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CO2 gas sensing properties of Na3BiO4-Bi2O3 mixed oxide nanostructures

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Abstract

In this paper, we report Na3BiO4-Bi2O3 mixed oxide nanoplates for carbon dioxide gas sensing applications. These nanoplates have been synthesized using electrochemical deposition with potentiostatic mode on ITO substrate and characterized using scanning electron microscopy (SEM) and X-ray diffraction (XRD) to analyze their surface morphology and structure. SEM study shows the presence of horizontally aligned nanoplates stacked on top of one another (thickness 40 to 75 nm). XRD pattern shows the presence of monoclinic Na3BiO4 and Bi2O3. The gas percentage response is evaluated by measuring the change in electrical resistance of the nanoplates in the presence of carbon dioxide for different pressures at 50 °C, 75 °C, and 100 °C. Percentage response of more than 100% is seen at 30 psi gas pressure which increases to 277% at 90 psi at 100C.

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The authors confirm that the data and materials used in this study are available on request.

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Acknowledgements

The authors are thankful to the UGC DAE CSR, Indore (CSR-IC/CRS-73/2014/435) for providing financial support. We are also thankful to MRC, MNIT Jaipur for providing characterization facilities.

Funding

This study was financially supported by the UGC DAE CSR, Indore (CSR-IC/CRS- 73/2014/435).

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Contributions

Sandeep Gupta: sample preparation, data acquisition, and writing the draft manuscript.

Anoop Mampazhasseri Divakaran: gas sensing set-up designing and XRD data analysis

Kamlendra Awasthi: supervision of data analysis

Manoj Kumar: conceptualization of research problem and supervision of experiments

Corresponding authors

Correspondence to Sandeep Gupta or Manoj Kumar.

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Gupta, S., Divakaran, A.M., Awasthi, K. et al. CO2 gas sensing properties of Na3BiO4-Bi2O3 mixed oxide nanostructures. Environ Sci Pollut Res 30, 71933–71939 (2023). https://doi.org/10.1007/s11356-022-21506-1

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