Abstract
The increasing rare earth elements’ (REE) demand to meet the market request and the current political scenario show that it is essential to find good solutions to recover these elements from waste (both industrial and mining). Zeolites are microporous materials with high cation exchange capacity, up to now only little investigated for REE recycle. Here, we propose the use of NH4+-exchanged zeolite L for Ce recovery from a very diluted solution (0.002 M), mimicking the Ce3+ concentration of the liquors deriving from the leaching of spent catalysts. The aim of this work is twofold: (i) to investigate the exploitability of zeolite L as cation exchanger in the Ce recovery; and (ii) to determine the best working conditions. The investigated process consists of a coupled cation exchange: (1) in the first exchange the NH4+ cations — present in the zeolite porosities — are exchanged with the Ce3+ ions in the solution; and (2) in the second experiment, the Ce3+ trapped into the zeolite is recovered through a further exchange with NH4. The best working conditions for Ce3+ exchange of NH4-zeolite L are: batch system, liquid/solid ratio equal to 90 mL/g and 180 mL/g, 24 h of contact at 25 °C. The resulting Ce adsorption capacity (qt) is equal to ~25 mg/g and ~39 mg/g and the removal efficiency 100% and 77% for the two tested liquid/solid ratios, respectively. The kinetics was proved to be fast and consistent with industrial timing; no energy cost for temperature setting is required; and the acid pH (~4) of the solutions does not affect the zeolite structure stability and its exchange performance. It has been demonstrated that the zeolite framework is not affected by the exchange so that the same absorbent material can be employed many times.
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References
Akbas YA, Yusan S (2020) Development and characterization of non-treated and chemically modified olive pomace biosorbents to remove Ce(III) ions from aqueous solutions. J. Radioanal. Nucl. Chem. 323:763–772
Bacakova L, Vandrovcova M, Kopova I, Jirka I (2018) Applications of zeolites in biotechnology and medicine - a review. Biomat. Sci. 6:974–989
Baerlocher C, McCusker LB (n.d.) Database of zeolite structures. http://www.iza-structure.org/databases/. Accessed 2021
Barros O, Costa L, Costa F, Lago A, Rocha V, Vipotnik Z, Silva B, Tavares T (2019) Recovery of rare earth elements from wastewater towards a circular economy. Molecules 24:1005
Binnemans K, Jones PT, Blanpain B, Van Gerven T, Yang YX, Walton A, Buchert M (2013) Recycling of rare earths: a critical review. J Clean Prod. 51:1–22
Binnemans K, Jones PT, Müller T, Yurramendi L (2018) Rare earths and the balance problem: how to deal with changing markets? J Sustain Metall 4:126–146
Borra CR, Vlugt TJH, Yang YX, Offerman SE (2018) Recovery of cerium from glass polishing waste: a critical review. Metals 8:801
Breck DW (1984) Zeolite Molecular sieves, 2nd edition. Krieger, Malabar (FL) 529-592 pp
Calzaferri G, Huber S, Maas H, Minkowski C (2003) Host-guest antenna materials. Angew Chem Int Ed 42:3732–3758
Čejka J, Corma A, Zones S (2010) Zeolite and catalysis: synthesis, reactions and applications. Wyley-YCH, Weinheim
Chang TM, Dang LX (2003) On rotational dynamics of an NH4+ ion in water. Chem Phys 118:8813–8820
Charalampides G, Vatalis KI, Apostoplos B, Ploutarch-Nikolas B (2015) Rare earth elements: industrial applications and economic dependency of Europe. Procedia Econ Financ 24:126–135
Confalonieri G, Ryzhikov A, Arletti R, Nouali H, Quartieri S, Daou TJ, Patarin J (2018) Intrusion-extrusion of electrolyte aqueous solutions in pure silica chabazite by in situ high pressure synchrotron X-ray powder diffraction. J Phys Chem C 122:28001–28012
Confalonieri G, Daou TJ, Nouali H, Arletti R, Ryzhikov A (2020) Energetic performance of pure silica zeolites under high-pressure intrusion of LiCl aqueous solutions: an overview. Molecules 25:2145
Confalonieri G, Vezzalini G, Quattrini F, Quartieri S, Dejoie C, Arletti R (2021) Ce-exchange capacity of zeolite L in different cationic forms: a structural investigation. J Appl Crystallogr 54:1766–1774
Corma A (2003) State of the art and future challenges of zeolites as catalysts. J Catal 216:298–312
Coudert FX, Kohen D (2017) Molecular insight into CO2 “Trapdoor” adsorption in zeolite Na-RHO. Chem Mater 29:2724–2730
de Aquino TF, Estevam ST, Viola VO, Marques CRM, Zancan FL, Vasconcelos LB, Riella HG, Pires MJR, Morales-Ospino R, Torres AEB, Bastos-Neto M, Cavalcante CL (2020) CO2 adsorption capacity of zeolites synthesized from coal fly ashes. Fuel 276:118143
de Farias ABV, da Costa TB, da Silva MGC, Vieira MGA (2021) Cerium recovery from aqueous solutions by bio/adsorption: a review in a circular economy context. J Clean Prod 326:129395
Duplouy L (2016) Preliminary investigation of rare earth elements ion exchange on zeolites. Dissertation University of Helsinki, Université de Lille
Eroglu N, Emekci M, Athanassiou CG (2017) Applications of natural zeolites on agriculture and food production. J Sci Food Agric 97:3487–3499
Eroshenko V, Regis RC, Soulard M, Patarin J (2001) Energetics: a new field of applications for hydrophobic zeolites. J Am Chem Soc 123:8129–8130
Fabbiani M, Confalonieri G, Morandi S, Arletti R, Quartieri S, Santoro M, Di Renzo F, Haines J, Fantini R, Tabacchi G, Fois E, Vezzalini G, Ricchiardi G, Martra G (2021) Steering polymer growth by molding nanochannels: 1,5-hexadiene polymerization in high silica mordenite. Microporous and Mesoporous Mater 311:110728
Faghihian H, Amini MK, Nezamzadeh AR (2005) Cerium uptake by zeolite A synthesized from natural clinoptilolite tuffs. J Radioanal Nucl Chem 264:577–582
Gao YQ, Zhang SM, Zhao KY, Wang ZW, Xu SX, Liang ZP, Wu K (2015) Adsorption of La3+ and Ce3+ by poly-gamma-glutamic acid crosslinked with polyvinyl alcohol. J Rare Earths 33:884–891
Gigli L, Arletti R, Tabacchi G, Fabbiani M, Vitillo JG, Martra G, Devaux A, Miletto I, Quartieri S, Calzaferri G, Fois E (2018) Structure and host-guest interactions of perylene-diimide dyes in zeolite L nanochannels. J Phys Chem C 122:3401–3418
Gorte RJ (2010) Ceria in catalysis: from automotive applications to the water gas shift reaction. AIChE 56:1126–1135
Gottardi G, Galli E (1985) Natural zeolites. Minerals, Rocks and Mountains. Springer-Verlag Berlin Heidelberg
Haque N, Hughes A, Lim S, Vernon C (2014) Rare earth elements: overview of mining, mineralogy, uses, sustainability and environmental impact. Resources 3:614–635
Hong SH, Jang MS, Cho SJ, Ahn WS (2014) Chabazite and zeolite 13X for CO2 capture under high pressure and moderate temperature conditions. Chem Commun 50:4927–4930
Ilyas S, Kim H, Srivastava RR (2021) Hydrometallurgical recycling of rare earth metal-cerium from bio-processed residual waste of exhausted automobile catalysts. JOM 73:19–26
Innocenzi V, Ferella F, De Michelis I, Veglio F (2015) Treatment of fluid catalytic cracking spent catalysts to recover lanthanum and cerium: comparison between selective precipitation and solvent extraction. J Ind Eng Chem 24:92–97
Krajnc A, Varlec J, Mazaj M, Ristic A, Logar NZ, Mali G (2017) Superior performance of microporous aluminophosphate with LTA topology in solar-energy storage and heat reallocation. Adv Energy Mater 7:1601815
LeVan MD, Carta G, Yon CMRHP, D.W. Green (Eds.) (1997): Adsorption and ion exchange. In: Perry RH , Green DW (Editors), Perry’s chemical engineering handbook, 7th edition. McGraw-Hill, New York
Lutz OMD, Hofer TS, Randolf BR, Rode BM (2012) Computational study of the cerium(III) ion in aqueous environment. Chem Phy. Lett. 539:50–53
Mancheri NA, Sprecher B, Bailey G, Ge JP, Tukker A (2019) Effect of Chinese policies on rare earth supply chain resilience. Resour Conserv Recycl 142:101–112
Maruthapandi M, Luong JHT, Gedanken A (2020) Nitrogen-enriched porous benzimidazole-linked polymeric network for the adsorption of La (III), Ce (III), and Nd (III). J Phys Chem C 124:6206–6214
Mendez-Arguello B, Lira-Saldivar RH (2019) Potential use of zeolite on sustainable agriculture for the new green revolution. Ecosistemas Y Recursos Agropecuarios 6:191–193
Meshram P, Abhilash (2020) Recovery and recycling of cerium from primary and secondary resources- a critical review. Miner Process Extr Metall Rev 41:279–310
Mosai AK, Chimuka L, Cukrowska EM, Kotze IA, Tutu H (2019) The recovery of rare earth elements (REEs) from aqueous solutions using natural zeolite and bentonite. Water Air Soil Pollut 230:188
Nakhli SAA, Delkash M, Bakhshayesh BE, Kazemian H (2017) Application of zeolites for sustainable agriculture: a review on water and nutrient retention. Water Air Soil Pollut 228:464
Porvali A, Agarwal V, Lundstrom M (2020) REE(III) recovery from spent NiMH batteries as REE double sulfates and their simultaneous hydrolysis and wet-oxidation. Waste Manage 107:66–73
Ramesh K, Reddy DD, Biswas AK, Rao AS (2011) Zeolites and their potential uses in agriculture. In: Advances in agronomy. Vol 113, pp 215-236
Royen H, Fortkamp U (2016) Rare earth elements - purification, separation and recycling. Report of IVL Swedish Environmental Research Institute 2016
Sadovsky D, Brenner A, Astrachan B, Asaf B, Gonen R (2016) Biosorption potential of cerium ions using Spirulina biomass. J Rare Earths 34:644–652
Soulard M, Patarin J (2011): Process for high-pressure energy storage by solvation/desolvation and associated storage device. Patent, France
Stylianou MA (2012) Natural zeolites in medicine. In: Handbook of natural zeolites, Bentham Science Publishers pp 317-334
Suli LM, Ibrahim WHW, Aziz BA, Deraman MR, Ismail NA (2017) A review of rare earth mineral processing technology. Chem Eng Res Bull 19:20
Tunsu C, Ekberg C, Foreman M, Retegan T (2016) Targeting fluorescent lamp waste for the recovery of cerium, lanthanum, europium, gadolinium, terbium and yttrium. Miner Process. Extr. Metall. 125:199–203
Vijayaraghavan K, Sathishkumar M, Balasubramanian R (2010) Biosorption of lanthanum, cerium, europium, and ytterbium by a brown marine alga, turbinaria conoides. Ind Eng Chem Res 49:4405–4411
Wang F, Zhu YF, Wang AQ (2020) Preparation of carboxymethyl cellulose-g-poly(acrylamide)/attapulgite porous monolith with an eco-friendly pickering-MIPE template for Ce(III) and Gd(III) adsorption. Frontiers in Chemistry 8:398
Yousefi T, Yavarpour S, Mousavi SH, Torab-Mostaedi M, Davarkhah R, Mobtaker HG (2015) Effective removal of Ce(III) and Pb(II) by new hybrid nano-material: HnPMo12O40@Fe(III)(x)Sn(II)(y)Sn(IV)(1-x-y). Process Saf Environ Prot 98:211–220
Yurramendi L, Gijsemans L, Forte F, Aldana JL, del Rio C, Binnemans K (2019) Enhancing rare-earth recovery from lamp phosphor waste. Hydrometallurgy 187:38–44
Zhao L, Azhar MR, Li XJ, Duan XG, Sun HQ, Wang SB, Fang XC (2019) Adsorption of cerium (III) by HKUST-1 metal-organic framework from aqueous solution. J Colloid Interface Sci 542:421–428
Zhao ZX, Qiu ZF, Yang J, Ma BT, Li Z, Lu SG, Xu YY, Cao LM, Zhang W (2020) Recovery of rare earth element cerium from spent automotive exhaust catalysts using a novel method. Waste and Biomass Valorization 11:4967–4976
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The authors thank Gianluca Malavasi and Lorenzo Tassi for the laboratory equipment and Massimo Tonelli, Monica Malavasi, Monica Vaccari, Simona Bigi and Michelangelo Polisi for their technical support.
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All the authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Giorgia Confalonieri, Vittorio Gozzoli and Laura Maletti. The first draft of the manuscript was written by Giorgia Confalonieri, and all the authors commented on the previous versions of the manuscript. All the authors read and approved the final manuscript.
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Confalonieri, G., Vezzalini, G., Maletti, L. et al. Ion exchange capacity of synthetic zeolite L: a promising way for cerium recovery. Environ Sci Pollut Res 29, 65176–65184 (2022). https://doi.org/10.1007/s11356-022-20429-1
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DOI: https://doi.org/10.1007/s11356-022-20429-1