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Synthesis and characterization of solid-state Fe-exchanged nano-bentonite and evaluation of methyl orange adsorption

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Abstract

A new adsorbent was synthesized using ion-exchange between iron salts and bentonite modified with acetyl trimethylammonium bromide (CTAB) in the solid phase. Ion-exchange was performed in the solid state at a temperature of 100 °C for 2 min. Various analyses such as X-ray diffraction (XRD), scanning electron microscopy (SEM), porosity measurement (BET), infrared Fourier transform (FT-IR), transmission electron microscopy (TEM), X-ray energy diffraction (EDX), and thermal weighing (TGA) were used to characterize the synthesized nano-adsorbents. Under optimal conditions (pH = 7, time 60 min, concentration of dye solution 150 ppm, and amount of nano-adsorbent 0.75 g/l), the modified nano-adsorbent absorbed 73% of the methyl orange (MO) dye. Adsorption isotherm studies and kinetic model showed that the pseudo-second-order model and Langmuir equation agree with the obtained results. After three reductions of the modified nano-adsorbent in the photo-Fenton process, the dye absorption percentage was 69.50%.

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Mohaghegh Ardabili, P. O. Box, 56199-11367, Ardabil, Iran

    Nahid Hajipour, Mohammad Ghorbanpour & Majid Safajou-jahankhanemlou

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  1. Nahid Hajipour
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  2. Mohammad Ghorbanpour
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  3. Majid Safajou-jahankhanemlou
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N.H., M.G., and M.S. contributed to the design and implementation of the research, to the analysis of the results, and to the writing of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Majid Safajou-jahankhanemlou.

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Hajipour, N., Ghorbanpour, M. & Safajou-jahankhanemlou, M. Synthesis and characterization of solid-state Fe-exchanged nano-bentonite and evaluation of methyl orange adsorption. Environ Sci Pollut Res 29, 49898–49907 (2022). https://doi.org/10.1007/s11356-022-19326-4

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