect of intramolecular synergism. Corros Sci 88:246–253. https://doi.org/10.1016/j.corsci.2014.07.039
Saddik R, Hammoudan I, Tighadouini S, Roby O, Radi S, Al-Zaben MI, Ben Bacha A, Masand VH, Almarhoon ZM (2022) Mesoporous silica modified with 2-phenylimidazo[1,2-a] pyridine-3-carbaldehyde as an effective adsorbent for Cu(II) from aqueous solutions: a combined experimental and theoretical study. Molecules 27(16). https://doi.org/10.3390/molecules27165168
Sanaei Z, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B (2019) Use of Rosa canina fruit extract as a green corrosion inhibitor for mild steel in 1 M HCl solution: a complementary experimental, molecular dynamics and quantum mechanics investigation. J Ind Eng Chem 69:18–31. https://doi.org/10.1016/j.jiec.2018.09.013
Sedik A, Lerari D, Salci A, Athmani S, Bachari K, Gecibesler H, Solmaz R (2020) Dardagan fruit extract as eco-friendly corrosion inhibitor for mild steel in 1 M HCl: electrochemical and surface morphological studies. J Taiwan Inst Chem Eng 107:189–200. https://doi.org/10.1016/j.jtice.2019.12.006
Shahini MH, Keramatinia M, Ramezanzadeh M, Ramezanzadeh B, Bahlakeh G (2021) Combined atomic-scale/DFT-theoretical simulations & electrochemical assessments of the chamomile flower extract as a green corrosion inhibitor for mild steel in HCl solution. J Mol Liq 342:117570. https://doi.org/10.1016/j.molliq.2021.117570
Singh P, Ebenso EE, Olasunkanmi LO, Obot IB, Quraishi MA (2016) Electrochemical, theoretical, and surface morphological studies of corrosion inhibition effect of green naphthyridine derivatives on mild steel in hydrochloric acid. J Phys Chem C 120(6):3408–3419. https://doi.org/10.1021/acs.jpcc.5b11901
Singh P, Chauhan DS, Chauhan SS, Singh G, Quraishi MA (2019) Chemically modified expired Dapsone drug as environmentally benign corrosion inhibitor for mild steel in sulphuric acid useful for industrial pickling process. J Mol Liq 286:110903. https://doi.org/10.1016/j.molliq.2019.110903
Singh A, Ansari KR, Quraishi MA, Kaya S, Erkan S (2021) Chemically modified guar gum and ethyl acrylate composite as a new corrosion inhibitor for reduction in hydrogen evolution and tubular steel corrosion protection in acidic environment. Int J Hydrogen Energy 46(14):9452–9465. https://doi.org/10.1016/j.ijhydene.2020.12.103
Sun H (1998) The COMPASS force field: parameterization and validation for phosphazenes. Comput Theor Polym Sci 8(1–2):229–246. https://doi.org/10.1016/S1089-3156(98)00042-7
Tan B, Zhang S, Liu H, Guo Y, Qiang Y, Li W, Guo L, Xu C, Chen S (2019) Corrosion inhibition of X65 steel in sulfuric acid by two food flavorants 2-isobutylthiazole and 1-(1,3-thiazol-2-yl) ethanone as the green environmental corrosion inhibitors: combination of experimental and theoretical researches. J Colloid Interface Sci 538:519–529. https://doi.org/10.1016/j.jcis.2018.12.020
Tang Y, Zhang F, Hu S, Cao Z, Wu Z, Jing W (2013) Novel benzimidazole derivatives as corrosion inhibitors of mild steel in the acidic media. Part I: gravimetric, electrochemical. SEM and XPS Studies Corrosion Science 74:271–282. https://doi.org/10.1016/j.corsci.2013.04.053
Tighadouini S, Radi S, Roby O, Hammoudan I, Saddik R, Garcia Y, Almarhoon ZM, Mabkhot YN (2021) Kinetics, thermodynamics, equilibrium, surface modelling, and atomic absorption analysis of selective Cu(ii) removal from aqueous solutions and rivers water using silica-2-(pyridin-2-ylmethoxy)ethan-1-ol hybrid material. RSC Adv 12(1):611–625. https://doi.org/10.1039/d1ra06640d
Verma C, Olasunkanmi LO, Ebenso EE, Quraishi MA, Obot IB (2016) Adsorption behavior of glucosamine-based, pyrimidine-fused heterocycles as green corrosion inhibitors for mild steel: experimental and theoretical studies. J Phys Chem C 120(21):11598–11611. https://doi.org/10.1021/acs.jpcc.6b04429
Verma C, Lgaz H, Verma DK, Ebenso EE, Bahadur I, Quraishi MA (2018a) Molecular dynamics and Monte Carlo simulations as powerful tools for study of interfacial adsorption behavior of corrosion inhibitors in aqueous phase : a review. J Mol Liq 260:99–120. https://doi.org/10.1016/j.molliq.2018.03.045
Verma C, Obot IB, Bahadur I, Sherif ESM, Ebenso EE (2018b) Choline based ionic liquids as sustainable corrosion inhibitors on mild steel surface in acidic medium: gravimetric, electrochemical, surface morphology, DFT and Monte Carlo simulation studies. Appl Surf Sci 457:134–149. https://doi.org/10.1016/j.apsusc.2018.06.035
Verma C, Quraishi MA, Ebenso EE, Bahadur I (2018c) A green and sustainable approach for mild steel acidic corrosion inhibition using leaves extract: experimental and DFT studies. J Bio- and Tribo-Corros 4(3):0. https://doi.org/10.1007/s40735-018-0150-3
Verma C, Quraishi MA, Ebenso EE (2020) Quinoline and its derivatives as corrosion inhibitors: a review. Surf Interfaces, 21(June). https://doi.org/10.1016/j.surfin.2020.100634
Wang D, Xiang B, Liang Y, Song S, Liu C (2014) Corrosion control of copper in 3.5 wt.% NaCl solution by domperidone: experimental and theoretical study. Corros Sci 85:77–86. https://doi.org/10.1016/j.corsci.2014.04.002
Wei H, Heidarshenas B, Zhou L, Hussain G, Li Q, Ostrikov K (Ken) (2020) Green inhibitors for steel corrosion in acidic environment: state of art. Mater Today Sustain 10:100044. https://doi.org/10.1016/j.mtsust.2020.100044
Xiao-Ci Y, Hong Z, Ming-Dao L, Hong-Xuan R, Lu-An Y (2000) Quantum chemical study of the inhibition properties of pyridine and its derivatives at an aluminum surface. Corros Sci 42(4):645–653. https://doi.org/10.1016/S0010-938X(99)00091-8
Yadav M, Kumar S, Tiwari N, Bahadur I, Ebenso EE (2015) Experimental and quantum chemical studies of synthesized triazine derivatives as an efficient corrosion inhibitor for N80 steel in acidic medium. J Mol Liq 212:151–167. https://doi.org/10.1016/j.molliq.2015.09.019
Yousefi A, Javadian S, Sharifi M, Dalir N, Motaee A (2019) An experimental and theoretical study of biodegradable gemini surfactants and surfactant/carbon nanotubes (CNTs) mixtures as new corrosion inhibitor. J Bio- and Tribo-Corros 5(4). https://doi.org/10.1007/s40735-019-0274-0
Yüce AO (2020) Corrosion inhibition behavior of Robinia pseudoacacia leaves extract as a eco-friendly inhibitor on mild steel in acidic media. Met Mater Int 26(4):456–466. https://doi.org/10.1007/s12540-019-00509-7
Zhang J (2009) A review of steel corrosion by liquid lead and lead-bismuth. Corros Sci 51(6):1207–1227. https://doi.org/10.1016/j.corsci.2009.03.013
Zhang Z, Chen S, Li Y, Li S, Wang L (2009) A study of the inhibition of iron corrosion by imidazole and its derivatives self-assembled films. Corros Sci 51(2):291–300. https://doi.org/10.1016/j.corsci.2008.10.040
Zhang D, Tang Y, Qi S, Dong D, Cang H, Lu G (2016) The inhibition performance of long-chain alkyl-substituted benzimidazole derivatives for corrosion of mild steel in HCl. Corros Sci 102:517–522. https://doi.org/10.1016/j.corsci.2015.10.002
Zhang HH, Chen Y, Zhang Z (2018) Comparative studies of two benzaldehyde thiosemicarbazone derivatives as corrosion inhibitors for mild steel in 1.0 M HCl. Results Phys 11(August):554–563. https://doi.org/10.1016/j.rinp.2018.09.038
Zhang J, Jing B, Tang Z, Ao Z, Xia D, Zhu M, Wang S (2021) Experimental and DFT insights into the visible-light driving metal-free C3N5 activated persulfate system for efficient water purification. Appl Catal B: Environ 289(January):120023. https://doi.org/10.1016/j.apcatb.2021.120023
Zhou L, Lv YL, Hu YX, Zhao JH, Xia X, Li X (2018) Experimental and theoretical investigations of 1,3,5-tris(4-aminophenoxy)benzene as an effective corrosion inhibitor for mild steel in 1 M HCl. J Mol Liq 249:179–187. https://doi.org/10.1016/j.molliq.2017.10.129
Zouitini A, Kandri Rodi Y, Ouzidan Y, Ouazzani Chahdi F, Mokhtari M, Abdel-Rahman I, Essassi EM, Aouniti A, Hammouti B, Elmsellem H (2019) Corrosion inhibition studies of new synthesized 1,4-dioctyl-6-methyl-1,4-dihydroquinoxaline-2,3-dione on mild steel in 1.0 M HCl solution using gravimetric and electrochemical techniques supported by theoretical DFT calculations. Int J Corros Scale Inhib 8(2):225–240. https://doi.org/10.17675/2305-6894-2019-8-2-5
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Conception and design of the study: Mimoun Belhadi.
Calculation of data: Imade Hammoudan, Anas Chraka.
Analysis and/or interpretation of data: Mimoun Belhadi, Imade Hammoudan, Anas Chraka, Said Tighadouini, and Mohammed Chafi. Mimoun BELHADI wrote the first draft of the manuscript and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Belhadi, M., Oubahou, M., Hammoudan, I. et al. A comprehensive assessment of carbon steel corrosion inhibition by 1,10-phenanthroline in the acidic environment: insights from experimental and computational studies. Environ Sci Pollut Res (2023). https://doi.org/10.1007/s11356-023-27582-1
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DOI: https://doi.org/10.1007/s11356-023-27582-1