Abstract
The treatment and recovery of pollutants in aquatic system is one of the greatest challenges for environmentalists throughout the world. In this study, solvent extraction of indium using phosphonium ionic liquid (Cyphos IL 104) as an extractant and its mathematical model was proposed for prediction of In(III) ion transport across a FSSLM (flat-sheet-supported liquid membrane). Solvent extraction experiments on indium have been carried out under various experimental conditions in order to assert some fundamental parameters using mathematical analysis for mass transfer process. Diffusion is the process which facilitates metal ion transport across liquid membrane, indicating the applicability of Fick’s law of diffusion in model formulation. The influence of different parameters like composition of diluent, feed acidity, and ligand concentration on In(III) ion transport rate has been reported. At different extractant concentrations, the modeling outputs and experimental indium extraction were observed to be in reasonably good agreement.
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References
Akama Y, Ito M (2000) Selective separation of cadmium from cobalt, copper, iron(III) and zinc by water based two phased system of tetra butyl ammonium bromide. Talanta 53:645–650. https://doi.org/10.1016/S0039-9140(00)00555-5
Akama Y, Suzuki S, Monobe Y (2016) Study on the adsorption and selective separation of indium from zinc with chelating cellulose. Cellulose Chem Technol 50:147–152. https://www.cellulosechemtechnol.ro/pdf/CCT1(2016)/p.147-152.pdf. Accessed 7 Dec 2022
Alguacil FJ (2017) Non-dispersive extraction of gold(III) with ionic liquid Cyphos IL101. Sep Purif Technol 179:72–76. https://doi.org/10.1016/j.seppur.2017.01.065
Alguacil FJ (2020) Liquid-liquid extraction of indium(III) from the HCl medium by ionic liquid A327H+Cl- and its use in a supported liquid membrane system. Molecules 25:5238. https://doi.org/10.3390/molecules25225238
Baczynska M, Regel-Rosocka M, Coll MT, Fortuny A, Sastre AM, Wisniewski M (2016) Transport of Zn(II), Fe(II), Fe(III) across polymer inclusion membranes (PIM) and flat sheet supported liquid membranes (SLM) containing phosphonium ionic liquids as metal ion carriers. Sep Sci Technol 51:2639–2648. https://doi.org/10.1080/01496395.2016.1174265
Barya MP, Kumar A, Thakur TK (2022) Utilization of constructed wetland for the removal of heavy metal through fly ash bricks manufactured using harvested plant biomass. Ecohydrology 15(4):e2424. https://doi.org/10.1002/eco.2424
Bonggotgetsakul YYN, Cattrall RW, Kolev SD (2016) Recovery of gold from aqua regia digested electronic scrap using a poly (vinylidene fluoride- co-hexa fluoropropene) (PVDF-HFP) based polymer inclusion membrane (PIM) containing Cyphos IL 104. J Membr Sci 514:274–281. https://doi.org/10.1016/j.memsci.2016.05.002
Cheng CY (2006) Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime. Hydrometallurgy 84:109–117. https://doi.org/10.1016/j.hydromet.2006.05.002
Cieszynska A, Wisniewski M (2012) Extractive recovery of palladium(II) from hydrochloric acid solutions with Cyphos IL 104. Hydrometallurgy 113–114:79–85. https://doi.org/10.1016/j.hydromet.2011.12.006
Cui L, Cheng F, Zhou J (2015) Behaviors and mechanism of iron extraction from chloride solutions using undiluted Cyphos IL 101. Ind Eng Chem Res 54:7534–7542. https://doi.org/10.1021/acs.iecr.5b01546
Danesi PR, Horwitz EP, Rickert PG (1983) Rate and mechanism of facilitated americium (III) transport through a supported liquid membrane containing a bifunctional organophosphorous mobile carrier. J Phys Chem A 87(23):4708–4715. https://doi.org/10.1021/j100246a033
Deferm C, de Voorde MV, Luyten J, Oosterhof H, Fransaer J, Binnemans K (2016) Purification of indium by solvent extraction with undiluted ionic liquids. Green Chem. 18:4116–4127. https://doi.org/10.1039/C6GC00586A
Dhiman S, Gupta B (2020a) Recovery of pure germanium oxide from Zener diodes using a recyclable ionic liquid Cyphos IL 104. J Environ Manage 276:111218. https://doi.org/10.1016/j.jenvman.2020.111218
Dhiman S, Gupta B (2020b) Cyphos IL 104 assisted extraction of indium and recycling of indium, tin and zinc from discarded LCD screen. Sep Purif Technol 237:116407. https://doi.org/10.1016/j.seppur.2019.116407
El-Nadi YA (2010) Effect of diluents on the extraction of praseodymium and samarium by Cyanex 923 from acidic nitrate medium. J Rare Earths 28:215–220. https://doi.org/10.1016/S1002-0721(09)60083-1
Fan S, Jia Q, Song N, Su R, Liao W (2010) Synergistic extraction study of indium from chloride medium by mixtures of sec-nonylphenoxy acetic acid and trialkyl amine. Sep Purif Technol 75:76–80. https://doi.org/10.1016/j.seppur.2010.07.015
Ferreira AF, Simoes PN, Ferreira AGM (2012) Quaternary phosphonium-based ionic liquids: thermal stability and heat capacity of the liquid phase. J Chem Thermodyn 45:16–27. https://doi.org/10.1016/j.jct.2011.08.019
Fraser KJ, MacFarlane DR (2009) Phosphonium-based ionic liquids: an overview. Aust J. Chem 62:309–321. https://www.publish.csiro.au/CH/CH08558. Accessed 7 Dec 2022
Haghighi HK, Irannajad M, Fortuny A, Sastre AM (2018) Mathematical modeling on non-dispersive extraction of germanium from aqueous solutions using Aliquat 336. Water Sci Technol 78:2489–2499. https://doi.org/10.2166/wst.2019.002
Iyer JN, Dhadke PM (2001) Liquid-liquid extraction and separation of gallium(III), indium(III), and thallium(III) by Cyanex 925. Sep Sci Technol 36:2773–2784. https://doi.org/10.1081/SS-100107225
Jahroni EZ, Bidari A, Assadi Y (2007) Dispersive liquid-liquid micro extraction combined with graphite furnance atomic absorption spectrometry ultra trace determination of cadimum in water samples. Anal Chem Acta 585:305–311. https://doi.org/10.1016/j.aca.2007.01.007
Jha AK, Jha MK, Kumari A, Sahu SK, Kumar V, Pandey BD (2013) Selective separation and recovery of cobalt from leach liquor of discarded Li-ion batteries using thiophosphinic extractant. Separ Purif Technol 104:160–166. https://doi.org/10.1016/j.seppur.2012.11.024
Jiang J, Liang D, Zhong Q (2011) Precipitation of indium using sodium tripolyphosphate. Hydrometallurgy 106:165–169. https://doi.org/10.1016/j.hydromet.2010.12.009
Kai C, Oshima T, Baba Y (2010) Synthesis of new extractants containing a carboxylic acid group and their extraction equilibria with indium(III), gallium(III) and zinc(II). Solvent Extr. Res. Dev. Jpn 17:175–185. https://doi.org/10.15261/serdj.17.175
Koter S, Szczepański P, Mateescu M, Nechifor G, Badalau L, Koter I (2013) Modeling of the cadmium transport through a bulk liquid membrane. Sep Purif Technol 107:135–143. https://doi.org/10.1016/j.seppur.2013.01.032
Kumar A, Gupta H (2020) Activated carbon from sawdust for naphthalene removal from contaminated water. Environ Technol Innov 20:101080. https://doi.org/10.1016/j.eti.2020.101080
Kumar A, Mishra S, Bakshi S, Upadhyay P, Thakur TK (2022a) Response of eutrophication and water quality drivers on greenhouse gas emissions in lakes of China: a critical analysis. Ecohydrology. https://doi.org/10.1002/eco.2483
Kumar A, Uoadhyay P, Prajapati SK (2022b) Impact of microplastics on riverine greenhouse gas emissions: a view point. Environ Sci Pollut Res. https://doi.org/10.1007/s11356-022-23929-2
Liu HM, Wu CC, Lin YH, Chiang CK (2009) Recovery of indium from etching wastewater using supercritical carbon dioxide extraction. J Hazard Mater 172:744–748. https://doi.org/10.1016/j.jhazmat.2009.07.098
Mishra RK, Rout PC, Sarangi K, Nathsarma KC (2011) Solvent extraction of Fe(III) from the chloride leach liquor of low grade iron ore tailings using Aliquat 336. Hydrometallurgy 108:93–99. https://doi.org/10.1016/j.hydromet.2011.03.003
Nayak S, Devi N (2017) Studies on extraction of gallium(III) from chloride solution using Cyphos IL 104 and its removal from photodiodes and red mud. Hydrometallurgy 171:191–197. https://doi.org/10.1016/j.hydromet.2017.04.016
Nayl AA (2010) Extraction and separation of Co(II) and Ni(II) from acidic sulfate solutions using Aliquat 336. J Hazard Mater 173:223–230. https://doi.org/10.1016/j.jhazmat.2009.08.072
Nguyen TH, Lee MS (2019) A review on separation of gallium and indium from leach liquors by solvent extraction and ion exchange. Miner Process Extr Metall Rev 40:278–291. https://doi.org/10.1080/08827508.2018.1538987
Nusen S, Zhu Z, Chairuangsri T, Cheng CY (2015) Recovery of germanium from synthetic leach solution of zinc refinery residues by synergistic solvent extraction using LIX 63 and Ionquest 801. Hydrometallurgy 151:122–132. https://doi.org/10.1016/j.hydromet.2014.11.016
Padhan E, Sarangi K (2014) Separation of molybdenum and cobalt from spent catalyst using Cyanex 272 and Cyanex 301. Int J Miner Process 127:52–61. https://doi.org/10.1016/j.minpro.2014.01.003
Paiva AP (2001) Recovery of indium from aqueous solutions by solvent extraction. Sep Sci Technol 36:1395–1419. https://doi.org/10.1081/SS-100103878
Pospiech B (2015) Studies on extraction and permeation of cadmium(II) using Cyphos IL 104 as selective extractant and ion carrier. Hydrometallurgy 154:88–94. https://doi.org/10.1016/j.hydromet.2015.04.007
Ramkumar J, Chandramouleeswaran S (2015) A perceptive on bulk liquid membrane: a brief review. Indian J. Adv. Chem. Sci. 3:293–298. http://ijacskros.com/artcles/IJACS-M156.pdf. Accessed 7 Dec 2022
Regel-Rosocka M, Nowak L, Wisniewski M (2012) Removal of zinc(II) and iron ions from chloride solutions with phosphonium ionic liquids. Sep Purif Technol 97:158–163. https://doi.org/10.1016/j.seppur.2012.01.035
Rzelewska M, Wisniewski M, Regel-Rosocka M (2017) Effect of composition and ageing of chloride solutions on extraction of Rh(III) and Ru(III) with phosphonium ionic liquids Cyphos IL 101 and IL 104. Sep Sci Technol 1–12. https://doi.org/10.1080/01496395.2017.1295996
Sato T, Sato M (1992) Liquid-liquid extraction of indium (III) from aqueous acid solutions by acid organophosphorus compounds. Hydrometallurgy 30:367–383. https://doi.org/10.1016/0304-386X(92)90094-G
Silveira AVM, Fuchs MS, Pinheiro DK, Tanabe EH, Bertuol DA (2015) Recovery of indium from LCD screens of discarded cell phones. Waste Manage 45:334–342. https://doi.org/10.1016/j.wasman.2015.04.007
Singh S, Kumar A, Gupta H (2020) Activated banana peel carbon: a potential adsorbent for Rhodamine B decontamination from aqueous system. Appl Water Sci 10:185. https://doi.org/10.1007/s13201-020-01274-4
Sriram S, Mohapatra PK, Pandey AK, Manchanda VK, Badheka LP (2000) Facilitated transport of americium (III) from nitric acid media using dimethyldibutyltetradecyl-1, 3-malonamide. J Membr Sci 177(1–2):163–175. https://doi.org/10.1016/S0376-7388(00)00474-9
Teramoto M, Kariya A, Yonehara T, Tokunaga M, Ohnishi N, Matsuyama H, Miyake Y (1993) Separation of gallium and indium by supported liquid membranes containing 2-bromodecanoic acid as carrier: design of supported liquid membrane module based on batch permeation experiments. Hydrometallurgy 33:1–15. https://doi.org/10.1016/0304-386X(93)90002-U
Tsai HS, Tsai TH (2012) Extraction equilibrium of indium(III) from nitric acid solutions by di(2-ethylhexyl)phosphoric acid dissolved in kerosene. Molecules 17:408–419. https://doi.org/10.3390/molecules17010408
Tsai HS, Tsai TH (2013) Extraction equilibrium of gallium(III) from nitric acid solutions by di(2-ethylhexyl)phosphoric acid dissolved in kerosene. Asian J Chem 25:1429–1433. https://doi.org/10.14233/ajchem.2013.13055
Virolainen S, Ibana D, Paatero E (2011) Recovery of indium from indium tin oxide by solvent extraction. Hydrometallurgy 107:56–61. https://doi.org/10.1016/j.hydromet.2011.01.005
Wilson AM, Bailey PJ, Tasker PA, Turkington JR, Grant RA, Love JB (2014) Solvent extraction: the coordination chemistry behind extractive metallurgy. Chem Soc Rev 123–134. https://doi.org/10.1039/C3CS60275C
Yen FC, Chang TC, Laohaprapanon S, Chen YL (2016) Recovery of indium from LCD waste by solvent extraction and the supported liquid membrane with strip dispersion using D2EHPA as the extractant. Solvent Extr. Res. Dev. Jpn 23:63–73. https://doi.org/10.15261/serdj.23.63
Zantea G, Boltoeva M, Masmoudi A, Barillon R, Trébouet D (2020) Supported ionic liquid and polymer inclusion membranes for metal separation. Sep Purif Rev 51:100–116. https://doi.org/10.1080/15422119.2020.1846564
Zhu Z, Yoko P, Cheng CY (2017) Recovery of cobalt and manganese from nickel laterite leach solutions containing chloride by solvent extraction using Cyphos IL 101. Hydrometallurgy 169:213–218. https://doi.org/10.1016/j.hydromet.2017.02.002
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The authors Dr. Rohit Kumar and Dr. Himanshu Gupta would like to thank IFTM University administration for providing necessary facilities to carry out the present study.
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Rohit Kumar, Soniya Dhiman, and Himanshu Gupta. The first draft of the manuscript was written by Soniya Dhiman and Rohit Kumar, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Kumar, R., Dhiman, S. & Gupta, H. Indium extraction from nitrate medium using Cyphos ionic liquid 104 and its mathematical modeling. Environ Sci Pollut Res 30, 107341–107349 (2023). https://doi.org/10.1007/s11356-022-24936-z
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DOI: https://doi.org/10.1007/s11356-022-24936-z