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The clean energy aspect of plastic waste — hydrogen gas production, CO2 reforming, and plastic waste management coincide with catalytic pyrolysis — an extensive review

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Abstract

Clean hydrogen has future fuel capable of receiving an abundance of carbon–neutral energy from hydrogen. In the recent world, new hydrogen affirmation projects have been launched for a green environment. On another side, plastic waste and CO2 threaten the green environment. Vacuum in plastic waste management, plastic waste leads to exhibiting harmful chemicals to the environment. The growth rate of the CO2 concentration in air is 2.45 ppm per year, steadily increasing in 2022. It is realized that uneven climate change, temperature raising the global level, ocean mean level raising, and frequent acidification are dangerous to living and ecosystems. This review discussed tackling multiple harmful environmental fatly by pyrolysis techniques; catalytic pyrolysis is almost reaching the commercialization stage. Recent pyrolysis upgradation methods with hydrogen gas production and the continuous development and execution of sustainable solutions for plastic waste management and CO2 reforming are discussed. Production of carbon nanotubes by plastic waste, the importance of catalyst modification, and the effect of catalyst deactivation are discussed. From this study, integrating the different applications with catalytic modification creates room for multipurpose pyrolysis, CO2 reforming, and hydrogen gas production by pyrolysis techniques capable of giving a sustainable solution for climate change issues and a clean environment. Additionally, carbon utilization by way of carbon nanotube production is also done. Overall, the review supports achieving clean energy from plastic waste.

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Abbreviations

CNT:

Carbon nanotube

H2 :

Hydrogen

CO2 :

Carbon dioxide

PPM:

Parts per million

PS:

Polystyrene

PET:

Polyethylene terephthalate

PP:

Polypropylene

HDPE:

High-density polyethylene

LDPE:

Low-density polyethylene

GHG:

Green house emission

NOX :

Nitrogen oxides

CO:

Carbon monoxide

ER:

Equivalence ratio

DRM:

Dry reforming method

SAP:

Supportive, active, and promoter

CV:

Calorific value

NET:

Negative emission technologies

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Authors

Contributions

Conceptualization; methodology; resources; formal analysis; writing—original draft preparation, review, and editing; supervision; and investigation were carried out by Pitchaiah Sudalaimuthu and Ravishankar Sathyamurthy.

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Correspondence to Ravishankar Sathyamurthy.

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The authors declare no competing interests.

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Responsible Editor: George Z. Kyzas

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Highlights

• Multipurpose catalytic pyrolysis provides room to waste plastics to clean energy hydrogen.

• Required end product composition is feasible by catalyst modification.

• CO2 reforming mitigates coke deposition and enhances catalyst activity and life.

• Carbon nanotube production supports the economic belt of catalytic pyrolysis.

• Incorporation strategies mutually valorize each other and enhance the hydrogen production.

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Sudalaimuthu, P., Sathyamurthy, R. The clean energy aspect of plastic waste — hydrogen gas production, CO2 reforming, and plastic waste management coincide with catalytic pyrolysis — an extensive review. Environ Sci Pollut Res 30, 66559–66584 (2023). https://doi.org/10.1007/s11356-023-26908-3

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  • DOI: https://doi.org/10.1007/s11356-023-26908-3

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