Abstract
Carbon nanomaterials (CNMs) are rapidly emerging in materials science research due to their widespread environmental applications. They are useful for environmental pollutants’ remediation through various methods. Heteroatom doping resulted in reliable approaches to overcome pristine CNMs challenges. The engineering of the dopants is believed to be a promising route to improve the efficiency of CNMs in environmental remediation. The idea of doping has been attractive since it allows the control of electronic properties due to the electron transfer between dopants and the host material and the dopants along with the bonding between analogous atoms and carbon atoms. This mini-review, through computational and experimental studies, puts special emphasis on the role of doping different CNMs as an efficient approach to enhance the environmental remediation.
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Ahmad K, Khan MQ, Alsalme A, Kim H (2022) Sulfur-doped graphitic-carbon nitride (S@ g-C3N4) as bi-functional catalysts for hydrazine sensing and hydrogen production applications. Synth Met 288:117100
Arooj M, Parambath JBM, Ali N et al (2022) Experimental and theoretical review on covalent coupling and elemental doping of carbon nanomaterials for environmental photocatalysis. Crit Rev Solid State Mater Sci. https://doi.org/10.1080/10408436.2022.2049697
Arooj M, Shehadi I, Nassab CN, Mohamed AA (2022) Computational insights into binding mechanism of drugs as potential inhibitors against SARS-CoV-2 targets. Chem Pap 76:111–121
Arooj M, Shehadi I, Nassab CN, Mohamed AA (2020) Physicochemical stability study of protein–benzoic acid complexes using molecular dynamics simulations. Amino Acids 52:1353–1362
Chen A, Zhang Y, Wei X, Pang J, Hu R, Guan J (2022) Preparation of in-situ nitrogen-doped lignin-based porous carbon and its efficient adsorption of chloramphenicol in water. Environ Sci Pollut Res 29:74306–74318. https://doi.org/10.1007/s11356-022-20045-z
Cortés-Arriagada D, Miranda-Rojas S, Ortega DE, Toro-Labbé A (2017) Oxidized and Si-doped graphene: emerging adsorbents for removal of dioxane. Phys Chem Chem Phys 19:17587–17597
Cortés-Arriagada D, Toro-Labbé A (2016) A theoretical investigation of the removal of methylated arsenic pollutants with silicon doped graphene. RSC Adv 6:28500–28511
Cortés-Arriagada D, Toro-Labbé A (2015) Improving As (iii) adsorption on graphene based surfaces: impact of chemical doping. Phys Chem Chem Phys 17:12056–12064
Cui H, Zhou Z, Jia D (2017) Heteroatom-doped graphene as electrocatalysts for air cathodes. Mater Horizons 4:7–19
Ding D, Yang S, Qian X et al (2020) Nitrogen-doping positively whilst sulfur-doping negatively affect the catalytic activity of biochar for the degradation of organic contaminant. Appl Catal B Environ 263:118348
dos Reis GS, de Oliveira HP, Larsson SH et al (2021) A short review on the electrochemical performance of hierarchical and nitrogen-doped activated biocarbon-based electrodes for supercapacitors. Nanomaterials 11:424
dos Reis GS, Guy M, Mathieu M et al (2022) A comparative study of chemical treatment by MgCl2, ZnSO4, ZnCl2, and KOH on physicochemical properties and acetaminophen adsorption performance of biobased porous materials from tree bark residues. Colloids Surf A Physicochem Eng Asp 642:128626
Duan X, Ao Z, Sun H et al (2015) Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: a mechanistic study. Chem Commun 51:15249–15252
Duan X, Sun H, Wang Y et al (2015) N-doping-induced nonradical reaction on single-walled carbon nanotubes for catalytic phenol oxidation. Acs Catal 5:553–559
Esrafili MD (2019) Electric field assisted activation of CO2 over P-doped graphene: a DFT study. J Mol Graph Model 90:192–198
Feng L, Qin Z, Huang Y et al (2020) Boron-, sulfur-, and phosphorus-doped graphene for environmental applications. Sci Total Environ 698:134239
González-Hourcade M, dos Reis GS, Grimm A et al (2022) Microalgae biomass as a sustainable precursor to produce nitrogen-doped biochar for efficient removal of emerging pollutants from aqueous media. J Clean Prod 348:131280
Gulati A, Kakkar R (2020) Graphene-based adsorbents for water remediation by removal of organic pollutants: Theoretical and experimental insights. Chem Eng Res Des 153:21–36
Guo D, Shibuya R, Akiba C et al (2016) Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts. Science 80-(351):361–365
Ha S, Choi GB, Hong S et al (2018) Substitutional boron doping of carbon materials. Carbon Lett 27:1–11
Hola K, Sudolská M, Kalytchuk S et al (2017) Graphitic nitrogen triggers red fluorescence in carbon dots. ACS Nano 11:12402–12410
Hou S, Cai X, Wu H et al (2013) Nitrogen-doped graphene for dye-sensitized solar cells and the role of nitrogen states in triiodide reduction. Energy Environ Sci 6:3356–3362
Hu Y, Chen D, Wang S et al (2022) Activation of peroxymonosulfate by nitrogen-doped porous carbon for efficient degradation of organic pollutants in water: Performance and mechanism. Sep Purif Technol 280:119791
Ji Y, Du J, Chen A (2022) Review on Heteroatom Doping Carbonaceous Materials Toward Electrocatalytic Carbon Dioxide Reduction. Trans Tianjin Univ 28:292–306
Kadian S, Manik G, Kalkal A, Singh, M, Chauhan RP (2019) Effect of sulfur doping on fluorescence and quantum yield of graphene quantum dots: An experimental and theoretical investigation. Nanotechnology 30(43):435704. https://doi.org/10.1088/1361-6528/ab3566
Keru G, Ndungu PG, Nyamori VO (2015) Effect of boron concentration on physicochemical properties of boron-doped carbon nanotubes. Mater Chem Phys 153:323–332. https://doi.org/10.1016/j.matchemphys.2015.01.020
Kiciński W, Szala M, Bystrzejewski M (2014) Sulfur-doped porous carbons: synthesis and applications. Carbon N Y 68:1–32
Kuganathan N, Anurakavan S, Abiman P et al (2021) Adsorption of lead on the surfaces of pristine and B, Si and N-doped graphene. Phys B Condens Matter 600:412639
Kumar M, Jeong DI, Sarwar N et al (2022) Cobalt supported nitrogen-doped carbon nanotube as efficient catalyst for hydrogen evolution reaction and reduction of 4-nitrophenol. Appl Surf Sci 572:151450
Lee CH, Jun B, Lee SU (2018) Metal-free oxygen evolution and oxygen reduction reaction bifunctional electrocatalyst in alkaline media: from mechanisms to structure–catalytic activity relationship. ACS Sustain Chem Eng 6:4973–4980
Li D, Duan X, Sun H et al (2017) Facile synthesis of nitrogen-doped graphene via low-temperature pyrolysis: the effects of precursors and annealing ambience on metal-free catalytic oxidation. Carbon N Y 115:649–658
Li D, Wen C, Huang J et al (2022) High-efficiency ultrathin porous phosphorus-doped graphitic carbon nitride nanosheet photocatalyst for energy production and environmental remediation. Appl Catal B Environ 307:121099
Li L, Gong L, Wang Y-X et al (2016) Removal of halogenated emerging contaminants from water by nitrogen-doped graphene decorated with palladium nanoparticles: experimental investigation and theoretical analysis. Water Res 98:235–241
Li M, Li Z, Yu X et al (2022) FeN4-doped carbon nanotubes derived from metal organic frameworks for effective degradation of organic dyes by peroxymonosulfate: Impacts of FeN4 spin states. Chem Eng J 431:133339
Li X, Huang X, Xi S et al (2018) Single cobalt atoms anchored on porous N-doped graphene with dual reaction sites for efficient Fenton-like catalysis. J Am Chem Soc 140:12469–12475
Liu H, Sun P, Feng M et al (2016) Nitrogen and sulfur co-doped CNT-COOH as an efficient metal-free catalyst for the degradation of UV filter BP-4 based on sulfate radicals. Appl Catal B Environ 187:1–10
Liu Z, Zhang D, Wei T et al (2019) Adsorption characteristics of formaldehyde on nitrogen doped graphene-based single atom adsorbents: a DFT study. Appl Surf Sci 493:1260–1267
Luo Z, Lim S, Tian Z et al (2011) Pyridinic N doped graphene: synthesis, electronic structure, and electrocatalytic property. J Mater Chem 21:8038–8044
Lv R, Li Q, Botello-Méndez AR et al (2012) Nitrogen-doped graphene: beyond single substitution and enhanced molecular sensing. Sci Rep 2:1–8
Ma C, Bai J, Hu X et al (2023) Nitrogen-doped porous carbons from polyacrylonitrile fiber as effective CO2 adsorbents. J Environ Sci 125:533–543
Ma H, Wang G, Xu Z et al (2022) Confining peroxymonosulfate activation in carbon nanotube intercalated nitrogen doped reduced graphene oxide membrane for enhanced water treatment: The role of nanoconfinement effect. J Colloid Interface Sci 608:2740–2751
Mauter MS, Elimelech M (2008) Environmental applications of carbon-based nanomaterials. Environ Sci Technol 42:5843–5859
Meshkat SS, Rashidi A, Dastgerdi ZH, Esrafili MD (2019) Efficient DBT removal from diesel oil by CVD synthesized N-doped graphene as a nanoadsorbent: Equilibrium, kinetic and DFT study. Ecotoxicol Environ Saf 172:89–96
Oh W-D, Lim T-T (2019) Design and application of heterogeneous catalysts as peroxydisulfate activator for organics removal: an overview. Chem Eng J 358:110–133
Olejnik A, Ficek M, Siuzdak K, Bogdanowicz R (2022) Multi-pathway mechanism of polydopamine film formation at vertically aligned diamondised boron-doped carbon nanowalls. Electrochim Acta 409:140000. https://doi.org/10.1016/j.electacta.2022.140000
Ortiz-Medina J, López-Urías F, Terrones H et al (2015) Differential response of doped/defective graphene and dopamine to electric fields: A density functional theory study. J Phys Chem C 119:13972–13978
Ortiz-Medina J, Wang Z, Cruz-Silva R et al (2019) Defect engineering and surface functionalization of nanocarbons for metal-free catalysis. Adv Mater 31:1805717
Parambath J, Arooj M, Omastova M, Chehimi MM, Kim S, Han C, Mohamed AA (2022) Immobilization of Gold–Aryl Nanoparticles Over Graphene Oxide Platforms: Experimental and Molecular Dynamics Calculations Study. J Clust Sci https://doi.org/10.1007/s10876-022-02247-0
Pattanayak DS, Pal D, Mishra J, Thakur C (2022) Noble metal–free doped graphitic carbon nitride (g-C3N4) for efficient photodegradation of antibiotics: progress, limitations, and future directions. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-022-20170-9
Peyghan AA, Noei M, Tabar MB (2013) A large gap opening of graphene induced by the adsorption of Co on the Al-doped site. J Mol Model 19:3007–3014
Peyghan AA, Noei M, Yourdkhani S (2013) Al-doped graphene-like BN nanosheet as a sensor for para-nitrophenol: DFT study. Superlattices Microstruct 59:115–122
Qu S, Yuan Y, Yang X et al (2022) Carbon defects in biochar facilitated nitrogen doping: the significant role of pyridinic nitrogen in peroxymonosulfate activation and ciprofloxacin degradation. Chem Eng J 441:135864. https://doi.org/10.1016/j.cej.2022.135864
Rad AS, Kashani OR (2015) Adsorption of acetyl halide molecules on the surface of pristine and Al-doped graphene: ab initio study. Appl Surf Sci 355:233–241
Sanchez-Sanchez A, Suarez-Garcia F, Martinez-Alonso A, Tascón JMD (2014) Influence of porous texture and surface chemistry on the CO2 adsorption capacity of porous carbons: acidic and basic site interactions. ACS Appl Mater Interfaces 6:21237–21247
Shaheen Shah S, Abu Nayem SM, Sultana N et al (2022) Preparation of Sulfur-doped Carbon for Supercapacitor Applications: A Review. ChemSusChem 15:e202101282. https://doi.org/10.1002/cssc.202101282
Shehadi I, Abla F, Wakefield B et al (2020) Facile protic hydration of acetonitrile to protonated acetamide at oxygen mediated by chloroauric acid: insights from experimental and calculations. Res Chem Intermed 46:593–607
Song Z, Wang M, Wang Z et al (2019) Insights into heteroatom-doped graphene for catalytic ozonation: active centers, reactive oxygen species evolution, and catalytic mechanism. Environ Sci Technol 53:5337–5348
Stoller MD, Park S, Zhu Y et al (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502
Sun F, Liu X, Gao J et al (2016) Highlighting the role of nitrogen doping in enhancing CO2 uptake onto carbon surfaces: a combined experimental and computational analysis. J Mater Chem A 4:18248–18252
Sun H, Kwan C, Suvorova A et al (2014) Catalytic oxidation of organic pollutants on pristine and surface nitrogen-modified carbon nanotubes with sulfate radicals. Appl Catal B Environ 154:134–141
Takahashi R, Harigai T, Tanimoto T et al (2019) Nitrogen doping of carbon nanoballoons by radiofrequency magnetron plasma and evaluation of their oxygen reduction reaction activity. Electron Commun Japan 102:3–10
Tan SM, Poh HL, Sofer Z, Pumera M (2013) Boron-doped graphene and boron-doped diamond electrodes: detection of biomarkers and resistance to fouling. Analyst 138:4885–4891
Tenne R (2006) Inorganic nanotubes and fullerene-like nanoparticles. J Mater Res 21:2726–2743
Vakili F, Rashidi A, Taghavi L, Mansouri N (2021) Single-step synthesis of N, S co-doped waste-derived nanoporous carbon sorbent for mercury vapor removal. Environ Sci Pollut Res 28:17265–17274
Wan Y, Hu Y, Zhou W (2022) Catalytic mechanism of nitrogen-doped biochar under different pyrolysis temperatures: The crucial roles of nitrogen incorporation and carbon configuration. Sci Total Environ 816:151502. https://doi.org/10.1016/j.scitotenv.2021.151502
Wan Z, Sun Y, Tsang DCW et al (2020) Customised fabrication of nitrogen-doped biochar for environmental and energy applications. Chem Eng J 401:126136
Wang D, Wang S, Lu Z (2021) S-doped 3D porous carbons derived from potassium thioacetate activation strategy for zinc-ion hybrid supercapacitor applications. Int J Energy Res 45:2498–2510. https://doi.org/10.1002/er.5944
Wang G, Chen S, Quan X et al (2017) Enhanced activation of peroxymonosulfate by nitrogen doped porous carbon for effective removal of organic pollutants. Carbon N Y 115:730–739
Wang T, Xue L, Liu Y et al (2022) Ring defects-rich and pyridinic N-doped graphene aerogel as floating adsorbent for efficient removal of tetracycline: Evidence from NEXAFS measurements and theoretical calculations. J Hazard Mater 435:128940
Wang Y, Rao L, Wang P et al (2019) Porous oxygen-doped carbon nitride: supramolecular preassembly technology and photocatalytic degradation of organic pollutants under low-intensity light irradiation. Environ Sci Pollut Res 26:15710–15723
Wang Y, Yu M, Zhang T et al (2022) Defect-rich boron doped carbon nanotubes as an electrocatalyst for hybrid Li–air batteries. Catal Sci Technol 12:332–338. https://doi.org/10.1039/D1CY01832A
Wirtz L, Rubio A (2003) Band structure of boron doped carbon nanotubes. AIP Conference Proceedings 685:402–405. https://doi.org/10.1063/1.1628059
Wu G, More KL, Johnston CM, Zelenay P (2011) High-performance electrocatalysts for oxygen reduction derived from polyaniline, iron, and cobalt. Science 80-(332):443–447
Xu L, Wu C, Liu P et al (2020) Peroxymonosulfate activation by nitrogen-doped biochar from sawdust for the efficient degradation of organic pollutants. Chem Eng J 387:124065. https://doi.org/10.1016/j.cej.2020.124065
Yan Z, Yao W, Hu L et al (2015) Progress in the preparation and application of three-dimensional graphene-based porous nanocomposites. Nanoscale 7:5563–5577
Yang Y, Zhang C, Huang D et al (2019) Boron nitride quantum dots decorated ultrathin porous g-C3N4: intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation. Appl Catal B Environ 245:87–99
Yin R, Guo W, Du J et al (2017) Heteroatoms doped graphene for catalytic ozonation of sulfamethoxazole by metal-free catalysis: Performances and mechanisms. Chem Eng J 317:632–639
Yu J, Tang L, Pang Y et al (2020) Hierarchical porous biochar from shrimp shell for persulfate activation: A two-electron transfer path and key impact factors. Appl Catal B Environ 260:118160. https://doi.org/10.1016/j.apcatb.2019.118160
Zhang H, Ding X, Wang S et al (2022a) Heavy Metal Removal from Wastewater by a Polypyrrole-derived N-doped Carbon Nanotube Decorated with Fish Scale-like Molybdenum Disulfide Nanosheets. Eng Sci 18:320–328
Zhang L, Ke Z, Wang W et al (2022b) Enhanced removal of multiple metal ions on S-doped graphene-like carbon-supported layered double oxide: Mechanism and DFT study. Sep Purif Technol 288:120636
Zhang Q, Yu Y, Hong J (2022c) Mechanism and efficiency research of P-and N-codoped graphene for enhanced paracetamol electrocatalytic degradation. Environ Sci Pollut Res 29:80281–80296
Zhang Y, Tan Y-W, Stormer HL, Kim P (2005) Experimental observation of the quantum Hall effect and Berry’s phase in graphene. Nature 438:201–204
Zhang Z, Sun Z, Yao J et al (2009) Transforming carbon nanotube devices into nanoribbon devices. J Am Chem Soc 131:13460–13463
Zhao L, He R, Rim KT et al (2011) Visualizing individual nitrogen dopants in monolayer graphene. Science 80-(333):999–1003
Zhuang Y, Wang X, Liu Q, Shi B (2020) N-doped FeOOH/RGO hydrogels with a dual-reaction-center for enhanced catalytic removal of organic pollutants. Chem Eng J 379:122310
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AAM acknowledges the University of Sharjah support of competitive grants 160–2142-029-P and 150–2142-017-P.
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Javad Parambath and Fatima Abla: writing the original draft of the review. Mahreen Arooj: writing the calculations section. Ahmed A. Mohamed: editing the review.
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Parambath, J.B.M., Abla, F., Arooj, M. et al. Doping matters in carbon nanomaterial efficiency in environmental remediation. Environ Sci Pollut Res 30, 124921–124933 (2023). https://doi.org/10.1007/s11356-023-25147-w
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DOI: https://doi.org/10.1007/s11356-023-25147-w