Abstract
The textile industry contributes significantly to environmental pollution through dyeing and finishing processes that release dyes into wastewater. Even small amounts of dyes can have harmful effects and cause negative impacts. These effluents have carcinogenic, toxic, and teratogenic properties and can take a long time to be naturally degraded through photo/bio-degradation processes. This work investigates degradation of Reactive Blue 21 (RB21) phthalocyanine dye using anodic oxidation process with PbO2 anode doped with iron III (0.1 M) (marked as Ti/PbO2-0.1Fe) and compared with pure PbO2. Ti/PbO2 films with and without doping were successfully prepared by electrodeposition technology on Ti substrates. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM/EDS) was used to characterize the electrode morphology. Also, linear scanning voltammetry (LSV) and cyclic voltammetry (CV) tests were conducted to investigate the electrochemical response of these electrodes. The influence of operational variables on the mineralization efficiency was studied as a function of pH, temperature, and current density. Doping Ti/PbO2 with Fe3+ (0.1 M) could reduce the particle to a smaller dimension and slightly increase the oxygen evolution potential (OEP). A large anodic peak was found for both electrodes prepared in the CV test, indicating that oxidation of the RB21 dye was easily achieved on the surface of the prepared anodes. No significant effect of initial pH on the mineralization of RB21 was observed. RB21 decolorization was more rapid at room temperature and increases with increasing current density. A possible degradation pathway for the anodic oxidation of RB21 in aqueous solution is proposed based on the identified reaction products. In general, it can be said that from the findings it was observed that the Ti/PbO2 and Ti/PbO2-0.1Fe electrodes show good performance on RB21 degradation. However, it was noted that the Ti/PbO2 electrode tends to deteriorate over time and exhibits poor substrate adhesion, while the Ti/PbO2-0.1Fe electrode displays superior substrate adhesion and stability.
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Abdel-Aziz MH, Bassyouni M, Zoromba MS, Alshehri AA (2019) Removal of dyes from waste solutions by anodic oxidation on an array of horizontal graphite rods anodes. Ind Eng Chem Res 58:1004–1018. https://doi.org/10.1021/acs.iecr.8b05291
Atrak K, Ramazani A, Taghavi Fardood S (2019) Green synthesis of Zn 0.5 Ni 0.5 AlFeO 4 magnetic nanoparticles and investigation of their photocatalytic activity for degradation of reactive blue 21 dye. Environ Technol (United Kingdom). https://doi.org/10.1080/09593330.2019.1581841
Baddouh A, Bessegato GG, Rguiti MM, El Ibrahimi B, Bazzi L, Hilali M, Zanoni MVB (2018) Electrochemical decolorization of Rhodamine B dye: influence of anode material, chloride concentration and current density. J Environ Chem Eng 6:2041–2047. https://doi.org/10.1016/J.JECE.2018.03.007
Baddouh A, El Ibrahimi B, Rguitti MM, Mohamed E, Hussain S, Bazzi L (2019) Electrochemical removal of methylene bleu dye in aqueous solution using Ti/RuO2–IrO2 and SnO2 electrodes. Sep Sci Technol 55:1852–1861. https://doi.org/10.1080/01496395.2019.1608244
Barroso-Martínez JS, Romo AIB, Pudar S, Putnam ST, Bustos E, Rodríguez-López J (2022) Real-time detection of hydroxyl radical generated at operating electrodes via redox-active adduct formation using scanning electrochemical microscopy. J Am Chem Soc 144:18896–18907. https://doi.org/10.1021/JACS.2C06278/SUPPL_FILE/JA2C06278_SI_001.PDF
Bensalah N, Faouzi Ahmadi M, Martinez-Huitle CA (2021) Electrochemical oxidation of 2-chloroaniline in single and divided electrochemical flow cells using boron doped diamond anodes. Sep Purif Technol 263:118399. https://doi.org/10.1016/J.SEPPUR.2021.118399
Brinzila CI, Pacheco MJ, Ciríaco L, Ciobanu RC, Lopes A (2012) Electrodegradation of tetracycline on BDD anode. Chem Eng J 209:54–61. https://doi.org/10.1016/J.CEJ.2012.07.112
Carvalho DA, Bezerra Rocha JH, Fernandes NS, Da Silva DR, Martínez-Huitle CA (2011) Application of electrochemical oxidation as alternative for removing methyl green dye from aqueous solutions. Lat Am Appl Res 41:127–133
Chaukura N, Murimba EC, Gwenzi W (2017) Synthesis, characterisation and methyl orange adsorption capacity of ferric oxide–biochar nano-composites derived from pulp and paper sludge. Appl Water Sci 7:2175–2186. https://doi.org/10.1007/s13201-016-0392-5
Ciríaco L, Anjo C, Correia J, Pacheco MJ, Lopes A (2009) Electrochemical degradation of ibuprofen on Ti/Pt/PbO2 and Si/BDD electrodes. Electrochim Acta 54:1464–1472. https://doi.org/10.1016/J.ELECTACTA.2008.09.022
Donkadokula NY, Kola AK, Naz I, Saroj D (2020) A review on advanced physico-chemical and biological textile dye wastewater treatment techniques. Rev Environ Sci Biotechnol 19:543–560. https://doi.org/10.1007/S11157-020-09543-Z/TABLES/4
El AA, Bensalah J, Idrissi A, Lamya K, Ouass A, Bouzakraoui S, Zarrouk A, Rifi EH, Lebkiri A (2022) Adsorption of a cationic dye (Methylene bleu) by Typha latifolia: equilibrium, kinetic, thermodynamic and DFT calculations. Chem Data Collect 38:100834. https://doi.org/10.1016/J.CDC.2022.100834
El Aggadi S, El Hourch A (2021) Removal of Reactive Blue 21 (RB21) Phthalocyanine dye from aqueous solution by adsorption process: a review. Polish J Environ Stud 30:3425–3432. https://doi.org/10.15244/PJOES/127384
El Aggadi S, El Abbassi Z, El Hourch A (2021) Color removal from dye-containing aqueous solutions by electrooxidation. Desalin Water Treat 215:232–236. https://doi.org/10.5004/dwt.2021.26766
El Aggadi S, Kerroum Y, El Hourch A (2022) Elaboration and characterization of Fe/C-doped lead dioxide-modified anodes for electrocatalytic degradation of Reactive Yellow 14. J Appl Electrochem 53:109–119. https://doi.org/10.1007/S10800-022-01766-Y/METRICS
Feng Q, Gao B, Yue Q, Guo K (2021) Flocculation performance of papermaking sludge-based flocculants in different dye wastewater treatment: comparison with commercial lignin and coagulants. Chemosphere 262:128416. https://doi.org/10.1016/J.CHEMOSPHERE.2020.128416
Ghanbari F, Khatebasreh M, Mahdavianpour M, Lin KYA (2020) Oxidative removal of benzotriazole using peroxymonosulfate/ozone/ultrasound: synergy, optimization, degradation intermediates and utilizing for real wastewater. Chemosphere 244:125326. https://doi.org/10.1016/J.CHEMOSPHERE.2019.125326
Hao X, Quansheng Y, Dan S, Honghui Y, Jidong L, Jiangtao F, Wei Y (2015) Fabrication and characterization of PbO2 electrode modified with [Fe(CN)6]3- and its application on electrochemical degradation of alkali lignin. J Hazard Mater 286:509–516. https://doi.org/10.1016/j.jhazmat.2014.12.065
Hao X, Wuqi G, Jia W, Jiangtao F, Honghui Y, Wei Y (2016) Preparation and characterization of titanium-based PbO2 electrodes modified by ethylene glycol. RSC Adv 6:7610–7617. https://doi.org/10.1039/c5ra21195f
He Y, Huang W, Chen R, Zhang W, Lin H, Li H (2015) Anodic oxidation of aspirin on PbO2, BDD and porous Ti/BDD electrodes: mechanism, kinetics and utilization rate. Sep Purif Technol 156:124–131. https://doi.org/10.1016/J.SEPPUR.2015.09.036
Hosseini SR, Akbari A (2023) Effects of chitosan and piperazine on surface morphology and mebeverine hydrochloride removal in polyurea thin film composite membranes. Brazilian J Chem Eng 40:247–255. https://doi.org/10.1007/s43153-022-00230-w
Jua LY, Karri RR, Mubarak NM, Yon LS, Bing CH, Khalid M, Jagadish P, Abdullah EC (2020) Modeling of methylene blue adsorption using functionalized Buckypaper/Polyvinyl alcohol membrane via ant colony optimization. Environ Pollut 259:113940
Karabacakoğlu B, Tezakıl F (2023) Electrocoagulation of corrugated box industrial effluents and optimization by response surface methodology. Electrocatalysis 14:159–169. https://doi.org/10.1007/S12678-022-00781-Z/FIGURES/7
Kumar D, Gupta SK (2022) Electrochemical oxidation of direct blue 86 dye using MMO coated Ti anode: modelling, kinetics and degradation pathway. Chem Eng Process - Process Intensif 181:109127. https://doi.org/10.1016/J.CEP.2022.109127
Li X, Xu H, Yan W (2016) Fabrication and characterization of PbO 2 electrode modified with polyvinylidene fluoride (PVDF). Appl Surf Sci 389:278–286. https://doi.org/10.1016/j.apsusc.2016.07.123
Man S, Bao H, Yang H, Xu K, Li A, Xie Y, Jian Y, Yang W, Mo Z, Li X (2021) Preparation and characterization of nano-SiC doped PbO2 electrode for degradation of toluene diamine. J Alloys Compd 859:157884. https://doi.org/10.1016/J.JALLCOM.2020.157884
Martínez-Huitle CA, Panizza M (2018) Electrochemical oxidation of organic pollutants for wastewater treatment. Curr Opin Electrochem 11:62–71. https://doi.org/10.1016/J.COELEC.2018.07.010
Moreira FC, Boaventura RAR, Brillas E, Vilar VJP (2017) Electrochemical advanced oxidation processes: a review on their application to synthetic and real wastewaters. Appl Catal B Environ 202:217–261. https://doi.org/10.1016/J.APCATB.2016.08.037
Nor FHM, Abdullah S, Ibrahim Z, Nor MHM, Osman MI, Al Farraj DA, AbdelGawwad MR, Kamyab H (2022) Role of extremophilic Bacillus cereus KH1 and its lipopeptide in treatment of organic pollutant in wastewater. Bioprocess Biosyst Eng 46:381–391. https://doi.org/10.1007/S00449-022-02749-1/METRICS
Othmani A, Kesraoui A, Akrout H, López-Mesas M, Seffen M, Valiente M (2019) Use of alternating current for colored water purification by anodic oxidation with SS/PbO2 and Pb/PbO2 electrodes. Environ Sci Pollut Res 26:25969–25984. https://doi.org/10.1007/S11356-019-05722-W/METRICS
Reid LM, Li T, Cao Y, Berlinguette CP (2018) Organic chemistry at anodes and photoanodes. Sustain Energy Fuels 2:1905–1927. https://doi.org/10.1039/C8SE00175H
Rossi A, Alves VA, Da Silva LA, Oliveira MA, Assis DOS, Santos FA, De Miranda RRS (2009) Electrooxidation and inhibition of the antibacterial activity of oxytetracycline hydrochloride using a RuO2 electrode. J Appl Electrochem 39:329–337. https://doi.org/10.1007/S10800-008-9676-2/METRICS
Samarghandi MR, Dargahi A, Shabanloo A, Nasab HZ, Vaziri Y, Ansari A (2020) Electrochemical degradation of methylene blue dye using a graphite doped PbO2 anode: optimization of operational parameters, degradation pathway and improving the biodegradability of textile wastewater. Arab J Chem 13:6847–6864. https://doi.org/10.1016/J.ARABJC.2020.06.038
Sandoval MA, Espinoza LC, Coreño O, García V, Fuentes R, Thiam A, Salazar R (2022) A comparative study of anodic oxidation and electrocoagulation for treating cattle slaughterhouse wastewater. J Environ Chem Eng 10:108306. https://doi.org/10.1016/J.JECE.2022.108306
Schneider M, Bláha L (2020) Advanced oxidation processes for the removal of cyanobacterial toxins from drinking water. Environ Sci Eur 32:1–24. https://doi.org/10.1186/S12302-020-00371-0
Silva MC, Corrêa AD, Amorim MTSP, Parpot P, Torres JA, Chagas PMB (2012) Decolorization of the phthalocyanine dye reactive blue 21 by turnip peroxidase and assessment of its oxidation products. J Mol Catal B Enzym 77:9–14. https://doi.org/10.1016/J.MOLCATB.2011.12.006
Song S, Fan J, He Z, Zhan L, Liu Z, Chen J, Xu X (2010) Electrochemical degradation of azo dye C.I. Reactive Red 195 by anodic oxidation on Ti/SnO2–Sb/PbO2 electrodes. Electrochim Acta 55:3606–3613. https://doi.org/10.1016/J.ELECTACTA.2010.01.101
Stirling R, Walker WS, Westerhoff P, Garcia-Segura S (2020) Techno-economic analysis to identify key innovations required for electrochemical oxidation as point-of-use treatment systems. Electrochim Acta 338:135874. https://doi.org/10.1016/J.ELECTACTA.2020.135874
Wang Y, Shen C, Zhang M, Zhang BT, Yu YG (2016) The electrochemical degradation of ciprofloxacin using a SnO2-Sb/Ti anode: influencing factors, reaction pathways and energy demand. Chem Eng J 296:79–89. https://doi.org/10.1016/J.CEJ.2016.03.093
Wang J, Zhi D, Zhou H, He X, Zhang D (2018) Evaluating tetracycline degradation pathway and intermediate toxicity during the electrochemical oxidation over a Ti/Ti4O7 anode. Water Res 137:324–334. https://doi.org/10.1016/J.WATRES.2018.03.030
Wang J, Zheng T, Liu H, Wang G, Zhang Y, Cai C (2020) Direct and indirect electrochemical oxidation of ethanethiol on grey cast iron anode in alkaline solution. Electrochim Acta 356:136706. https://doi.org/10.1016/J.ELECTACTA.2020.136706
Wu J, Zhang H, Oturan N, Wang Y, Chen L, Oturan MA (2012) Application of response surface methodology to the removal of the antibiotic tetracycline by electrochemical process using carbon-felt cathode and DSA (Ti/RuO2–IrO2) anode. Chemosphere 87:614–620. https://doi.org/10.1016/J.CHEMOSPHERE.2012.01.036
Yao Y, Ren B, Yang Y, Huang C, Li M (2019) Preparation and electrochemical treatment application of Ce-PbO2/ZrO2 composite electrode in the degradation of acridine orange by electrochemical advanced oxidation process. J Hazard Mater 361:141–151. https://doi.org/10.1016/J.JHAZMAT.2018.08.081
Zhang C, Liu J, Chen B (2019) Effect of Ce(NO 3) 4 on the electrochemical properties of Ti/PbO 2 –TiO 2 –Ce(NO 3) 4 electrode for zinc electrowinning. Appl Phys A Mater Sci Process 125:1–7. https://doi.org/10.1007/s00339-019-2462-7
Zhao J, Zhu C, Lu J, Hu C, Peng S, Chen T (2014) Electro-catalytic degradation of bisphenol A with modified Co3O4/β-PbO2/Ti electrode. Electrochim Acta 118:169–175. https://doi.org/10.1016/J.ELECTACTA.2013.12.005
Zhao B, Yu H, Lu Y, Qu J, Zhu S, Huo M (2019) Polyethylene glycol assisted synthesis of a praseodymium-doped PbO 2 electrode and its enhanced electrocatalytic oxidation performance. J Taiwan Inst Chem Eng 100:144–150. https://doi.org/10.1016/j.jtice.2019.04.015
Zheng T, Wei C, Chen H, Xu J, Wu Y, Xing X (2022) Fabrication of PbO2 electrodes with different doses of Er doping for sulfonamides degradation. Int J Environ Res Public Heal 19:13503. https://doi.org/10.3390/IJERPH192013503
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Sanaa El Aggadi: conceptualization, methodology, software, data curation, writing—original draft, writing—review and editing. Maryem Ennouhi: conceptualization, data curation. Amale Boutakiout: conceptualization, review and editing. Fatima Ezzahra Ennoukh: conceptualization, data curation. Abderrahim El Hourch: conceptualization, supervision, validation.
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El Aggadi, S., Ennouhi, M., Boutakiout, A. et al. Iron (III)-doped PbO2 and its application as electrocatalyst for decomposition of phthalocyanine dye. Environ Sci Pollut Res 30, 70183–70193 (2023). https://doi.org/10.1007/s11356-023-27332-3
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DOI: https://doi.org/10.1007/s11356-023-27332-3