Abstract
The heterogeneous photocatalysis is known to provide significant degradation and mineralization of emerging contaminants including antibiotics. For this, nanosized Mg0.3Zn0.7O (MZO) was prepared by nitrate route to be used as photocatalyst. The single-phase was confirmed by X-ray diffraction with a crystallite size of 33 nm. The morphology was visualized by scanning electron microscope/energy-dispersive X-ray analysis. The physicochemical properties were studied by the FTIR, XPS, and optical analyses. The diffuse reflectance gives a direct forbidden band of 3.26 eV. The electrochemical characterization showed an n-type semiconductor with a flat band of − 0.56 VAg/AgCl. The photodegradation of Cefixime (CFX) was carried out under solar light; the operating parameters such as the catalyst dose, solution pH, and initial CFX concentration (Co) were optimized. The best performance occurs at neutral pH ~ 6 within 4 h with an abatement of 94% for an initial CFX concentration of 5 mg/L and MZO dose of 0.75 g/L. The photodegradation follows a first-order kinetic with an apparent rate constant of 0.012 min-1. The effects of scavenging agents indicated the dominant role of hydroxyl •OH followed by the holes (h+). The results showed the potentiality of MZO as an environmentally friendly photocatalyst for CFX photodegradation.
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References
Akika FZ, Benamira M, Lahmar H et al (2020) Structural and optical properties of Cu-doped ZnAl2O4 and its application as photocatalyst for Cr(VI) reduction under sunlight. Surf Interfaces 18:100406. https://doi.org/10.1016/j.surfin.2019.100406
Asadi-Ghalhari M, Mostafaloo R, Ghafouri N et al (2021) Removal of Cefixime from aqueous solutions via proxy electrocoagulation: modeling and optimization by response surface methodology. React Kinet Mech Catal. https://doi.org/10.1007/s11144-021-02055-z
Baaloudj O, Assadi AA, Azizi M, et al (2021a) Synthesis and characterization of ZnBi2O4 nanoparticles: photocatalytic performance for antibiotic removal under different light sources. https://doi.org/10.3390/app11093975
Baaloudj O, Assadi I, Nasrallah N et al (2021b) Simultaneous removal of antibiotics and inactivation of antibiotic-resistant bacteria by photocatalysis: a review. J Water Process Eng 42:102089. https://doi.org/10.1016/j.jwpe.2021.102089
Baaloudj O, Nasrallah N, Bouallouche R et al (2022) High efficient Cefixime removal from water by the sillenite Bi12TiO20: photocatalytic mechanism and degradation pathway. J Clean Prod 330:129934. https://doi.org/10.1016/j.jclepro.2021.129934
Baaloudj O, Nasrallah N, Kenfoud H, et al (2021c) Application of Bi12ZnO20 sillenite as an efficient photocatalyst for wastewater treatment: removal of both organic and inorganic compounds. Materials 1–17. https://doi.org/10.3390/ma14185409
Badawi AK, Ismail B, Baaloudj O, Abdalla KZ (2022) Advanced wastewater treatment process using algal photo-bioreactor associated with dissolved-air flotation system: a pilot-scale demonstration. J Water Process Eng 46:102565. https://doi.org/10.1016/j.jwpe.2022.102565
Badi N, Khasim S, Pasha A (2019) Synthesis and characterization of urea-doped MgZnO nanoparticles for electronic applications. Appl Phys A 1–8. https://doi.org/10.1007/s00339-019-3149-9
Bai J, Ye X, Jia J et al (2017) Phosphorus sorption-desorption and effects of temperature, pH and salinity on phosphorus sorption in marsh soils from coastal wetlands with different flooding conditions. Chemosphere 188:677–688. https://doi.org/10.1016/j.chemosphere.2017.08.117
Balakrishnan G, Velavan R, Batoo KM, Raslan EH (2020) Results in physics microstructure, optical and photocatalytic properties of MgO nanoparticles. Results in Physics 16:103013. https://doi.org/10.1016/j.rinp.2020.103013
Benamira M, Lahmar H, Messaadia L et al (2019) Hydrogen production on the new hetero-system Pr2NiO4/SnO2 under visible light irradiation. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2019.11.064
Bhattacharya P, Das RR, Katiyar RS (2003) Fabrication of stable wide-band-gap ZnO/MgO multilayer thin films. Appl Phys Lett 83:2010–2012. https://doi.org/10.1063/1.1609250
Bourkeb K, Baaloudj O (2021) Facile electrodeposition of ZnO on graphitic substrate for photocatalytic application: degradation of antibiotic in a continuous stirred-tank reactor. J Solid State Electrochem. https://doi.org/10.1007/s10008-021-05045-2
Brahimi B, Kenfoud H, Benrighi Y, Baaloudj O (2021a) Structural and optical properties of Bi12NiO19 sillenite crystals: application for the removal of Basic Blue 41 from wastewater. Photochem 1:319–329. https://doi.org/10.3390/photochem1030020
Brahimi B, Mekatel E, Mellal M et al (2021b) Enhanced photodegradation of acid orange 61 by the novel hetero-junction CoFe2O4/AgCl. Opt Mater 121:111576. https://doi.org/10.1016/j.optmat.2021.111576
Brahimi B, Mekatel E, Mellal M, Trari M (2021c) Synthesis of the hexaferrite semiconductor SrFe12O19 and its application in the photodegradation of Basic Red 46. J Mater Sci: Mater Electron 32:17780–17790. https://doi.org/10.1007/s10854-021-06314-6
Chabane L, Zebbar N, Kechouane M et al (2016) Al-doped and in-doped ZnO thin films in heterojunctions with silicon. Thin Solid Films 605:57–63. https://doi.org/10.1016/j.tsf.2015.10.063
Dillert R, Taffa DH, Wark M, et al (2015) Research update: photoelectrochemical water splitting and photocatalytic hydrogen production using ferrites (MFe2O4) under visible light irradiation. APL Mater 3. https://doi.org/10.1063/1.4931763
Douafer S, Lahmar H, Benamira M et al (2019) Chromate reduction on the novel hetero-system LiMn2O4/SnO2 catalyst under solar light irradiation. Surfaces and Interfaces 17:100372. https://doi.org/10.1016/j.surfin.2019.100372
Elhadj M, Samira A, Mohamed T et al (2019) Removal of Basic Red 46 dye from aqueous solution by adsorption and photocatalysis. Sep Sci Technol 168:1–19. https://doi.org/10.1080/01496395.2019.1577896
Etacheri V, Roshan R, Kumar V (2012) Mg-doped ZnO nanoparticles for efficient sunlight-driven photocatalysis. ACS Appl Mater Interfaces 4:2717–2725. https://doi.org/10.1021/am300359h
Gao H, Yang H, Wang S (2018) Comparative study on optical and electrochemical properties of MFe2O4 (M = Mg, Ca, Ba) nanoparticles. Trans Indian Ceram Soc 77:150–160. https://doi.org/10.1080/0371750X.2018.1512381
Gaya UI, Abdullah AH (2008) Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. J Photochem Photobiol, C 9:1–12. https://doi.org/10.1016/j.jphotochemrev.2007.12.003
Ghauch A, Tuqan A, Assi HA (2009) Antibiotic removal from water: elimination of amoxicillin and ampicillin by microscale and nanoscale iron particles. Environ Pollut 157:1626–1635. https://doi.org/10.1016/j.envpol.2008.12.024
He W, Wang J, Hu W (2021) Preparation of MgxZn1-xO resistive switching film by sol-gel method and its corrosion behavior in 3.5 wt% NaCl solution. Int J Electrochem Sci 16:1–24. https://doi.org/10.20964/2021.02.45
Jasaitis D, Beganskiene A, Senvaitiene J et al (2011) Sol-gel synthesis and characterization of cobalt chromium spinel CoCr 2O 4. Chemija 22:125–130. https://doi.org/10.1039/c3ce41663a
Ji R, Ma M, He Y et al (2018) Improved corrosion resistance of Al2O3 ceramic coatings on AZ31 magnesium alloy fabricated through cathode plasma electrolytic deposition combined with surface pore-sealing treatment. Ceram Int 44:15192–15199. https://doi.org/10.1016/j.ceramint.2018.05.159
Kebir M, Boudjemaa A, Bachari K (2015) Materials science in semiconductor processing enhancement photo-catalytic degradation of benzoic acid using the heterosystem NiCo2O4/ZnO. Mater Sci Semicond Process 39:300–307. https://doi.org/10.1016/j.mssp.2015.05.036
Kenfoud H, Baaloudj O, Nasrallah N et al (2021a) Structural and electrochemical characterizations of Bi12CoO20 sillenite crystals: degradation and reduction of organic and inorganic pollutants. J Mater Sci: Mater Electron. https://doi.org/10.1007/s10854-021-06194-w
Kenfoud H, Nasrallah N, Baaloudj O et al (2022a) Enhanced photocatalytic reduction of Cr(VI) by the novel hetero-system BaFe2O4/SnO2. J Phys Chem Solids 160:110315. https://doi.org/10.1016/j.jpcs.2021.110315
Kenfoud H, Nasrallah N, Baaloudj O et al (2020) Photocatalytic reduction of Cr(VI) onto the spinel CaFe2O4 nanoparticles. Optik 223:165610. https://doi.org/10.1016/j.ijleo.2020.165610
Kenfoud H, Nasrallah N, Baaloudj O, et al (2022b) Opto-electrochemical characteristics of synthesized BaFe2O4 nanocomposites: photocatalytic degradation and hydrogen generation investigation. Int J Hydrogen Energy 1–13. https://doi.org/10.1016/j.ijhydene.2022b.01.232
Kenfoud H, Nasrallah N, Meziani D, Trari M (2021b) Photoelectrochemical study of the spinel CaFe2O4 nanostructure: application to Basic Blue 41 oxidation under solar light. https://doi.org/10.1007/s10008-021-04952-8
Kilinç N, Arda L, Öztürk S, Öztürk ZZ (2010) Structure and electrical properties of Mg-doped ZnO nanoparticles. Cryst Res Technol 45:529–538. https://doi.org/10.1002/crat.200900662
Kowsari E (2017) Carbon-based nanocomposites for visible light-induced photocatalysis. 203–249. https://doi.org/10.1007/978-3-319-62446-4_8
Kumar R, Barakat MA, Al-Mur BA et al (2020) Photocatalytic degradation of cefoxitin sodium antibiotic using novel BN/CdAl2O4 composite. J Clean Prod 246:119076. https://doi.org/10.1016/j.jclepro.2019.119076
Liu HY, Hsu PH (2020) Investigation and fabrication of p-Si/N-Mg0.3Zn0.7O: In self-powered heterojunction photodiodes by mist atmospheric pressure chemical vapor deposition. IEEE Sens J 20:12702–12708. https://doi.org/10.1109/JSEN.2020.3001575
Malato S, Fernández-Ibáñez P, Maldonado MI et al (2009) Decontamination and disinfection of water by solar photocatalysis: recent overview and trends. Catal Today 147:1–59. https://doi.org/10.1016/j.cattod.2009.06.018
Mekatel EH, Boumediene TH, Dahdouh N, et al (2021) Removal of Maxilon Red dye by adsorption and photocatalysis: optimum conditions, equilibrium, and kinetic studies. https://doi.org/10.30492/ijcce.2019.37245
Mekatel H, Amokrane S, Bellal B et al (2012) Photocatalytic reduction of Cr(VI) on nanosized Fe2O3 supported on natural Algerian clay: characteristics, kinetic and thermodynamic study. Chem Eng J 200–202:611–618. https://doi.org/10.1016/j.cej.2012.06.121
Rajeshwar K, Osugi ME, Chanmanee W et al (2008) Heterogeneous photocatalytic treatment of organic dyes in air and aqueous media. J Photochem Photobiol, C 9:171–192. https://doi.org/10.1016/j.jphotochemrev.2008.09.001
Rehman S, Ullah R, Butt AM, Gohar ND (2009) Strategies of making TiO2 and ZnO visible light active. J Hazard Mater 170:560–569. https://doi.org/10.1016/j.jhazmat.2009.05.064
Saadati F, Keramati N, Ghazi MM (2016) Influence of parameters on the photocatalytic degradation of tetracycline in wastewater: a review. Crit Rev Environ Sci Technol 46:757–782
Salina M, Mamat MH, Bakar SA et al (2011) Highly conductive vertically aligned carbon nanotubes grown on Mg 0.3Zn0.7O thin film template using thermal chemical vapour deposition method. Jpn J Appl Phys 50:5–10. https://doi.org/10.1143/JJAP.50.06GE02
Schmidt-Grund R, Carstens A, Rheinländer B et al (2006) Refractive indices and band-gap properties of rocksalt MgxZn1-xO (0.68≤x≤1). J Appl Phys 99:7. https://doi.org/10.1063/1.2205350
Sheydaei M, Reza H, Shiadeh K et al (2018) Preparation of nano N-TiO2/graphene oxide/titan grid sheets for visible light assisted photocatalytic ozonation of ce fi xime. Chem Eng J 353:138–146. https://doi.org/10.1016/j.cej.2018.07.089
Singh J, Juneja S, Palsaniya S et al (2019) Evidence of oxygen defects mediated enhanced photocatalytic and antibacterial performance of ZnO nanorods. Colloids Surf, B 184:110541. https://doi.org/10.1016/j.colsurfb.2019.110541
Sowri Babu K, Ramachandra Reddy A, Sujatha C et al (2013) Synthesis and optical characterization of porous ZnO. J Adv Ceram 2:260–265. https://doi.org/10.1007/s40145-013-0069-6
Thein MT, Pung SY, Aziz A, Itoh M (2016) Effect of Ni coupling on the photoluminescence property and photocatalytic activity of ZnO nanorods. J Taiwan Inst Chem Eng 61:156–165. https://doi.org/10.1016/j.jtice.2015.11.024
Venieri D, Gounaki I, Bikouvaraki M et al (2017) Solar photocatalysis as disinfection technique: inactivation of Klebsiella pneumoniae in sewage and investigation of changes in antibiotic resistance profile. J Environ Manage 195:140–147. https://doi.org/10.1016/j.jenvman.2016.06.009
Zhou Z, Liu X, Sun K et al (2019) Persulfate-based advanced oxidation processes (AOPs) for organic-contaminated soil remediation: a review. Chem Eng J 372:836–851. https://doi.org/10.1016/j.cej.2019.04.213
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This study was financially supported by both the Faculties of Mechanical Engineering and Process Engineering and Chemistry (USTHB, Algiers).
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Billal Brahimi, writing—original draft preparation; Elhadj Mekatel, writing—review and editing; Hamza Kenfoud, visualization; Salah Eddine Berrabah, investigation; Mohamed Trari, supervision.
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Brahimi, B., Mekatel, E., Kenfoud, H. et al. Efficient removal of the antibiotic Cefixime on Mg0.3Zn0.7O under solar light: kinetic and mechanism studies. Environ Sci Pollut Res 29, 75512–75524 (2022). https://doi.org/10.1007/s11356-022-20626-y
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DOI: https://doi.org/10.1007/s11356-022-20626-y